Improving piezoelectric strain, temperature stability and strain symmetry on KNN-based ceramics sintered in reducing atmosphere via designing internal bias field.

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Title: Improving piezoelectric strain, temperature stability and strain symmetry on KNN-based ceramics sintered in reducing atmosphere via designing internal bias field.
Authors: Cen, Zhenyong1 (AUTHOR) zycenguet@163.com, Lu, Yuwei1 (AUTHOR), Feng, Meiyi1 (AUTHOR), Cao, Fuzhi1 (AUTHOR), Cai, Jiexing1 (AUTHOR), Zeng, Fanda2 (AUTHOR), Zhou, Changrong3 (AUTHOR), Luo, Nengneng1 (AUTHOR), Dou, Zhongshang4 (AUTHOR), Xu, Ze1,2 (AUTHOR) xu-ze@mail.tsinghua.edu.cn
Source: Ceramics International. Mar2025, Vol. 51 Issue 6, p7684-7692. 9p.
Subjects: Oxygen vacancy, Lead-free ceramics, Piezoelectric ceramics, High temperatures, Ceramics
Abstract: The KNNT-7BZ+8Mn ceramics sintered in reducing atmosphere with large piezoelectric strain, high temperature stability and good bipolar strain symmetry are prepared successfully via designing internal bias field (E i). With increasing re-oxidation time (t a) from 4h to 6h, oxygen vacancy (V o · · ) concentration decreases, weakening domain pinning effect. E i created by defect polarization (P d) can be enhanced by constructing weak binding defects (Mn Nb ′), which enhances spontaneous polarization (P S) stretching. Piezoelectric strain of ceramics annealed at t a = 5h can be increased by synergistic effect between weakening of domain pinning effect and enhancement of P S stretching. E i of suitable strength created by reducing the concentration of V o · · can improve bipolar strain symmetry of KNNT-7BZ+8Mn ceramics. Improving temperature stability from 83 °C at t a = 4h to 130 °C at t a = 6h for KNNT-7BZ+8Mn ceramics is attributing to the stable E i. [ABSTRACT FROM AUTHOR]
Copyright of Ceramics International is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Improving piezoelectric strain, temperature stability and strain symmetry on KNN-based ceramics sintered in reducing atmosphere via designing internal bias field.
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  Data: <searchLink fieldCode="AR" term="%22Cen%2C+Zhenyong%22">Cen, Zhenyong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zycenguet@163.com</i><br /><searchLink fieldCode="AR" term="%22Lu%2C+Yuwei%22">Lu, Yuwei</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Feng%2C+Meiyi%22">Feng, Meiyi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cao%2C+Fuzhi%22">Cao, Fuzhi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cai%2C+Jiexing%22">Cai, Jiexing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zeng%2C+Fanda%22">Zeng, Fanda</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhou%2C+Changrong%22">Zhou, Changrong</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Luo%2C+Nengneng%22">Luo, Nengneng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Dou%2C+Zhongshang%22">Dou, Zhongshang</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Ze%22">Xu, Ze</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> xu-ze@mail.tsinghua.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Ceramics+International%22">Ceramics International</searchLink>. Mar2025, Vol. 51 Issue 6, p7684-7692. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Oxygen+vacancy%22">Oxygen vacancy</searchLink><br /><searchLink fieldCode="DE" term="%22Lead-free+ceramics%22">Lead-free ceramics</searchLink><br /><searchLink fieldCode="DE" term="%22Piezoelectric+ceramics%22">Piezoelectric ceramics</searchLink><br /><searchLink fieldCode="DE" term="%22High+temperatures%22">High temperatures</searchLink><br /><searchLink fieldCode="DE" term="%22Ceramics%22">Ceramics</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The KNNT-7BZ+8Mn ceramics sintered in reducing atmosphere with large piezoelectric strain, high temperature stability and good bipolar strain symmetry are prepared successfully via designing internal bias field (E i). With increasing re-oxidation time (t a) from 4h to 6h, oxygen vacancy (V o · · ) concentration decreases, weakening domain pinning effect. E i created by defect polarization (P d) can be enhanced by constructing weak binding defects (Mn Nb ′), which enhances spontaneous polarization (P S) stretching. Piezoelectric strain of ceramics annealed at t a = 5h can be increased by synergistic effect between weakening of domain pinning effect and enhancement of P S stretching. E i of suitable strength created by reducing the concentration of V o · · can improve bipolar strain symmetry of KNNT-7BZ+8Mn ceramics. Improving temperature stability from 83 °C at t a = 4h to 130 °C at t a = 6h for KNNT-7BZ+8Mn ceramics is attributing to the stable E i. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Ceramics International is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.ceramint.2024.12.206
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: 7684
    Subjects:
      – SubjectFull: Oxygen vacancy
        Type: general
      – SubjectFull: Lead-free ceramics
        Type: general
      – SubjectFull: Piezoelectric ceramics
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      – SubjectFull: High temperatures
        Type: general
      – SubjectFull: Ceramics
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      – TitleFull: Improving piezoelectric strain, temperature stability and strain symmetry on KNN-based ceramics sintered in reducing atmosphere via designing internal bias field.
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            NameFull: Cen, Zhenyong
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            NameFull: Lu, Yuwei
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            – D: 01
              M: 03
              Text: Mar2025
              Type: published
              Y: 2025
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