New Modeling Approaches for Ethylene Oxychlorination in Fluidized Bed Reactors: Industrial and Low Flow Rate Conditions.

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Title: New Modeling Approaches for Ethylene Oxychlorination in Fluidized Bed Reactors: Industrial and Low Flow Rate Conditions.
Authors: El Bazi, Wail1 w.elbazi@usms.ma, Bideq, Mustapha2, El-Abidi, Abderrahim2, Yadir, Said2
Source: Bulletin of Chemical Reaction Engineering & Catalysis. Aug2024, Vol. 19 Issue 2, p300-316. 17p.
Subjects: Fluidized bed reactors, Pebble bed reactors, Ethylene, Mass transfer, Gas flow, Temperature control
Abstract: A simple model (Continuous Stirred-Tank Reactor) has been developed to predict the behavior of industrial ethylene oxychlorination fluidized beds operating in a turbulent regime. The approach showed good agreement both with results from industrial reactors and with those corresponding to the (Simple two phases-Plug bubble-Mixed flow emulsion approach) validated in the literature. For low flow rates, the use of the (Simple two phases - Plug bubble - Plug emulsion model) adapted to these conditions enabled us to highlight the location and extent of undesirable thermal hot spots for the process, and to propose actions to control them by acting on the temperature and/or on the feed gas flows. By comparing this model with the plug approach, the significant slowdown in ethylene conversion caused by resistance to mass transfer when feed flow rates are low is highlighted. [ABSTRACT FROM AUTHOR]
Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: New Modeling Approaches for Ethylene Oxychlorination in Fluidized Bed Reactors: Industrial and Low Flow Rate Conditions.
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  Data: <searchLink fieldCode="JN" term="%22Bulletin+of+Chemical+Reaction+Engineering+%26+Catalysis%22">Bulletin of Chemical Reaction Engineering & Catalysis</searchLink>. Aug2024, Vol. 19 Issue 2, p300-316. 17p.
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  Data: <searchLink fieldCode="DE" term="%22Fluidized+bed+reactors%22">Fluidized bed reactors</searchLink><br /><searchLink fieldCode="DE" term="%22Pebble+bed+reactors%22">Pebble bed reactors</searchLink><br /><searchLink fieldCode="DE" term="%22Ethylene%22">Ethylene</searchLink><br /><searchLink fieldCode="DE" term="%22Mass+transfer%22">Mass transfer</searchLink><br /><searchLink fieldCode="DE" term="%22Gas+flow%22">Gas flow</searchLink><br /><searchLink fieldCode="DE" term="%22Temperature+control%22">Temperature control</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: A simple model (Continuous Stirred-Tank Reactor) has been developed to predict the behavior of industrial ethylene oxychlorination fluidized beds operating in a turbulent regime. The approach showed good agreement both with results from industrial reactors and with those corresponding to the (Simple two phases-Plug bubble-Mixed flow emulsion approach) validated in the literature. For low flow rates, the use of the (Simple two phases - Plug bubble - Plug emulsion model) adapted to these conditions enabled us to highlight the location and extent of undesirable thermal hot spots for the process, and to propose actions to control them by acting on the temperature and/or on the feed gas flows. By comparing this model with the plug approach, the significant slowdown in ethylene conversion caused by resistance to mass transfer when feed flow rates are low is highlighted. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.9767/bcrec.20148
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 17
        StartPage: 300
    Subjects:
      – SubjectFull: Fluidized bed reactors
        Type: general
      – SubjectFull: Pebble bed reactors
        Type: general
      – SubjectFull: Ethylene
        Type: general
      – SubjectFull: Mass transfer
        Type: general
      – SubjectFull: Gas flow
        Type: general
      – SubjectFull: Temperature control
        Type: general
    Titles:
      – TitleFull: New Modeling Approaches for Ethylene Oxychlorination in Fluidized Bed Reactors: Industrial and Low Flow Rate Conditions.
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            NameFull: Bideq, Mustapha
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            NameFull: Yadir, Said
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            – D: 01
              M: 08
              Text: Aug2024
              Type: published
              Y: 2024
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