Tunable TiZrMoC Coatings: A Comprehensive Study of Microstructure, Mechanical Properties, and Wear Resistance.

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Title: Tunable TiZrMoC Coatings: A Comprehensive Study of Microstructure, Mechanical Properties, and Wear Resistance.
Authors: Pogrebnjak, Alexander1,2 (AUTHOR) oleksandr.pohrebniak@stuba.sk, Buranych, Volodymyr2 (AUTHOR) maksakova.tereshenko@gmail.com, Ivashchenko, Volodymyr3 (AUTHOR) dir@ipms.kyiv.ua, Borba-Pogrebnjak, Svitlana1 (AUTHOR) o.goncharov@mss.sumdu.edu.ua, Maksakova, Olga2 (AUTHOR) martin.sahul@stuba.sk, Caplovicová, Maria4 (AUTHOR) maria.caplovicova@stuba.sk, Goncharov, Alexander1,2 (AUTHOR), Onoprienko, Alexei3 (AUTHOR) onopr@ipms.kiev.ua, Skrynskyy, Petro3 (AUTHOR) p.scryn@ipms.kyiv.ua, Sahul, Martin2 (AUTHOR), Konarski, Piotr5 (AUTHOR) piotr.konarski@itr.lukasiewicz.gov.pl, Budzynski, Piotr6 (AUTHOR) p.budzynski@pollub.pl, Kaminski, Mariusz6 (AUTHOR) mariusz.kaminski@pollub.pl, Opielak, Marek7 (AUTHOR) m.opielak@pollub.pl, Flock, Dominik8 (AUTHOR) dominik.flock@tu-ilmenau.de, Pelenovich, Vasiliy9,10 (AUTHOR) pelenovich@mail.ru, Bing, Yang11 (AUTHOR) 00008360@whu.edu.cn
Source: Nanomaterials (2079-4991). Dec2024, Vol. 14 Issue 24, p1986. 23p.
Subjects: X-ray photoelectron spectroscopy, DC sputtering, Valence (Chemistry), Magnetron sputtering, Wear resistance
Abstract: TiZrMoC coatings were deposited on Si(100) substrates using a DC dual magnetron sputtering. The composition was controlled by adjusting the sputtering parameters of the TiZrMo and graphite targets. The influence of graphite target current on the resulting coating properties was explored. TEM analysis revealed a single-phase structure with Ti/Mo/Zr substitutional elements, columnar grains, and a strong [111] texture. Nanotwins and stacking faults were prevalent within the nanocrystals. EDX, SIMS, XRD, and XPS analyses confirmed the elemental composition and nanostructure. Computational modeling was employed to investigate the mixing behavior of the quaternary solid solutions depending on the valency electron concentration. The films exhibited exceptional mechanical properties, including a maximum hardness of 35 GPa and a wear rate of 2.11 × 10−7 mm3N−1m−1, attributed to the presence of an amorphous carbon layer and optimized deposition parameters. These findings demonstrate the potential of TiZrMoC coatings for advanced applications requiring exceptional wear resistance and durability. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Tunable TiZrMoC Coatings: A Comprehensive Study of Microstructure, Mechanical Properties, and Wear Resistance.
