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Synthesis and characterisation of biodegradable copolymer containing phthalocyanine by ring-opening polymerization.

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Title: Synthesis and characterisation of biodegradable copolymer containing phthalocyanine by ring-opening polymerization.
Authors: Güngördü Solğun, Derya1 (AUTHOR), Savaş, Bedrettin2 (AUTHOR), Salih Ağırtaş, Mehmet1 (AUTHOR) salihagirtas@hotmail.com, Öztürk, Temel3 (AUTHOR)
Source: Materials Research Innovations. Jan2025, Vol. 29 Issue 1, p51-56. 6p.
Subjects: Methoxyethanol, Ring-opening polymerization, Methyl ether, Reactive oxygen species, Ethylene glycol
Abstract: In this study, well-known biodegradable poly [(β-butyrolactone-block-ethylene glycol methyl ether)-phthalocyanine- (β-butyrolactone-block-ethylene glycol methyl ether)] abbreviated as poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was synthesised. In the first part, poly (β-butyrolactone-block-ethylene glycol methyl ether) [poly(BL-b-mEG)] block copolymer was prepared by ring-opening polymerisation (ROP) method of β-butyrolactone using poly (ethylene glycol) methyl ether. In the second part, poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was obtained from the reaction poly(BL-b-mEG) block copolymer, SiPcCl2, and K2CO3. Axial binding of poly(BL-b-mEG) block copolymers to the phthalocyanine compound was achieved. The synthesised products were characterised by using multi-instruments such as1H-NMR, FT-IR, GPC, ve UV-visible. The electronic and singlet oxygen production capacity of poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was investigated. [ABSTRACT FROM AUTHOR]
Copyright of Materials Research Innovations is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Group: Ti
  Data: Synthesis and characterisation of biodegradable copolymer containing phthalocyanine by ring-opening polymerization.
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  Data: <searchLink fieldCode="AR" term="%22Güngördü+Solğun%2C+Derya%22">Güngördü Solğun, Derya</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Savaş%2C+Bedrettin%22">Savaş, Bedrettin</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Salih+Ağırtaş%2C+Mehmet%22">Salih Ağırtaş, Mehmet</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> salihagirtas@hotmail.com</i><br /><searchLink fieldCode="AR" term="%22Öztürk%2C+Temel%22">Öztürk, Temel</searchLink><relatesTo>3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+Research+Innovations%22">Materials Research Innovations</searchLink>. Jan2025, Vol. 29 Issue 1, p51-56. 6p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Methoxyethanol%22">Methoxyethanol</searchLink><br /><searchLink fieldCode="DE" term="%22Ring-opening+polymerization%22">Ring-opening polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+ether%22">Methyl ether</searchLink><br /><searchLink fieldCode="DE" term="%22Reactive+oxygen+species%22">Reactive oxygen species</searchLink><br /><searchLink fieldCode="DE" term="%22Ethylene+glycol%22">Ethylene glycol</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this study, well-known biodegradable poly [(β-butyrolactone-block-ethylene glycol methyl ether)-phthalocyanine- (β-butyrolactone-block-ethylene glycol methyl ether)] abbreviated as poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was synthesised. In the first part, poly (β-butyrolactone-block-ethylene glycol methyl ether) [poly(BL-b-mEG)] block copolymer was prepared by ring-opening polymerisation (ROP) method of β-butyrolactone using poly (ethylene glycol) methyl ether. In the second part, poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was obtained from the reaction poly(BL-b-mEG) block copolymer, SiPcCl2, and K2CO3. Axial binding of poly(BL-b-mEG) block copolymers to the phthalocyanine compound was achieved. The synthesised products were characterised by using multi-instruments such as1H-NMR, FT-IR, GPC, ve UV-visible. The electronic and singlet oxygen production capacity of poly(BL-b-mEG)-Pc-poly(BL-b-mEG) copolymer was investigated. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials Research Innovations is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1080/14328917.2024.2371098
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      – Code: eng
        Text: English
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        PageCount: 6
        StartPage: 51
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      – SubjectFull: Methoxyethanol
        Type: general
      – SubjectFull: Ring-opening polymerization
        Type: general
      – SubjectFull: Methyl ether
        Type: general
      – SubjectFull: Reactive oxygen species
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      – SubjectFull: Ethylene glycol
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      – TitleFull: Synthesis and characterisation of biodegradable copolymer containing phthalocyanine by ring-opening polymerization.
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            NameFull: Güngördü Solğun, Derya
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            NameFull: Savaş, Bedrettin
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            NameFull: Salih Ağırtaş, Mehmet
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            – D: 01
              M: 01
              Text: Jan2025
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              Y: 2025
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