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Possible Influence of Pores and Other Structural Defects on the Temperature of the Polymorphic Transformation of HMX.

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Title: Possible Influence of Pores and Other Structural Defects on the Temperature of the Polymorphic Transformation of HMX.
Authors: Zlobin, A. M.1 (AUTHOR) postmaster@ifv.vniief.ru, Belukhina, P. S.1 (AUTHOR), Bondareva, S. V.1 (AUTHOR), Vakhmistrov, S. A.1 (AUTHOR), Grebennikova, S. E.1 (AUTHOR), Kirsanova, T. E.1 (AUTHOR), Miroshnichenko, N. A.1 (AUTHOR), Skvirskaya, A. V.1 (AUTHOR), Starostina, A. A.1 (AUTHOR), Sheikov, A. V.1 (AUTHOR)
Source: Combustion, Explosion, & Shock Waves. Dec2024, Vol. 60 Issue 6, p730-736. 7p.
Subjects: Polymorphic transformations, Differential thermal analysis, Crystal defects, Enthalpy, Crystals
Abstract: Results of experimental investigations of the polymorphic transformation of various fractions of HMX are reported; the studies are performed by methods of differential thermal and thermogravimetric analysis, as well as by picnometer tests. With an increase in the crystal size, it is found that the temperature of the beginning of the polymorphic transformation of HMX decreases, and the HMX density also decreases. It is hypothesized that the change in the polymorphic transformation temperature is associated with the dependence of the enthalpy jump on the polymorphic transformation on structural defects. [ABSTRACT FROM AUTHOR]
Copyright of Combustion, Explosion, & Shock Waves is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Possible Influence of Pores and Other Structural Defects on the Temperature of the Polymorphic Transformation of HMX.
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  Data: <searchLink fieldCode="JN" term="%22Combustion%2C+Explosion%2C+%26+Shock+Waves%22">Combustion, Explosion, & Shock Waves</searchLink>. Dec2024, Vol. 60 Issue 6, p730-736. 7p.
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  Data: Results of experimental investigations of the polymorphic transformation of various fractions of HMX are reported; the studies are performed by methods of differential thermal and thermogravimetric analysis, as well as by picnometer tests. With an increase in the crystal size, it is found that the temperature of the beginning of the polymorphic transformation of HMX decreases, and the HMX density also decreases. It is hypothesized that the change in the polymorphic transformation temperature is associated with the dependence of the enthalpy jump on the polymorphic transformation on structural defects. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Combustion, Explosion, & Shock Waves is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – SubjectFull: Crystal defects
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      – TitleFull: Possible Influence of Pores and Other Structural Defects on the Temperature of the Polymorphic Transformation of HMX.
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