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  Data: <searchLink fieldCode="AR" term="%22Pogrebnjak%2C+Alexander%22">Pogrebnjak, Alexander</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> oleksandr.pohrebniak@stuba.sk</i><br /><searchLink fieldCode="AR" term="%22Buranych%2C+Volodymyr%22">Buranych, Volodymyr</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> maksakova.tereshenko@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Ivashchenko%2C+Volodymyr%22">Ivashchenko, Volodymyr</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> dir@ipms.kyiv.ua</i><br /><searchLink fieldCode="AR" term="%22Borba-Pogrebnjak%2C+Svitlana%22">Borba-Pogrebnjak, Svitlana</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> o.goncharov@mss.sumdu.edu.ua</i><br /><searchLink fieldCode="AR" term="%22Maksakova%2C+Olga%22">Maksakova, Olga</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> martin.sahul@stuba.sk</i><br /><searchLink fieldCode="AR" term="%22Caplovicová%2C+Maria%22">Caplovicová, Maria</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> maria.caplovicova@stuba.sk</i><br /><searchLink fieldCode="AR" term="%22Goncharov%2C+Alexander%22">Goncharov, Alexander</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Onoprienko%2C+Alexei%22">Onoprienko, Alexei</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> onopr@ipms.kiev.ua</i><br /><searchLink fieldCode="AR" term="%22Skrynskyy%2C+Petro%22">Skrynskyy, Petro</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> p.scryn@ipms.kyiv.ua</i><br /><searchLink fieldCode="AR" term="%22Sahul%2C+Martin%22">Sahul, Martin</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Konarski%2C+Piotr%22">Konarski, Piotr</searchLink><relatesTo>5</relatesTo> (AUTHOR)<i> piotr.konarski@itr.lukasiewicz.gov.pl</i><br /><searchLink fieldCode="AR" term="%22Budzynski%2C+Piotr%22">Budzynski, Piotr</searchLink><relatesTo>6</relatesTo> (AUTHOR)<i> p.budzynski@pollub.pl</i><br /><searchLink fieldCode="AR" term="%22Kaminski%2C+Mariusz%22">Kaminski, Mariusz</searchLink><relatesTo>6</relatesTo> (AUTHOR)<i> mariusz.kaminski@pollub.pl</i><br /><searchLink fieldCode="AR" term="%22Opielak%2C+Marek%22">Opielak, Marek</searchLink><relatesTo>7</relatesTo> (AUTHOR)<i> m.opielak@pollub.pl</i><br /><searchLink fieldCode="AR" term="%22Flock%2C+Dominik%22">Flock, Dominik</searchLink><relatesTo>8</relatesTo> (AUTHOR)<i> dominik.flock@tu-ilmenau.de</i><br /><searchLink fieldCode="AR" term="%22Pelenovich%2C+Vasiliy%22">Pelenovich, Vasiliy</searchLink><relatesTo>9,10</relatesTo> (AUTHOR)<i> pelenovich@mail.ru</i><br /><searchLink fieldCode="AR" term="%22Bing%2C+Yang%22">Bing, Yang</searchLink><relatesTo>11</relatesTo> (AUTHOR)<i> 00008360@whu.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Dec2024, Vol. 14 Issue 24, p1986. 23p.
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  Data: <searchLink fieldCode="DE" term="%22X-ray+photoelectron+spectroscopy%22">X-ray photoelectron spectroscopy</searchLink><br /><searchLink fieldCode="DE" term="%22DC+sputtering%22">DC sputtering</searchLink><br /><searchLink fieldCode="DE" term="%22Valence+%28Chemistry%29%22">Valence (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetron+sputtering%22">Magnetron sputtering</searchLink><br /><searchLink fieldCode="DE" term="%22Wear+resistance%22">Wear resistance</searchLink>
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  Data: TiZrMoC coatings were deposited on Si(100) substrates using a DC dual magnetron sputtering. The composition was controlled by adjusting the sputtering parameters of the TiZrMo and graphite targets. The influence of graphite target current on the resulting coating properties was explored. TEM analysis revealed a single-phase structure with Ti/Mo/Zr substitutional elements, columnar grains, and a strong [111] texture. Nanotwins and stacking faults were prevalent within the nanocrystals. EDX, SIMS, XRD, and XPS analyses confirmed the elemental composition and nanostructure. Computational modeling was employed to investigate the mixing behavior of the quaternary solid solutions depending on the valency electron concentration. The films exhibited exceptional mechanical properties, including a maximum hardness of 35 GPa and a wear rate of 2.11 × 10−7 mm3N−1m−1, attributed to the presence of an amorphous carbon layer and optimized deposition parameters. These findings demonstrate the potential of TiZrMoC coatings for advanced applications requiring exceptional wear resistance and durability. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/nano14241986
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        Text: English
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        PageCount: 23
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      – SubjectFull: DC sputtering
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      – SubjectFull: Valence (Chemistry)
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      – SubjectFull: Magnetron sputtering
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      – SubjectFull: Wear resistance
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      – TitleFull: Tunable TiZrMoC Coatings: A Comprehensive Study of Microstructure, Mechanical Properties, and Wear Resistance.
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