View in EDS HTML Full Text PDF Full Text

Application of a Modified van Der Waals Model to Calculate Phase Diagrams of Binary Mixtures of Helium, Neon, Hydrogen, and Deuterium.

Saved in:
Bibliographic Details
Title: Application of a Modified van Der Waals Model to Calculate Phase Diagrams of Binary Mixtures of Helium, Neon, Hydrogen, and Deuterium.
Authors: Medvedev, A. B.1 (AUTHOR) postmaster@ifv.vniief.ru
Source: High Temperature. Oct2024, Vol. 62 Issue 5, p604-615. 12p.
Subjects: Isothermal compression, Phase equilibrium, Binary mixtures, Phase diagrams, Hydrogen, Neon, Deuterium, Equations of state
Abstract: Based on the previously developed modified van der Waals model for individual substances, updated thermal equations of state for helium, neon, hydrogen, and deuterium up to pressures of ~200 MPa and temperatures of ~1000 K are constructed, consistent with the experimental data on isothermal compression with an accuracy of ~1% in density (except for the region near the critical point). Their advantage lies in the relatively small (five) number of free parameters. Using these equations on the basis of a modified van der Waals model for mixtures, the phase diagrams of binary mixtures of helium, neon, hydrogen, and deuterium with each other and some other substances (argon, methane, hydrogen dioxide, etc.) are described. Using one additional parameter, satisfactory agreement with the liquid–gas phase equilibrium experiment is achieved for most of the named mixtures up to pressures of ~200 MPa. The developed approach can be used to describe phase diagrams of binary mixtures other than those considered. [ABSTRACT FROM AUTHOR]
Copyright of High Temperature is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Full text is not displayed to guests.
FullText Links:
  – Type: pdflink
Text:
  Availability: 1
Header DbId: egs
DbLabel: Engineering Source
An: 184167510
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Application of a Modified van Der Waals Model to Calculate Phase Diagrams of Binary Mixtures of Helium, Neon, Hydrogen, and Deuterium.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Medvedev%2C+A%2E+B%2E%22">Medvedev, A. B.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> postmaster@ifv.vniief.ru</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22High+Temperature%22">High Temperature</searchLink>. Oct2024, Vol. 62 Issue 5, p604-615. 12p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Isothermal+compression%22">Isothermal compression</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+equilibrium%22">Phase equilibrium</searchLink><br /><searchLink fieldCode="DE" term="%22Binary+mixtures%22">Binary mixtures</searchLink><br /><searchLink fieldCode="DE" term="%22Phase+diagrams%22">Phase diagrams</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen%22">Hydrogen</searchLink><br /><searchLink fieldCode="DE" term="%22Neon%22">Neon</searchLink><br /><searchLink fieldCode="DE" term="%22Deuterium%22">Deuterium</searchLink><br /><searchLink fieldCode="DE" term="%22Equations+of+state%22">Equations of state</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Based on the previously developed modified van der Waals model for individual substances, updated thermal equations of state for helium, neon, hydrogen, and deuterium up to pressures of ~200 MPa and temperatures of ~1000 K are constructed, consistent with the experimental data on isothermal compression with an accuracy of ~1% in density (except for the region near the critical point). Their advantage lies in the relatively small (five) number of free parameters. Using these equations on the basis of a modified van der Waals model for mixtures, the phase diagrams of binary mixtures of helium, neon, hydrogen, and deuterium with each other and some other substances (argon, methane, hydrogen dioxide, etc.) are described. Using one additional parameter, satisfactory agreement with the liquid–gas phase equilibrium experiment is achieved for most of the named mixtures up to pressures of ~200 MPa. The developed approach can be used to describe phase diagrams of binary mixtures other than those considered. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of High Temperature is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=184167510
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1134/S0018151X25700154
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 12
        StartPage: 604
    Subjects:
      – SubjectFull: Isothermal compression
        Type: general
      – SubjectFull: Phase equilibrium
        Type: general
      – SubjectFull: Binary mixtures
        Type: general
      – SubjectFull: Phase diagrams
        Type: general
      – SubjectFull: Hydrogen
        Type: general
      – SubjectFull: Neon
        Type: general
      – SubjectFull: Deuterium
        Type: general
      – SubjectFull: Equations of state
        Type: general
    Titles:
      – TitleFull: Application of a Modified van Der Waals Model to Calculate Phase Diagrams of Binary Mixtures of Helium, Neon, Hydrogen, and Deuterium.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Medvedev, A. B.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 10
              Text: Oct2024
              Type: published
              Y: 2024
          Identifiers:
            – Type: issn-print
              Value: 0018151X
          Numbering:
            – Type: volume
              Value: 62
            – Type: issue
              Value: 5
          Titles:
            – TitleFull: High Temperature
              Type: main
ResultId 1