Preparation of Antioxidant and Antifouling Ultrafiltration Membrane by Co-blending Eugenol with Polyethylene Glycol-Modified Polyvinylidene Fluoride.

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Title: Preparation of Antioxidant and Antifouling Ultrafiltration Membrane by Co-blending Eugenol with Polyethylene Glycol-Modified Polyvinylidene Fluoride.
Authors: Wang, Ting1,2 (AUTHOR) wangting@sinap.ac.cn, Hu, Jun1 (AUTHOR), Hou, Zhengchi3 (AUTHOR), Yang, Haijun3 (AUTHOR)
Source: Journal of Macromolecular Science: Physics. 2025, Vol. 64 Issue 4, p375-393. 19p.
Subjects: Methoxyethanol, Antioxidant testing, Service life, Eugenol, Phase separation, Polyvinylidene fluoride
Abstract: Polyvinylidene fluoride-graft-polyethylene glycol methyl acrylate (PVDF-g-PEGMA) was prepared by grafting PEGMA onto PVDF using a homogeneous irradiation grafting method. After incorporating various concentrations of eugenol, a natural antioxidant component of clove oil, the membranes were fabricated through non-solvent induced phase separation. The results indicated that the addition of eugenol did not alter the inherent properties of the membrane but slightly reduced the pore size and water flux. The cyclic flux test showed that eugenol did not compromise the anti-fouling performance of the membrane, with the flux recovery ratio exceeding 93%. The antioxidant performance test revealed that eugenol enhanced the membrane's capacity to remove free radicals and imparted oxidation resistance in NaClO solution, making the modified membrane suitable for use in oxidizing environments. This study successfully demonstrated a simple method to prepare a bifunctional membrane with anti-fouling and antioxidant properties, potentially extending its service life and applicability in oxidative contexts. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Macromolecular Science: Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Preparation of Antioxidant and Antifouling Ultrafiltration Membrane by Co-blending Eugenol with Polyethylene Glycol-Modified Polyvinylidene Fluoride.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Wang%2C+Ting%22">Wang, Ting</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> wangting@sinap.ac.cn</i><br /><searchLink fieldCode="AR" term="%22Hu%2C+Jun%22">Hu, Jun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hou%2C+Zhengchi%22">Hou, Zhengchi</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Haijun%22">Yang, Haijun</searchLink><relatesTo>3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Macromolecular+Science%3A+Physics%22">Journal of Macromolecular Science: Physics</searchLink>. 2025, Vol. 64 Issue 4, p375-393. 19p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Methoxyethanol%22">Methoxyethanol</searchLink><br /><searchLink fieldCode="DE" term="%22Antioxidant+testing%22">Antioxidant testing</searchLink><br /><searchLink fieldCode="DE" term="%22Service+life%22">Service life</searchLink><br /><searchLink fieldCode="DE" term="%22Eugenol%22">Eugenol</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+separation%22">Phase separation</searchLink><br /><searchLink fieldCode="DE" term="%22Polyvinylidene+fluoride%22">Polyvinylidene fluoride</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Polyvinylidene fluoride-graft-polyethylene glycol methyl acrylate (PVDF-g-PEGMA) was prepared by grafting PEGMA onto PVDF using a homogeneous irradiation grafting method. After incorporating various concentrations of eugenol, a natural antioxidant component of clove oil, the membranes were fabricated through non-solvent induced phase separation. The results indicated that the addition of eugenol did not alter the inherent properties of the membrane but slightly reduced the pore size and water flux. The cyclic flux test showed that eugenol did not compromise the anti-fouling performance of the membrane, with the flux recovery ratio exceeding 93%. The antioxidant performance test revealed that eugenol enhanced the membrane's capacity to remove free radicals and imparted oxidation resistance in NaClO solution, making the modified membrane suitable for use in oxidizing environments. This study successfully demonstrated a simple method to prepare a bifunctional membrane with anti-fouling and antioxidant properties, potentially extending its service life and applicability in oxidative contexts. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Macromolecular Science: Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1080/00222348.2024.2347764
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 19
        StartPage: 375
    Subjects:
      – SubjectFull: Methoxyethanol
        Type: general
      – SubjectFull: Antioxidant testing
        Type: general
      – SubjectFull: Service life
        Type: general
      – SubjectFull: Eugenol
        Type: general
      – SubjectFull: Phase separation
        Type: general
      – SubjectFull: Polyvinylidene fluoride
        Type: general
    Titles:
      – TitleFull: Preparation of Antioxidant and Antifouling Ultrafiltration Membrane by Co-blending Eugenol with Polyethylene Glycol-Modified Polyvinylidene Fluoride.
        Type: main
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            NameFull: Wang, Ting
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            NameFull: Hu, Jun
      – PersonEntity:
          Name:
            NameFull: Hou, Zhengchi
      – PersonEntity:
          Name:
            NameFull: Yang, Haijun
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          Dates:
            – D: 01
              M: 04
              Text: 2025
              Type: published
              Y: 2025
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              Value: 00222348
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              Value: 64
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              Value: 4
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            – TitleFull: Journal of Macromolecular Science: Physics
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