Bio-sourced tartaric acid-derived tartarimides as diol counterparts towards renewable polyurethanes.
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| Title: | Bio-sourced tartaric acid-derived tartarimides as diol counterparts towards renewable polyurethanes. |
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| Authors: | Kara, Zehra1 (AUTHOR), Yalvar, Mehmet Alp1 (AUTHOR), Arslan, Mehmet1 (AUTHOR) mehmet.arslan@yalova.edu.tr |
| Source: | Journal of Macromolecular Science: Pure & Applied Chemistry. 2024, Vol. 61 Issue 12, p977-985. 9p. |
| Subjects: | Reactive polymers, Crosslinked polymers, Condensation reactions, Monomers, Tartaric acid |
| Abstract: | The depletion of petroleum-based fossil resources and ever-increasing environmental problems are serious issues in the production of polymeric materials. An increasingly important approach is to obtain the building blocks used in the production of these materials from renewable sources of natural origin. In the present study, bio-sourced tartaric acid-based tartarimides were evaluated as monomeric diol compounds to synthesize polyurethane polymers. Structurally diverse tartarimides were conveniently obtained from the condensation reactions of tartaric acid with various primary amine compounds. The diol structure of the generated tartarimides allowed to access polyurethanes along with the polymerizations of diisocyanate monomers. Copolymers in the range of 22.9 kDa to 29.3 kDa molecular weights were obtained with moderately high total monomer conversions (up to 96%). Depending on the tartarimide and diisocyanate monomers employed during polymerization, copolymers with different physical and thermal properties were generated. By utilizing tartarimides carrying furan and alkene functionalities, side chain reactive polyurethanes were synthesized. These reactive polymers were evaluated in post-polymerization modification and crosslinking processes by using radical thiol-ene and Diels-Alder based click reactions. The results obtained in this study demonstrated that the bio-sourced tartarimides could provide a convenient access to structurally tailorable polyurethane polymers that are important materials in various applications. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Macromolecular Science: Pure & Applied Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 181626873 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Bio-sourced tartaric acid-derived tartarimides as diol counterparts towards renewable polyurethanes. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Kara%2C+Zehra%22">Kara, Zehra</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yalvar%2C+Mehmet+Alp%22">Yalvar, Mehmet Alp</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Arslan%2C+Mehmet%22">Arslan, Mehmet</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> mehmet.arslan@yalova.edu.tr</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Macromolecular+Science%3A+Pure+%26+Applied+Chemistry%22">Journal of Macromolecular Science: Pure & Applied Chemistry</searchLink>. 2024, Vol. 61 Issue 12, p977-985. 9p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Reactive+polymers%22">Reactive polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Crosslinked+polymers%22">Crosslinked polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Condensation+reactions%22">Condensation reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Monomers%22">Monomers</searchLink><br /><searchLink fieldCode="DE" term="%22Tartaric+acid%22">Tartaric acid</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The depletion of petroleum-based fossil resources and ever-increasing environmental problems are serious issues in the production of polymeric materials. An increasingly important approach is to obtain the building blocks used in the production of these materials from renewable sources of natural origin. In the present study, bio-sourced tartaric acid-based tartarimides were evaluated as monomeric diol compounds to synthesize polyurethane polymers. Structurally diverse tartarimides were conveniently obtained from the condensation reactions of tartaric acid with various primary amine compounds. The diol structure of the generated tartarimides allowed to access polyurethanes along with the polymerizations of diisocyanate monomers. Copolymers in the range of 22.9 kDa to 29.3 kDa molecular weights were obtained with moderately high total monomer conversions (up to 96%). Depending on the tartarimide and diisocyanate monomers employed during polymerization, copolymers with different physical and thermal properties were generated. By utilizing tartarimides carrying furan and alkene functionalities, side chain reactive polyurethanes were synthesized. These reactive polymers were evaluated in post-polymerization modification and crosslinking processes by using radical thiol-ene and Diels-Alder based click reactions. The results obtained in this study demonstrated that the bio-sourced tartarimides could provide a convenient access to structurally tailorable polyurethane polymers that are important materials in various applications. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Macromolecular Science: Pure & Applied Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1080/10601325.2024.2419528 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 9 StartPage: 977 Subjects: – SubjectFull: Reactive polymers Type: general – SubjectFull: Crosslinked polymers Type: general – SubjectFull: Condensation reactions Type: general – SubjectFull: Monomers Type: general – SubjectFull: Tartaric acid Type: general Titles: – TitleFull: Bio-sourced tartaric acid-derived tartarimides as diol counterparts towards renewable polyurethanes. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Kara, Zehra – PersonEntity: Name: NameFull: Yalvar, Mehmet Alp – PersonEntity: Name: NameFull: Arslan, Mehmet IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 12 Text: 2024 Type: published Y: 2024 Identifiers: – Type: issn-print Value: 10601325 Numbering: – Type: volume Value: 61 – Type: issue Value: 12 Titles: – TitleFull: Journal of Macromolecular Science: Pure & Applied Chemistry Type: main |
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