Production of Ag nanowires with high yield and narrow size distribution by promoting nucleation through hot injection and their application to disposable paper electrodes.

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Title: Production of Ag nanowires with high yield and narrow size distribution by promoting nucleation through hot injection and their application to disposable paper electrodes.
Authors: Lin Feng, Lin1 (AUTHOR), Hyuck Heo, Jin1 (AUTHOR), Ji Han, Hye2 (AUTHOR), Jun Park, Bum1,2 (AUTHOR), Hyuk Im, Sang1 (AUTHOR) imromy@korea.ac.kr
Source: Journal of Industrial & Engineering Chemistry. Apr2025, Vol. 144, p616-624. 9p.
Subjects: Rate of nucleation, Corporate bonds, Nanowires, Electrodes, Cellulose
Abstract: • The growth of a narrow diameter distribution of Ag Nws was achieved using the hot injection method. • The Ag NWs exhibited an average diameter of 35 nm, lengths > 20 μm, and yield > 87%. • Disposable Ag NWs paper electrodes worked well even when subjected to bending or tearing. The polyol method has been the most commonly used technique for fabricating silver nanowires (Ag NWs), wherein additive reagents facilitate precise control over their morphology. In this work, we introduced a straightforward approach to synthesize Ag NWs with minimal impurities and uniform diameter by using hot injection method. The underlying mechanism and final product are evaluated, and the scalable process was optimized to achieve a high yield (∼87.8%). It was found that the hot injection of a Ag precursor at 170 °C significantly accelerated the reduction of Ag ions. The issue of the uniformity of Ag NWs was addressed by adding an organic halide to control the nucleation rate of Ag. The resulting Ag NWs solution was used to impregnated cellulose paper, forming an enhanced electrical network compared to other substrates. Given the low commercial cost of paper, this approach holds significant potential for widespread use in disposable electrodes. Furthermore, after subjecting the fabricated paper electrodes to various forms of damage, the connected LED bulbs consistently maintained their brightness. This demonstrates the network stability and suitability of these electrodes for flexible applications. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Industrial & Engineering Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Production of Ag nanowires with high yield and narrow size distribution by promoting nucleation through hot injection and their application to disposable paper electrodes.
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  Data: <searchLink fieldCode="AR" term="%22Lin+Feng%2C+Lin%22">Lin Feng, Lin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hyuck+Heo%2C+Jin%22">Hyuck Heo, Jin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ji+Han%2C+Hye%22">Ji Han, Hye</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jun+Park%2C+Bum%22">Jun Park, Bum</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hyuk+Im%2C+Sang%22">Hyuk Im, Sang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> imromy@korea.ac.kr</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Industrial+%26+Engineering+Chemistry%22">Journal of Industrial & Engineering Chemistry</searchLink>. Apr2025, Vol. 144, p616-624. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Rate+of+nucleation%22">Rate of nucleation</searchLink><br /><searchLink fieldCode="DE" term="%22Corporate+bonds%22">Corporate bonds</searchLink><br /><searchLink fieldCode="DE" term="%22Nanowires%22">Nanowires</searchLink><br /><searchLink fieldCode="DE" term="%22Electrodes%22">Electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Cellulose%22">Cellulose</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: • The growth of a narrow diameter distribution of Ag Nws was achieved using the hot injection method. • The Ag NWs exhibited an average diameter of 35 nm, lengths > 20 μm, and yield > 87%. • Disposable Ag NWs paper electrodes worked well even when subjected to bending or tearing. The polyol method has been the most commonly used technique for fabricating silver nanowires (Ag NWs), wherein additive reagents facilitate precise control over their morphology. In this work, we introduced a straightforward approach to synthesize Ag NWs with minimal impurities and uniform diameter by using hot injection method. The underlying mechanism and final product are evaluated, and the scalable process was optimized to achieve a high yield (∼87.8%). It was found that the hot injection of a Ag precursor at 170 °C significantly accelerated the reduction of Ag ions. The issue of the uniformity of Ag NWs was addressed by adding an organic halide to control the nucleation rate of Ag. The resulting Ag NWs solution was used to impregnated cellulose paper, forming an enhanced electrical network compared to other substrates. Given the low commercial cost of paper, this approach holds significant potential for widespread use in disposable electrodes. Furthermore, after subjecting the fabricated paper electrodes to various forms of damage, the connected LED bulbs consistently maintained their brightness. This demonstrates the network stability and suitability of these electrodes for flexible applications. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Industrial & Engineering Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1016/j.jiec.2024.10.006
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: 616
    Subjects:
      – SubjectFull: Rate of nucleation
        Type: general
      – SubjectFull: Corporate bonds
        Type: general
      – SubjectFull: Nanowires
        Type: general
      – SubjectFull: Electrodes
        Type: general
      – SubjectFull: Cellulose
        Type: general
    Titles:
      – TitleFull: Production of Ag nanowires with high yield and narrow size distribution by promoting nucleation through hot injection and their application to disposable paper electrodes.
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            NameFull: Lin Feng, Lin
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            NameFull: Hyuck Heo, Jin
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            NameFull: Ji Han, Hye
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            NameFull: Jun Park, Bum
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            NameFull: Hyuk Im, Sang
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            – D: 25
              M: 04
              Text: Apr2025
              Type: published
              Y: 2025
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              Value: 144
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            – TitleFull: Journal of Industrial & Engineering Chemistry
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