Preparation of amorphous Nd/Dy-based metal organic framework@MXene for solar driven selective photocatalytic and serving as sensor for fluorescence quenching detection, and biological activity.
Saved in:
| Title: | Preparation of amorphous Nd/Dy-based metal organic framework@MXene for solar driven selective photocatalytic and serving as sensor for fluorescence quenching detection, and biological activity. |
|---|---|
| Authors: | Zairov, Rustem R.1,2 (AUTHOR), Syed, Asad3 (AUTHOR), Tawfiq, Maha Mohammed4 (AUTHOR), Al-Hussainy, Ali Fawzi5 (AUTHOR), Mansoor, Aseel Salah6 (AUTHOR), Radi, Usama Kadem7 (AUTHOR), Idan, Ameer Hassan8 (AUTHOR), Bahair, Hala9 (AUTHOR), AL-Shwaiman, Hind A.3 (AUTHOR), Subramaniam, Manjula10 (AUTHOR), Wong, Ling Shing11 (AUTHOR), Janani, Baadal Jushi1,12 (AUTHOR) bajujanani@gmail.com, Sinyashin, Oleg G.2 (AUTHOR) |
| Source: | Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy. Feb2025, Vol. 327, pN.PAG-N.PAG. 1p. |
| Subjects: | Metal-organic frameworks, Transition metal carbides, Picric acid, Metallic glasses, Fluorescence quenching |
| Abstract: | [Display omitted] • Synthesis of Neodymium/Dysprosium metal organic framework on the MXene was conducted. • The prepared Nd/Dy-MOF@MXene was utilized in selective degradation of methyl orange dye. • The results showed exceptional efficiency of Nd/Dy-MOF@MXene to detection 2,4,6-trinitrophenol (91 %). • The antibacterial activity of Nd/Dy-MOF@MXene was investigated against Gram-positive and -negative strains. The development of a new Neodymium/Dysprosium metal–organic framework, referred to as Nd/Dy-BTC MOF, based on benzene-1,2,4-tricarboxylic acid, has been achieved through an in situ growth process on 2D transition metal carbides (MXene) surfaces. This synthesis was conducted via a solvothermal method utilizing a solvent mixture of water, ethanol, and dimethylformamide. The primary objective of this research is to investigate the framework's efficacy as a photocatalyst for the degradation of anionic dye, as well as its potential for sensing certain explosives. The Nd/Dy-MOF@MXene has been characterized by various analysis techniques. The prepared Nd/Dy-MOF@MXene was utilized as catalyst in selective degradation of methyl orange dye. The study examined the influence of pH and catalyst concentration, revealing that the catalyst achieves peak efficiency of 93.55% when exposed to sunlight in an acidic medium. The reusability of the catalyst shows the highest efficient photocatalyst after four cycles of reusability. The detection of explosives, specifically 2,4,6-trinitrophenol, through photoluminescence techniques has been conducted, utilizing the Stern-Volmer equation to evaluate the quenching efficiency. The findings indicated remarkable efficiency and selectivity of Nd/Dy-MOF@MXene for 2,4,6-trinitrophenol, achieving a quenching efficiency of 91%. Furthermore, the reusability tests demonstrated that Nd/Dy-MOF@MXene exhibits outstanding recyclability, maintaining performance over five cycles. The antibacterial activity of Nd/Dy-MOF@MXene was investigated against Gram-positive and Gram-negative strains due to indication of medicine properties of Nd/Dy-MOF@MXene. These results paves a way for manufacturing innnovation in near future. [ABSTRACT FROM AUTHOR] |
| Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
|---|---|
| Header | DbId: egs DbLabel: Engineering Source An: 181283317 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
| IllustrationInfo | |
| Items | – Name: Title Label: Title Group: Ti Data: Preparation of amorphous Nd/Dy-based metal organic framework@MXene for solar driven selective photocatalytic and serving as sensor for fluorescence quenching detection, and biological activity. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Zairov%2C+Rustem+R%2E%22">Zairov, Rustem R.</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Syed%2C+Asad%22">Syed, Asad</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tawfiq%2C+Maha+Mohammed%22">Tawfiq, Maha Mohammed</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Al-Hussainy%2C+Ali+Fawzi%22">Al-Hussainy, Ali Fawzi</searchLink><relatesTo>5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mansoor%2C+Aseel+Salah%22">Mansoor, Aseel Salah</searchLink><relatesTo>6</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Radi%2C+Usama+Kadem%22">Radi, Usama Kadem</searchLink><relatesTo>7</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Idan%2C+Ameer+Hassan%22">Idan, Ameer Hassan</searchLink><relatesTo>8</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Bahair%2C+Hala%22">Bahair, Hala</searchLink><relatesTo>9</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22AL-Shwaiman%2C+Hind+A%2E%22">AL-Shwaiman, Hind A.