The impact of design and operational parameters on the optimal performance of direct air capture units using solid sorbents.
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| Title: | The impact of design and operational parameters on the optimal performance of direct air capture units using solid sorbents. |
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| Authors: | Ward, Adam1,2 (AUTHOR), Papathanasiou, Maria M.1,2 (AUTHOR), Pini, Ronny1 (AUTHOR) r.pini@imperial.ac.uk |
| Source: | Adsorption. Oct2024, Vol. 30 Issue 7, p1829-1848. 20p. |
| Abstract: | Direct capture of CO 2 from ambient air is technically feasible today, with commercial units already in operation. A demonstrated technology for achieving direct air capture (DAC) is chemical separation of CO 2 in a steam-assisted temperature-vacuum swing adsorption (S-TVSA) process. However, the potential to develop scalable solutions remains high, requiring a detailed understanding of the impact of both process design and operation on the performance of the DAC unit. Here, we address this knowledge gap by presenting a state-of-the-art process simulation tool for the purification of CO 2 from ambient air by a 5-step S-TVSA process. By considering the benchmark adsorbent APDES-NFC, we conduct multi-objective productivity/energy usage optimization of the DAC unit, subject to the requirement of producing a high purity CO 2 product ( ≥ 95 %). For the base case scenario, we find a maximum productivity of Pr max = 6.20 kg/m 3 /day and a minimum specific equivalent work of W EQ , min = 1.66 MJ/kg. While in reasonable agreement with published data, our results indicate that the description of both competitive adsorption and adsorption kinetics are key factors in introducing uncertainty in process model predictions. We also demonstrate that the application of formal optimization techniques, rather than design heuristics, is central to reliably assess the process performance limits. We identity that system designs employing moderate CO 2 sorption kinetics and contactors with low length-to-radius ratios yield the best performance in terms of system productivity. Finally, we find that moderate-high ambient relative humidities (50–75%) offer significantly favourable performance, and that a wide range of feed temperatures (5–30 ∘ C) can be accommodated via process optimization without a significant impact on performance. [ABSTRACT FROM AUTHOR] |
| Copyright of Adsorption is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 179772431 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10450-024-00526-y Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 20 StartPage: 1829 Titles: – TitleFull: The impact of design and operational parameters on the optimal performance of direct air capture units using solid sorbents. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Ward, Adam – PersonEntity: Name: NameFull: Papathanasiou, Maria M. – PersonEntity: Name: NameFull: Pini, Ronny IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 10 Text: Oct2024 Type: published Y: 2024 Identifiers: – Type: issn-print Value: 09295607 Numbering: – Type: volume Value: 30 – Type: issue Value: 7 Titles: – TitleFull: Adsorption Type: main |
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