Synthesis and characterization of Ni@TiO2 nanocapsules for RF-MLCC electrodes via DC arc plasma method.
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| Title: | Synthesis and characterization of Ni@TiO2 nanocapsules for RF-MLCC electrodes via DC arc plasma method. |
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| Authors: | Li, Xi-Yang1 (AUTHOR), Wei, Guang-Long1 (AUTHOR), Shen, Nai-Rui1 (AUTHOR), Wang, Yi-Long1 (AUTHOR), Dong, Xing-Long1 (AUTHOR) dongxl@dlut.edu.cn, Jung, Youngguan2 (AUTHOR) |
| Source: | Materials Science & Engineering: B. Jan2025, Vol. 311, pN.PAG-N.PAG. 1p. |
| Subjects: | Ceramic capacitors, Plasma arcs, Titanium dioxide, Nitrogen plasmas, Quality factor, Nanocapsules |
| Abstract: | [Display omitted] • Ni@TiO 2 nanocapsules made by DC arc plasma in N 2 , forming core–shell structures. • TiO 2 coat on Ni nanoparticles raised oxidation resistance, start temp up ∼ 50 °C. • Improved sintering seen; 30 wt% TiO 2 samples reached 5.3% shrinkage rate. • Better high-frequency performance and Q value make Ni@TiO 2 nanocapsules a promising material for RF-MLCC internal electrodes. Ni@TiO 2 core–shell nanocapsules (NCs) were synthesized in-situ using a DC arc plasma in a nitrogen atmosphere. Compared to bare Ni nanoparticles, the coated Ni@TiO 2 nanocapsules exhibit enhanced oxidation resistance, thermal stability, delayed initial sintering temperature, and controllable thermal expansion. The sample with 30 wt% TiO 2 addition shows an onset oxidation temperature of 251.9 °C and a sintering shrinkage of 5.4 % at 1200 °C. The TiO 2 shell demonstrates high compatibility with the Ni core and an excellent quality factor (Q), with the 5 wt% TiO 2 addition sample achieving a maximum Q value of 16.5 at 12.3 GHz. Additionally, the DC arc method enables the in-situ preparation of Ni@TiO 2 NCs under a nitrogen atmosphere, making it suitable for large-scale industrial production. Thus, Ni@TiO 2 NCs present a promising material for next-generation radio-frequency multilayer ceramic capacitors (RF-MLCCs). [ABSTRACT FROM AUTHOR] |
| Copyright of Materials Science & Engineering: B is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 181488306 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Synthesis and characterization of Ni@TiO2 nanocapsules for RF-MLCC electrodes via DC arc plasma method. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Li%2C+Xi-Yang%22">Li, Xi-Yang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wei%2C+Guang-Long%22">Wei, Guang-Long</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Shen%2C+Nai-Rui%22">Shen, Nai-Rui</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Yi-Long%22">Wang, Yi-Long</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Dong%2C+Xing-Long%22">Dong, Xing-Long</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> dongxl@dlut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Jung%2C+Youngguan%22">Jung, Youngguan</searchLink><relatesTo>2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Materials+Science+%26+Engineering%3A+B%22">Materials Science & Engineering: B</searchLink>. Jan2025, Vol. 311, pN.PAG-N.PAG. 1p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Ceramic+capacitors%22">Ceramic capacitors</searchLink><br /><searchLink fieldCode="DE" term="%22Plasma+arcs%22">Plasma arcs</searchLink><br /><searchLink fieldCode="DE" term="%22Titanium+dioxide%22">Titanium dioxide</searchLink><br /><searchLink fieldCode="DE" term="%22Nitrogen+plasmas%22">Nitrogen plasmas</searchLink><br /><searchLink fieldCode="DE" term="%22Quality+factor%22">Quality factor</searchLink><br /><searchLink fieldCode="DE" term="%22Nanocapsules%22">Nanocapsules</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: [Display omitted] • Ni@TiO 2 nanocapsules made by DC arc plasma in N 2 , forming core–shell structures. • TiO 2 coat on Ni nanoparticles raised oxidation resistance, start temp up ∼ 50 °C. • Improved sintering seen; 30 wt% TiO 2 samples reached 5.3% shrinkage rate. • Better high-frequency performance and Q value make Ni@TiO 2 nanocapsules a promising material for RF-MLCC internal electrodes. Ni@TiO 2 core–shell nanocapsules (NCs) were synthesized in-situ using a DC arc plasma in a nitrogen atmosphere. Compared to bare Ni nanoparticles, the coated Ni@TiO 2 nanocapsules exhibit enhanced oxidation resistance, thermal stability, delayed initial sintering temperature, and controllable thermal expansion. The sample with 30 wt% TiO 2 addition shows an onset oxidation temperature of 251.9 °C and a sintering shrinkage of 5.4 % at 1200 °C. The TiO 2 shell demonstrates high compatibility with the Ni core and an excellent quality factor (Q), with the 5 wt% TiO 2 addition sample achieving a maximum Q value of 16.5 at 12.3 GHz. Additionally, the DC arc method enables the in-situ preparation of Ni@TiO 2 NCs under a nitrogen atmosphere, making it suitable for large-scale industrial production. Thus, Ni@TiO 2 NCs present a promising material for next-generation radio-frequency multilayer ceramic capacitors (RF-MLCCs). [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Materials Science & Engineering: B is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1016/j.mseb.2024.117861 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 1 StartPage: N.PAG Subjects: – SubjectFull: Ceramic capacitors Type: general – SubjectFull: Plasma arcs Type: general – SubjectFull: Titanium dioxide Type: general – SubjectFull: Nitrogen plasmas Type: general – SubjectFull: Quality factor Type: general – SubjectFull: Nanocapsules Type: general Titles: – TitleFull: Synthesis and characterization of Ni@TiO2 nanocapsules for RF-MLCC electrodes via DC arc plasma method. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Li, Xi-Yang – PersonEntity: Name: NameFull: Wei, Guang-Long – PersonEntity: Name: NameFull: Shen, Nai-Rui – PersonEntity: Name: NameFull: Wang, Yi-Long – PersonEntity: Name: NameFull: Dong, Xing-Long – PersonEntity: Name: NameFull: Jung, Youngguan IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 01 Text: Jan2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 09215107 Numbering: – Type: volume Value: 311 Titles: – TitleFull: Materials Science & Engineering: B Type: main |
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