Amorphization‐controlled ion release of cobalt‐exchanged zeolite X.

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Title: Amorphization‐controlled ion release of cobalt‐exchanged zeolite X.
Authors: Azar, Ayda Nemati Vesali1 (AUTHOR), Duval, Alexis1 (AUTHOR), Langenhorst, Falko2 (AUTHOR), Wondraczek, Lothar1,3 (AUTHOR) lothar.wondraczek@uni-jena.de
Source: Journal of the American Ceramic Society. Oct2024, Vol. 107 Issue 10, p6607-6618. 12p.
Subjects: Ion exchange (Chemistry), Amorphization, Zeolites, Ions
Abstract: Zeolitic carrier materials offer ion release and uptake functionality for a wide range of applications. The release kinetics are controlled by the mobility of the target species within the zeolite framework and at its surface. Here, we achieve control over the release dynamics and the quantity of released Co2+ ions from a faujasitic zeolite through mechanical amorphization of the zeolite framework. We identify a two‐step reaction mechanism in which ion release and reintegration compete on short and intermediate timescales. The competition between these two processes is governed by the degree of amorphization, with a timescale ranging from a few minutes to several days. [ABSTRACT FROM AUTHOR]
Copyright of Journal of the American Ceramic Society is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Amorphization‐controlled ion release of cobalt‐exchanged zeolite X.
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  Data: <searchLink fieldCode="AR" term="%22Azar%2C+Ayda+Nemati+Vesali%22">Azar, Ayda Nemati Vesali</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Duval%2C+Alexis%22">Duval, Alexis</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Langenhorst%2C+Falko%22">Langenhorst, Falko</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wondraczek%2C+Lothar%22">Wondraczek, Lothar</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<i> lothar.wondraczek@uni-jena.de</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Ceramic+Society%22">Journal of the American Ceramic Society</searchLink>. Oct2024, Vol. 107 Issue 10, p6607-6618. 12p.
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  Data: <searchLink fieldCode="DE" term="%22Ion+exchange+%28Chemistry%29%22">Ion exchange (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Amorphization%22">Amorphization</searchLink><br /><searchLink fieldCode="DE" term="%22Zeolites%22">Zeolites</searchLink><br /><searchLink fieldCode="DE" term="%22Ions%22">Ions</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Zeolitic carrier materials offer ion release and uptake functionality for a wide range of applications. The release kinetics are controlled by the mobility of the target species within the zeolite framework and at its surface. Here, we achieve control over the release dynamics and the quantity of released Co2+ ions from a faujasitic zeolite through mechanical amorphization of the zeolite framework. We identify a two‐step reaction mechanism in which ion release and reintegration compete on short and intermediate timescales. The competition between these two processes is governed by the degree of amorphization, with a timescale ranging from a few minutes to several days. [ABSTRACT FROM AUTHOR]
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  Label:
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  Data: <i>Copyright of Journal of the American Ceramic Society is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1111/jace.19948
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      – Code: eng
        Text: English
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        PageCount: 12
        StartPage: 6607
    Subjects:
      – SubjectFull: Ion exchange (Chemistry)
        Type: general
      – SubjectFull: Amorphization
        Type: general
      – SubjectFull: Zeolites
        Type: general
      – SubjectFull: Ions
        Type: general
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      – TitleFull: Amorphization‐controlled ion release of cobalt‐exchanged zeolite X.
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            NameFull: Azar, Ayda Nemati Vesali
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            NameFull: Duval, Alexis
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            NameFull: Langenhorst, Falko
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            – D: 01
              M: 10
              Text: Oct2024
              Type: published
              Y: 2024
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