Estimation of gamma radiation effects on the polypropylene (PP) films at various doses.

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Title: Estimation of gamma radiation effects on the polypropylene (PP) films at various doses.
Authors: Massoud, Ayman1 (AUTHOR) ayman_mass@yahoo.com, Maziad, Nabila A.2 (AUTHOR), Othman, Mousa3 (AUTHOR), Borai, Emad H.4 (AUTHOR)
Source: Journal of Macromolecular Science: Pure & Applied Chemistry. 2024, Vol. 61 Issue 12, p1005-1018. 14p.
Subjects: Radiation sterilization, Gamma rays, Ionizing radiation, Electron paramagnetic resonance, Fourier transform infrared spectroscopy
Abstract: Medical polypropylene (PP) is exposed to ionizing radiation during the sterilization process before its use for medical purposes. Herein, the raw and manufactured PP were prepared as polymeric films with the same specifications. Then, raw and manufactured PP were irradiated by different doses of gamma rays in the air to discover the gamma radiation effects on the prepared films. The gamma doses were 25, 50, 75, 100, and 200 kGy. The irradiated raw and manufactured PP were characterized by different analytical techniques such as Electron Spin Resonance Spectrometer (ESR), Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), and mechanical properties. The FTIR study indicated the presence of a new band at a low gamma dose for both cases. The crystallinity percentages of both raw and manufactured PP gradually reduced when the gamma doses increased. The thermal stability of films decreased by increasing the gamma doses. Raising the gamma dosages resulted in a decrease in the mechanical characteristics of raw PP and manufactured PP such as elongation @ break, elastic modulus, and tensile strength. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Macromolecular Science: Pure & Applied Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Estimation of gamma radiation effects on the polypropylene (PP) films at various doses.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Massoud%2C+Ayman%22">Massoud, Ayman</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ayman_mass@yahoo.com</i><br /><searchLink fieldCode="AR" term="%22Maziad%2C+Nabila+A%2E%22">Maziad, Nabila A.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Othman%2C+Mousa%22">Othman, Mousa</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Borai%2C+Emad+H%2E%22">Borai, Emad H.</searchLink><relatesTo>4</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Macromolecular+Science%3A+Pure+%26+Applied+Chemistry%22">Journal of Macromolecular Science: Pure & Applied Chemistry</searchLink>. 2024, Vol. 61 Issue 12, p1005-1018. 14p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Radiation+sterilization%22">Radiation sterilization</searchLink><br /><searchLink fieldCode="DE" term="%22Gamma+rays%22">Gamma rays</searchLink><br /><searchLink fieldCode="DE" term="%22Ionizing+radiation%22">Ionizing radiation</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+paramagnetic+resonance%22">Electron paramagnetic resonance</searchLink><br /><searchLink fieldCode="DE" term="%22Fourier+transform+infrared+spectroscopy%22">Fourier transform infrared spectroscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Medical polypropylene (PP) is exposed to ionizing radiation during the sterilization process before its use for medical purposes. Herein, the raw and manufactured PP were prepared as polymeric films with the same specifications. Then, raw and manufactured PP were irradiated by different doses of gamma rays in the air to discover the gamma radiation effects on the prepared films. The gamma doses were 25, 50, 75, 100, and 200 kGy. The irradiated raw and manufactured PP were characterized by different analytical techniques such as Electron Spin Resonance Spectrometer (ESR), Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), and mechanical properties. The FTIR study indicated the presence of a new band at a low gamma dose for both cases. The crystallinity percentages of both raw and manufactured PP gradually reduced when the gamma doses increased. The thermal stability of films decreased by increasing the gamma doses. Raising the gamma dosages resulted in a decrease in the mechanical characteristics of raw PP and manufactured PP such as elongation @ break, elastic modulus, and tensile strength. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Macromolecular Science: Pure & Applied Chemistry is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1080/10601325.2024.2419531
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      – Code: eng
        Text: English
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        PageCount: 14
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      – SubjectFull: Radiation sterilization
        Type: general
      – SubjectFull: Gamma rays
        Type: general
      – SubjectFull: Ionizing radiation
        Type: general
      – SubjectFull: Electron paramagnetic resonance
        Type: general
      – SubjectFull: Fourier transform infrared spectroscopy
        Type: general
    Titles:
      – TitleFull: Estimation of gamma radiation effects on the polypropylene (PP) films at various doses.
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            NameFull: Massoud, Ayman
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            NameFull: Maziad, Nabila A.
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            NameFull: Othman, Mousa
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            NameFull: Borai, Emad H.
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          Dates:
            – D: 01
              M: 12
              Text: 2024
              Type: published
              Y: 2024
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            – TitleFull: Journal of Macromolecular Science: Pure & Applied Chemistry
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