The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites.

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Title: The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites.
Authors: Kosmela, Paulina1 (AUTHOR), Olszewski, Adam1 (AUTHOR), Barczewski, Mateusz2 (AUTHOR), Piasecki, Adam3 (AUTHOR), Hejna, Aleksander1,2 (AUTHOR) aleksander.hejna@put.poznan.pl
Source: Journal of Materials Engineering & Performance. Mar2025, Vol. 34 Issue 5, p4203-4216. 14p.
Subjects: Filler materials, Performance of tires, Automobile tires, Fireproofing agents, Urethane foam, Flammability
Abstract: Current sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the impact of hybrid flame retardant (FR) combinations of ammonium polyphosphate (APP) or melamine cyanurate (MC) with organophosphorus compounds on the performance of foamed flexible PU/GTR composites. Such works are of vital importance, because matching to the needs of material with the mode of action of particular FRs is quite challenging. Except for the flammability reduction, they also affect structure and performance of composites. Fire resistance was enhanced for all applied FRs compositions; however, APP was found more effective than MC due to the efficient formation of protective char layer. Moreover, introduction of MC induced heterogeneity of cellular structure and excessive stiffening of PU structure, which increased its friability and cells' coalescence, deteriorating thermal insulation performance and damping ability. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Engineering & Performance is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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An: 183974944
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  Label: Title
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  Data: The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites.
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  Data: <searchLink fieldCode="AR" term="%22Kosmela%2C+Paulina%22">Kosmela, Paulina</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Olszewski%2C+Adam%22">Olszewski, Adam</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Barczewski%2C+Mateusz%22">Barczewski, Mateusz</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Piasecki%2C+Adam%22">Piasecki, Adam</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hejna%2C+Aleksander%22">Hejna, Aleksander</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> aleksander.hejna@put.poznan.pl</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Engineering+%26+Performance%22">Journal of Materials Engineering & Performance</searchLink>. Mar2025, Vol. 34 Issue 5, p4203-4216. 14p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Filler+materials%22">Filler materials</searchLink><br /><searchLink fieldCode="DE" term="%22Performance+of+tires%22">Performance of tires</searchLink><br /><searchLink fieldCode="DE" term="%22Automobile+tires%22">Automobile tires</searchLink><br /><searchLink fieldCode="DE" term="%22Fireproofing+agents%22">Fireproofing agents</searchLink><br /><searchLink fieldCode="DE" term="%22Urethane+foam%22">Urethane foam</searchLink><br /><searchLink fieldCode="DE" term="%22Flammability%22">Flammability</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Current sustainability-oriented trends affect polyurethane (PU) materials and stimulate the incorporation of recycled or waste-based materials as fillers. Ground tire rubber (GTR) poses as an auspicious candidate due to the excellent performance of car tires. Despite the benefits related to the mechanical performance, it contributes to the increasing flammability of the resulting composites. Herein, presented work assessed the impact of hybrid flame retardant (FR) combinations of ammonium polyphosphate (APP) or melamine cyanurate (MC) with organophosphorus compounds on the performance of foamed flexible PU/GTR composites. Such works are of vital importance, because matching to the needs of material with the mode of action of particular FRs is quite challenging. Except for the flammability reduction, they also affect structure and performance of composites. Fire resistance was enhanced for all applied FRs compositions; however, APP was found more effective than MC due to the efficient formation of protective char layer. Moreover, introduction of MC induced heterogeneity of cellular structure and excessive stiffening of PU structure, which increased its friability and cells' coalescence, deteriorating thermal insulation performance and damping ability. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Engineering & Performance is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s11665-024-09362-1
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 14
        StartPage: 4203
    Subjects:
      – SubjectFull: Filler materials
        Type: general
      – SubjectFull: Performance of tires
        Type: general
      – SubjectFull: Automobile tires
        Type: general
      – SubjectFull: Fireproofing agents
        Type: general
      – SubjectFull: Urethane foam
        Type: general
      – SubjectFull: Flammability
        Type: general
    Titles:
      – TitleFull: The Impact of Hybrid Flame Retardant Compositions on the Performance of Foamed Flexible Polyurethane/Ground Tire Rubber Composites.
        Type: main
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          Name:
            NameFull: Kosmela, Paulina
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            NameFull: Olszewski, Adam
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            NameFull: Barczewski, Mateusz
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            NameFull: Piasecki, Adam
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            NameFull: Hejna, Aleksander
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            – D: 01
              M: 03
              Text: Mar2025
              Type: published
              Y: 2025
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              Value: 34
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