</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Subramaniam%2C+Manjula%22">Subramaniam, Manjula</searchLink><relatesTo>10</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wong%2C+Ling+Shing%22">Wong, Ling Shing</searchLink><relatesTo>11</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Janani%2C+Baadal+Jushi%22">Janani, Baadal Jushi</searchLink><relatesTo>1,12</relatesTo> (AUTHOR)<i> bajujanani@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Sinyashin%2C+Oleg+G%2E%22">Sinyashin, Oleg G.</searchLink><relatesTo>2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Spectrochimica+Acta+Part+A%3A+Molecular+%26+Biomolecular+Spectroscopy%22">Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy</searchLink>. Feb2025, Vol. 327, pN.PAG-N.PAG. 1p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Transition+metal+carbides%22">Transition metal carbides</searchLink><br /><searchLink fieldCode="DE" term="%22Picric+acid%22">Picric acid</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+glasses%22">Metallic glasses</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescence+quenching%22">Fluorescence quenching</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: [Display omitted] • Synthesis of Neodymium/Dysprosium metal organic framework on the MXene was conducted. • The prepared Nd/Dy-MOF@MXene was utilized in selective degradation of methyl orange dye. • The results showed exceptional efficiency of Nd/Dy-MOF@MXene to detection 2,4,6-trinitrophenol (91 %). • The antibacterial activity of Nd/Dy-MOF@MXene was investigated against Gram-positive and -negative strains. The development of a new Neodymium/Dysprosium metal–organic framework, referred to as Nd/Dy-BTC MOF, based on benzene-1,2,4-tricarboxylic acid, has been achieved through an in situ growth process on 2D transition metal carbides (MXene) surfaces. This synthesis was conducted via a solvothermal method utilizing a solvent mixture of water, ethanol, and dimethylformamide. The primary objective of this research is to investigate the framework's efficacy as a photocatalyst for the degradation of anionic dye, as well as its potential for sensing certain explosives. The Nd/Dy-MOF@MXene has been characterized by various analysis techniques. The prepared Nd/Dy-MOF@MXene was utilized as catalyst in selective degradation of methyl orange dye. The study examined the influence of pH and catalyst concentration, revealing that the catalyst achieves peak efficiency of 93.55% when exposed to sunlight in an acidic medium. The reusability of the catalyst shows the highest efficient photocatalyst after four cycles of reusability. The detection of explosives, specifically 2,4,6-trinitrophenol, through photoluminescence techniques has been conducted, utilizing the Stern-Volmer equation to evaluate the quenching efficiency. The findings indicated remarkable efficiency and selectivity of Nd/Dy-MOF@MXene for 2,4,6-trinitrophenol, achieving a quenching efficiency of 91%. Furthermore, the reusability tests demonstrated that Nd/Dy-MOF@MXene exhibits outstanding recyclability, maintaining performance over five cycles. The antibacterial activity of Nd/Dy-MOF@MXene was investigated against Gram-positive and Gram-negative strains due to indication of medicine properties of Nd/Dy-MOF@MXene. These results paves a way for manufacturing innnovation in near future. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
| PLink | https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=181283317 |
| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.saa.2024.125406 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 1 StartPage: N.PAG Subjects: – SubjectFull: Metal-organic frameworks Type: general – SubjectFull: Transition metal carbides Type: general – SubjectFull: Picric acid Type: general – SubjectFull: Metallic glasses Type: general – SubjectFull: Fluorescence quenching Type: general Titles: – TitleFull: Preparation of amorphous Nd/Dy-based metal organic framework@MXene for solar driven selective photocatalytic and serving as sensor for fluorescence quenching detection, and biological activity. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Zairov, Rustem R. – PersonEntity: Name: NameFull: Syed, Asad – PersonEntity: Name: NameFull: Tawfiq, Maha Mohammed – PersonEntity: Name: NameFull: Al-Hussainy, Ali Fawzi – PersonEntity: Name: NameFull: Mansoor, Aseel Salah – PersonEntity: Name: NameFull: Radi, Usama Kadem – PersonEntity: Name: NameFull: Idan, Ameer Hassan – PersonEntity: Name: NameFull: Bahair, Hala – PersonEntity: Name: NameFull: AL-Shwaiman, Hind A. – PersonEntity: Name: NameFull: Subramaniam, Manjula – PersonEntity: Name: NameFull: Wong, Ling Shing – PersonEntity: Name: NameFull: Janani, Baadal Jushi – PersonEntity: Name: NameFull: Sinyashin, Oleg G. IsPartOfRelationships: – BibEntity: Dates: – D: 15 M: 02 Text: Feb2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 13861425 Numbering: – Type: volume Value: 327 Titles: – TitleFull: Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy Type: main |
| ResultId | 1 |
