Characterization of Sm-rich phase and properties of hypereutectic Al-Ni alloys modified by Sm.

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Title: Characterization of Sm-rich phase and properties of hypereutectic Al-Ni alloys modified by Sm.
Authors: Mo, Liling1 (AUTHOR), Duan, Shougang1 (AUTHOR), Lin, Mingxian1 (AUTHOR), Chen, Linbo1 (AUTHOR), Du, Jun1 (AUTHOR) tandujun@sina.com
Source: Journal of Alloys & Compounds. Nov2024, Vol. 1005, pN.PAG-N.PAG. 1p.
Subjects: Tensile strength, Thermal conductivity, Thermal expansion, Thermal properties, Alloys, Hypereutectic alloys
Abstract: The impact of Samarium (Sm) addition on hypereutectic Al-Ni alloys was systematically investigated, focusing on microstructural changes and thermal-physical, mechanical properties. The addition of 0.1–0.5 wt% Sm resulted in the refinement of primary Al 3 Ni phases from coarse lath-like structures to small particles, enhancing mechanical properties and reducing thermal expansion coefficients (CTE). Thermal conductivity (TC) improved with 0.1–0.3 wt% Sm addition, but declined at the amount of 0.5 wt%. Excessive Sm addition leads to the formation of a Sm-rich phase, characterized by a two-phase mixed structure of Al 11 (Ni, Sm) 3 surrounded by Al 4 Sm. Sm addition lowered the precipitation temperature of the primary Al 3 Ni phase, inducing significant constitutional undercooling and exhibiting a phase refinement effect. The Al-9Ni-0.3Sm alloy showed excellent performance, with a TC of 211.8 W/(m·K), CTE of 17.3×10−6/K (@25–100 °C), ultimate tensile strength of 169.5 MPa, and elongation of 10.4 %. Optimal addition of Sm improved TC, mechanical properties as well as reduced the CTE in the Al alloy at the same time and showed a good modification effect. [Display omitted] • Sm addition refines the primary and eutectic Al 3 Ni phases in the Al-10Ni alloy. • Adding Sm lowers the initial solidification temperature, inducing constitutional undercooling for phase refinement. • Sm modification enhances both thermal-physical properties and mechanical properties. • A new Sm-rich structure forms at higher Sm content, affecting modification and refinement effects in the Al-10Ni alloy. • The Sm-rich structure is determined as a structure of the inner Al 11 (Sm, Ni) 3 phase wrapped by the outer Al 4 Sm phase. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
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  Data: Characterization of Sm-rich phase and properties of hypereutectic Al-Ni alloys modified by Sm.
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  Data: <searchLink fieldCode="AR" term="%22Mo%2C+Liling%22">Mo, Liling</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Duan%2C+Shougang%22">Duan, Shougang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lin%2C+Mingxian%22">Lin, Mingxian</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Linbo%22">Chen, Linbo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Du%2C+Jun%22">Du, Jun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> tandujun@sina.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Alloys+%26+Compounds%22">Journal of Alloys & Compounds</searchLink>. Nov2024, Vol. 1005, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Tensile+strength%22">Tensile strength</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+conductivity%22">Thermal conductivity</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+expansion%22">Thermal expansion</searchLink><br /><searchLink fieldCode="DE" term="%22Thermal+properties%22">Thermal properties</searchLink><br /><searchLink fieldCode="DE" term="%22Alloys%22">Alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Hypereutectic+alloys%22">Hypereutectic alloys</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The impact of Samarium (Sm) addition on hypereutectic Al-Ni alloys was systematically investigated, focusing on microstructural changes and thermal-physical, mechanical properties. The addition of 0.1–0.5 wt% Sm resulted in the refinement of primary Al 3 Ni phases from coarse lath-like structures to small particles, enhancing mechanical properties and reducing thermal expansion coefficients (CTE). Thermal conductivity (TC) improved with 0.1–0.3 wt% Sm addition, but declined at the amount of 0.5 wt%. Excessive Sm addition leads to the formation of a Sm-rich phase, characterized by a two-phase mixed structure of Al 11 (Ni, Sm) 3 surrounded by Al 4 Sm. Sm addition lowered the precipitation temperature of the primary Al 3 Ni phase, inducing significant constitutional undercooling and exhibiting a phase refinement effect. The Al-9Ni-0.3Sm alloy showed excellent performance, with a TC of 211.8 W/(m·K), CTE of 17.3×10−6/K (@25–100 °C), ultimate tensile strength of 169.5 MPa, and elongation of 10.4 %. Optimal addition of Sm improved TC, mechanical properties as well as reduced the CTE in the Al alloy at the same time and showed a good modification effect. [Display omitted] • Sm addition refines the primary and eutectic Al 3 Ni phases in the Al-10Ni alloy. • Adding Sm lowers the initial solidification temperature, inducing constitutional undercooling for phase refinement. • Sm modification enhances both thermal-physical properties and mechanical properties. • A new Sm-rich structure forms at higher Sm content, affecting modification and refinement effects in the Al-10Ni alloy. • The Sm-rich structure is determined as a structure of the inner Al 11 (Sm, Ni) 3 phase wrapped by the outer Al 4 Sm phase. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Alloys & Compounds is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1016/j.jallcom.2024.175990
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Tensile strength
        Type: general
      – SubjectFull: Thermal conductivity
        Type: general
      – SubjectFull: Thermal expansion
        Type: general
      – SubjectFull: Thermal properties
        Type: general
      – SubjectFull: Alloys
        Type: general
      – SubjectFull: Hypereutectic alloys
        Type: general
    Titles:
      – TitleFull: Characterization of Sm-rich phase and properties of hypereutectic Al-Ni alloys modified by Sm.
        Type: main
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      – PersonEntity:
          Name:
            NameFull: Mo, Liling
      – PersonEntity:
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            NameFull: Duan, Shougang
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            NameFull: Lin, Mingxian
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            NameFull: Chen, Linbo
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            NameFull: Du, Jun
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            – D: 15
              M: 11
              Text: Nov2024
              Type: published
              Y: 2024
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              Value: 09258388
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              Value: 1005
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            – TitleFull: Journal of Alloys & Compounds
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