Microstructural constituents in compositionally graded NiCrFeSiBC hardfacing alloy/316L SS additive manufactured deposits.

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Title: Microstructural constituents in compositionally graded NiCrFeSiBC hardfacing alloy/316L SS additive manufactured deposits.
Authors: Haribabu, S.1,2 (AUTHOR) haribabu.mme@gmail.com, Paul, C. P.2,3 (AUTHOR), Srihari, V.4 (AUTHOR), Sudha, C.1,2 (AUTHOR)
Source: Welding International. Mar2025, Vol. 39 Issue 3, p175-181. 7p.
Subjects: Liquid metal fast breeder reactors, Liquid alloys, Steel welding, Fretting corrosion, Residual stresses
Abstract: Ni-Cr-Fe-Si-B-C hardfacing alloys (D50) provide excellent resistance to abrasive and adhesive wear, high temperature oxidation and corrosion. These alloys are candidate materials for hardface coatings on in-reactor components of fast breeder reactors. Conventionally these deposits are made on steels through the welding route. Due to high fluidity of the molten alloy, generation of residual stress and significant dilution of the deposit, achieving crack free deposits is often a very difficult and time consuming task. To address such issues arising out of conventional fabrication routes, compositionally graded coatings have been tried through laser additive manufacturing. A 3 layered compositionally graded deposit (D50/50D50-50SS/SS) was made on 316 L SS build plate and the phase constituents and possible correlation with micro hardness was analyzed. Uppermost D50 layer consisted of γ-Ni, γ-Ni + Ni3B and γ-Ni + Cr5B3 eutectics, CrB, Cr7C3, Cr23C6, Cr3C2 and Ni3Si precipitates. The middle layer consisted of γ-(Ni,Fe), γ-(Ni,Fe)+Cr5B3, Cr5B3, Cr3C2, Cr7C3,Cr23C6 and Ni3Si. The SS layer closest to the build plate had γ-Fe, Cr3C2 and Cr7C3 precipitates. Corresponding to the variation in microstructure a gradual change in hardness also can be seen starting from the top layer to SS build plate: 580 ± 35 HV0.1, 532 ± 17 HV0.1, 348 ± 21 HV0.1 and 230 ± 10 HV0.1, which is promising. [ABSTRACT FROM AUTHOR]
Copyright of Welding International is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Microstructural constituents in compositionally graded NiCrFeSiBC hardfacing alloy/316L SS additive manufactured deposits.
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  Data: <searchLink fieldCode="JN" term="%22Welding+International%22">Welding International</searchLink>. Mar2025, Vol. 39 Issue 3, p175-181. 7p.
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  Data: <searchLink fieldCode="DE" term="%22Liquid+metal+fast+breeder+reactors%22">Liquid metal fast breeder reactors</searchLink><br /><searchLink fieldCode="DE" term="%22Liquid+alloys%22">Liquid alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Steel+welding%22">Steel welding</searchLink><br /><searchLink fieldCode="DE" term="%22Fretting+corrosion%22">Fretting corrosion</searchLink><br /><searchLink fieldCode="DE" term="%22Residual+stresses%22">Residual stresses</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Ni-Cr-Fe-Si-B-C hardfacing alloys (D50) provide excellent resistance to abrasive and adhesive wear, high temperature oxidation and corrosion. These alloys are candidate materials for hardface coatings on in-reactor components of fast breeder reactors. Conventionally these deposits are made on steels through the welding route. Due to high fluidity of the molten alloy, generation of residual stress and significant dilution of the deposit, achieving crack free deposits is often a very difficult and time consuming task. To address such issues arising out of conventional fabrication routes, compositionally graded coatings have been tried through laser additive manufacturing. A 3 layered compositionally graded deposit (D50/50D50-50SS/SS) was made on 316 L SS build plate and the phase constituents and possible correlation with micro hardness was analyzed. Uppermost D50 layer consisted of γ-Ni, γ-Ni + Ni3B and γ-Ni + Cr5B3 eutectics, CrB, Cr7C3, Cr23C6, Cr3C2 and Ni3Si precipitates. The middle layer consisted of γ-(Ni,Fe), γ-(Ni,Fe)+Cr5B3, Cr5B3, Cr3C2, Cr7C3,Cr23C6 and Ni3Si. The SS layer closest to the build plate had γ-Fe, Cr3C2 and Cr7C3 precipitates. Corresponding to the variation in microstructure a gradual change in hardness also can be seen starting from the top layer to SS build plate: 580 ± 35 HV0.1, 532 ± 17 HV0.1, 348 ± 21 HV0.1 and 230 ± 10 HV0.1, which is promising. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Welding International is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1080/09507116.2024.2406272
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        Text: English
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        Type: general
      – SubjectFull: Liquid alloys
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      – SubjectFull: Steel welding
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      – SubjectFull: Fretting corrosion
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      – SubjectFull: Residual stresses
        Type: general
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      – TitleFull: Microstructural constituents in compositionally graded NiCrFeSiBC hardfacing alloy/316L SS additive manufactured deposits.
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            – D: 01
              M: 03
              Text: Mar2025
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              Y: 2025
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