Analysis of the Effects of Neutron Radiation on Cellulose Linen Fabrics Using Non-Destructive Testing.

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Title: Analysis of the Effects of Neutron Radiation on Cellulose Linen Fabrics Using Non-Destructive Testing.
Authors: Barta, César1 (AUTHOR) cesar.barta@alumnos.uc3m.es, Fernández-Álvarez, María2 (AUTHOR) maria.fernandez@icv.csic.es, Ruiz-Navas, Elisa María1 (AUTHOR)
Source: Polymers (20734360). Dec2024, Vol. 16 Issue 23, p3401. 19p.
Subjects: Gamma rays, Linen, Nuclear magnetic resonance, Raman spectroscopy, Nondestructive testing, Nuclear magnetic resonance spectroscopy, Neutron irradiation
Abstract: This work describes the effects of using neutron irradiation on cellulose and non-destructive methods to analyze linen fabrics of high heritage value. For this purpose, 8 samples were irradiated with increasing doses of neutrons and gamma rays up to 166 kGy of total dose. The samples were characterized by techniques such as ultraviolet luminescence, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, Raman spectroscopy, and the nuclear magnetic resonance (NMR) technique. The luminescence of linen fabrics in the ultraviolet range increases markedly with dosage. Some chemical changes were also perceived by the ATR-FTIR spectra in the linen samples. Similarly, the fluorescence background observed in Raman spectroscopy intensifies with dosage. Due to the heterogeneity of the textile cellulose, NMR offers limited applicability for detecting neutron doses in cultural heritage fabrics. Radiation is applied for preservation against microorganisms in cultural heritage objects where the damage is to be assessed. This radiation can occasionally be found after earthquakes or in volcanic archaeological sites, which could question its dating using carbon 14. Despite some limitations encountered due to working with commonly used linen fabrics, the techniques employed in this study have made it possible to observe trends between the responses obtained and the irradiation dose for each linen sample. [ABSTRACT FROM AUTHOR]
Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Analysis of the Effects of Neutron Radiation on Cellulose Linen Fabrics Using Non-Destructive Testing.
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  Data: <searchLink fieldCode="JN" term="%22Polymers+%2820734360%29%22">Polymers (20734360)</searchLink>. Dec2024, Vol. 16 Issue 23, p3401. 19p.
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  Data: <searchLink fieldCode="DE" term="%22Gamma+rays%22">Gamma rays</searchLink><br /><searchLink fieldCode="DE" term="%22Linen%22">Linen</searchLink><br /><searchLink fieldCode="DE" term="%22Nuclear+magnetic+resonance%22">Nuclear magnetic resonance</searchLink><br /><searchLink fieldCode="DE" term="%22Raman+spectroscopy%22">Raman spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Nondestructive+testing%22">Nondestructive testing</searchLink><br /><searchLink fieldCode="DE" term="%22Nuclear+magnetic+resonance+spectroscopy%22">Nuclear magnetic resonance spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22Neutron+irradiation%22">Neutron irradiation</searchLink>
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  Data: This work describes the effects of using neutron irradiation on cellulose and non-destructive methods to analyze linen fabrics of high heritage value. For this purpose, 8 samples were irradiated with increasing doses of neutrons and gamma rays up to 166 kGy of total dose. The samples were characterized by techniques such as ultraviolet luminescence, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, Raman spectroscopy, and the nuclear magnetic resonance (NMR) technique. The luminescence of linen fabrics in the ultraviolet range increases markedly with dosage. Some chemical changes were also perceived by the ATR-FTIR spectra in the linen samples. Similarly, the fluorescence background observed in Raman spectroscopy intensifies with dosage. Due to the heterogeneity of the textile cellulose, NMR offers limited applicability for detecting neutron doses in cultural heritage fabrics. Radiation is applied for preservation against microorganisms in cultural heritage objects where the damage is to be assessed. This radiation can occasionally be found after earthquakes or in volcanic archaeological sites, which could question its dating using carbon 14. Despite some limitations encountered due to working with commonly used linen fabrics, the techniques employed in this study have made it possible to observe trends between the responses obtained and the irradiation dose for each linen sample. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Polymers (20734360) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.3390/polym16233401
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      – Code: eng
        Text: English
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        PageCount: 19
        StartPage: 3401
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        Type: general
      – SubjectFull: Linen
        Type: general
      – SubjectFull: Nuclear magnetic resonance
        Type: general
      – SubjectFull: Raman spectroscopy
        Type: general
      – SubjectFull: Nondestructive testing
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      – SubjectFull: Nuclear magnetic resonance spectroscopy
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      – SubjectFull: Neutron irradiation
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      – TitleFull: Analysis of the Effects of Neutron Radiation on Cellulose Linen Fabrics Using Non-Destructive Testing.
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          Name:
            NameFull: Barta, César
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            NameFull: Fernández-Álvarez, María
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            NameFull: Ruiz-Navas, Elisa María
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            – D: 01
              M: 12
              Text: Dec2024
              Type: published
              Y: 2024
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