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Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials.

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Title: Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials.
Authors: Li, Zhipeng1 (AUTHOR), Zhang, Luxia1 (AUTHOR), Han, Xiangyu1 (AUTHOR), An, Qinchen1 (AUTHOR) lizhipeng152226@163.com, Chen, Mengying1 (AUTHOR), Song, Zichang1 (AUTHOR), Dong, Linyi1 (AUTHOR), Wang, Xianhua1 (AUTHOR) xianhua.w@163.com, Yu, Yang1 (AUTHOR) xianhua.w@163.com
Source: Polymers (20734360). Jun2024, Vol. 16 Issue 11, p1539. 15p.
Subjects: Polyacrylamide gel electrophoresis, Colloidal crystals, X-ray photoelectron spectroscopy, Porosity, Trace analysis, Egg whites, Scanning electron microscopy
Abstract: Sample pretreatment is a key step for qualitative and quantitative analysis of trace substances in complex samples. Cis-dihydroxyl (cis-diol) group-containing substances exist widely in biological samples and can be selectively bound by boronate affinity adsorbents. Based on this, in this article, we proposed a simple method for the preparation of novel spherical three-dimensionally ordered macropore (3DOM) materials based on a combination of the boronate affinity technique and colloidal crystal template method. The prepared 3DOM materials were characterized using Fourier transform–infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and thermo-gravimetric analysis, and results showed that they possessed the characteristics of a high specific surface area, high porosity, and more boronic acid recognition sites. The adsorption performance evaluation results showed that the maximum adsorption capacity of the boron affinity 3DOMs on ovalbumin (OVA) could reach to 438.79 mg/g. Kinetic and isothermal adsorption experiments indicated that the boronate affinity 3DOM material exhibited a high affinity and selectivity towards OVA and adenosine. Sodium dodecyl sulfate–polyacrylamide gel electrophoresis analysis of the proteins in egg whites was conducted and proved that the glycoprotein in the egg whites could be separated and enriched with a good performance. Therefore, a novel boronate affinity 3DOM material a with highly ordered and interconnected pore structure was prepared and could be applied in the separation and enrichment of molecules with cis-diol groups from complex samples with a good selectivity, efficiency, and high throughput. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Synthesis and Characterization of Boronate Affinity Three-Dimensionally Ordered Macroporous Materials.
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  Data: <searchLink fieldCode="AR" term="%22Li%2C+Zhipeng%22">Li, Zhipeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Luxia%22">Zhang, Luxia</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Han%2C+Xiangyu%22">Han, Xiangyu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22An%2C+Qinchen%22">An, Qinchen</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> lizhipeng152226@163.com</i><br /><searchLink fieldCode="AR" term="%22Chen%2C+Mengying%22">Chen, Mengying</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Song%2C+Zichang%22">Song, Zichang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Dong%2C+Linyi%22">Dong, Linyi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Xianhua%22">Wang, Xianhua</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xianhua.w@163.com</i><br /><searchLink fieldCode="AR" term="%22Yu%2C+Yang%22">Yu, Yang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xianhua.w@163.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. Jun2024, Vol. 16 Issue 11, p1539. 15p.
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  Data: <searchLink fieldCode="DE" term="%22Polyacrylamide+gel+electrophoresis%22">Polyacrylamide gel electrophoresis</searchLink><br /><searchLink fieldCode="DE" term="%22Colloidal+crystals%22">Colloidal crystals</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+photoelectron+spectroscopy%22">X-ray photoelectron spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Porosity%22">Porosity</searchLink><br /><searchLink fieldCode="DE" term="%22Trace+analysis%22">Trace analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Egg+whites%22">Egg whites</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopy%22">Scanning electron microscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Sample pretreatment is a key step for qualitative and quantitative analysis of trace substances in complex samples. Cis-dihydroxyl (cis-diol) group-containing substances exist widely in biological samples and can be selectively bound by boronate affinity adsorbents. Based on this, in this article, we proposed a simple method for the preparation of novel spherical three-dimensionally ordered macropore (3DOM) materials based on a combination of the boronate affinity technique and colloidal crystal template method. The prepared 3DOM materials were characterized using Fourier transform–infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and thermo-gravimetric analysis, and results showed that they possessed the characteristics of a high specific surface area, high porosity, and more boronic acid recognition sites. The adsorption performance evaluation results showed that the maximum adsorption capacity of the boron affinity 3DOMs on ovalbumin (OVA) could reach to 438.79 mg/g. Kinetic and isothermal adsorption experiments indicated that the boronate affinity 3DOM material exhibited a high affinity and selectivity towards OVA and adenosine. Sodium dodecyl sulfate–polyacrylamide gel electrophoresis analysis of the proteins in egg whites was conducted and proved that the glycoprotein in the egg whites could be separated and enriched with a good performance. Therefore, a novel boronate affinity 3DOM material a with highly ordered and interconnected pore structure was prepared and could be applied in the separation and enrichment of molecules with cis-diol groups from complex samples with a good selectivity, efficiency, and high throughput. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/polym16111539
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      – Code: eng
        Text: English
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        PageCount: 15
        StartPage: 1539
    Subjects:
      – SubjectFull: Polyacrylamide gel electrophoresis
        Type: general
      – SubjectFull: Colloidal crystals
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      – SubjectFull: X-ray photoelectron spectroscopy
        Type: general
      – SubjectFull: Porosity
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      – SubjectFull: Trace analysis
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      – SubjectFull: Egg whites
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      – SubjectFull: Scanning electron microscopy
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            – D: 01
              M: 06
              Text: Jun2024
              Type: published
              Y: 2024
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