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Performance and Morphology of Waterborne Polyurethane Asphalt in the Vicinity of Phase Inversion.

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Title: Performance and Morphology of Waterborne Polyurethane Asphalt in the Vicinity of Phase Inversion.
Authors: Wu, Chengwei1 (AUTHOR) 522022240039@smail.nju.edu.cn, Yang, Haocheng1 (AUTHOR) 522023240043@smail.nju.edu.cn, Cui, Xinpeng1 (AUTHOR) 15299908527@163.com, Chen, Yachun2 (AUTHOR) 13585153616@163.com, Xi, Zhonghua3 (AUTHOR) xizh@nju.edu.cn, Cai, Jun4 (AUTHOR) caijun@nju.edu.cn, Zhang, Junsheng1 (AUTHOR) zhangjs@nju.edu.cn, Xie, Hongfeng1 (AUTHOR) zhangjs@nju.edu.cn
Source: Materials (1996-1944). Jul2024, Vol. 17 Issue 13, p3368. 14p.
Subjects: Bituminous materials, Glass transition temperature, Polyurethanes, Asphalt, Tensile strength, Thermal stability
Abstract: Waterborne polyurethane asphalt emulsion (WPUA) is an environmentally friendly bituminous material, whose performance is highly dependent on the phase structure of the continuous phase. In this paper, WPUAs in the vicinity of phase inversion were prepared using waterborne polyurethane (WPU) and asphalt emulsion. The chemical structures, thermal stability, dynamic mechanical properties, phase-separated morphology and mechanical performance of WPUAs were studied. Fourier-transform infrared (FTIR) spectra revealed that there are no –NCO bonds in either the pure WPU or WPUAs. Moreover, the preparation of WPUA is a physical process. The addition of WPU weakens the thermal stability of asphalt emulsion. WPU improves the storage modulus of asphalt emulsion at lower and higher temperatures. The glass transition temperatures of the WPUA films are higher than that of the pure WPU film. When the WPU concentration increases from 30 wt% to 40 wt%, phase inversion occurs; that is, the continuous phase shifts from asphalt to WPU. The WPUA films have lower tensile strength and toughness than the pure WPU film. However, the elongations at break of the WPUA films are higher than that of the pure WPU film. Both the tensile strength and toughness of the WPUA films increase with the WPU concentration. Due to the occurrence of phase inversion, the elongation at break, tensile strength and toughness of the WPUA film containing 30 wt% WPU are increased by 29%, 250% and 369%, respectively, compared to the film with 40 wt% WPU. [ABSTRACT FROM AUTHOR]
Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Performance and Morphology of Waterborne Polyurethane Asphalt in the Vicinity of Phase Inversion.
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  Data: <searchLink fieldCode="AR" term="%22Wu%2C+Chengwei%22">Wu, Chengwei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> 522022240039@smail.nju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Yang%2C+Haocheng%22">Yang, Haocheng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> 522023240043@smail.nju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Cui%2C+Xinpeng%22">Cui, Xinpeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> 15299908527@163.com</i><br /><searchLink fieldCode="AR" term="%22Chen%2C+Yachun%22">Chen, Yachun</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> 13585153616@163.com</i><br /><searchLink fieldCode="AR" term="%22Xi%2C+Zhonghua%22">Xi, Zhonghua</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> xizh@nju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Cai%2C+Jun%22">Cai, Jun</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> caijun@nju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Junsheng%22">Zhang, Junsheng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhangjs@nju.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Xie%2C+Hongfeng%22">Xie, Hongfeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhangjs@nju.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Materials+%281996-1944%29%22">Materials (1996-1944)</searchLink>. Jul2024, Vol. 17 Issue 13, p3368. 14p.
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  Data: <searchLink fieldCode="DE" term="%22Bituminous+materials%22">Bituminous materials</searchLink><br /><searchLink fieldCode="DE" term="%22Glass+transition+temperature%22">Glass transition temperature</searchLink><br /><searchLink fieldCode="DE" term="%22Polyurethanes%22">Polyurethanes</searchLink><br /><searchLink fieldCode="DE" term="%22Asphalt%22">Asphalt</searchLink><br /><searchLink fieldCode="DE" term="%22Tensile+strength%22">Tensile strength</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+stability%22">Thermal stability</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Waterborne polyurethane asphalt emulsion (WPUA) is an environmentally friendly bituminous material, whose performance is highly dependent on the phase structure of the continuous phase. In this paper, WPUAs in the vicinity of phase inversion were prepared using waterborne polyurethane (WPU) and asphalt emulsion. The chemical structures, thermal stability, dynamic mechanical properties, phase-separated morphology and mechanical performance of WPUAs were studied. Fourier-transform infrared (FTIR) spectra revealed that there are no –NCO bonds in either the pure WPU or WPUAs. Moreover, the preparation of WPUA is a physical process. The addition of WPU weakens the thermal stability of asphalt emulsion. WPU improves the storage modulus of asphalt emulsion at lower and higher temperatures. The glass transition temperatures of the WPUA films are higher than that of the pure WPU film. When the WPU concentration increases from 30 wt% to 40 wt%, phase inversion occurs; that is, the continuous phase shifts from asphalt to WPU. The WPUA films have lower tensile strength and toughness than the pure WPU film. However, the elongations at break of the WPUA films are higher than that of the pure WPU film. Both the tensile strength and toughness of the WPUA films increase with the WPU concentration. Due to the occurrence of phase inversion, the elongation at break, tensile strength and toughness of the WPUA film containing 30 wt% WPU are increased by 29%, 250% and 369%, respectively, compared to the film with 40 wt% WPU. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/ma17133368
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      – Code: eng
        Text: English
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        PageCount: 14
        StartPage: 3368
    Subjects:
      – SubjectFull: Bituminous materials
        Type: general
      – SubjectFull: Glass transition temperature
        Type: general
      – SubjectFull: Polyurethanes
        Type: general
      – SubjectFull: Asphalt
        Type: general
      – SubjectFull: Tensile strength
        Type: general
      – SubjectFull: Thermal stability
        Type: general
    Titles:
      – TitleFull: Performance and Morphology of Waterborne Polyurethane Asphalt in the Vicinity of Phase Inversion.
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            – D: 01
              M: 07
              Text: Jul2024
              Type: published
              Y: 2024
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