Biochar Addition Changes the Aggregation of Clay Mineral and Natural Soil Nanoparticles via Different Mechanisms.
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| Title: | Biochar Addition Changes the Aggregation of Clay Mineral and Natural Soil Nanoparticles via Different Mechanisms. |
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| Authors: | Li, Qi‐rui1,2 (AUTHOR), Xu, Chen‐yang1,3 (AUTHOR) xuchenyang.ms@163.com, Geng, Zeng‐chao1,3 (AUTHOR), Hu, Fei‐nan4,5 (AUTHOR), Wang, Chun‐li1,2 (AUTHOR) |
| Source: | European Journal of Soil Science. Mar/Apr2025, Vol. 76 Issue 2, p1-12. 12p. |
| Subjects: | Organic compound content of soils, Clay, Soil mineralogy, DLVO theory, Clay minerals, Hematite |
| Abstract: | Wide application of biochar and subsequent release of biochar nanoparticles (NPs) significantly impact the stability of natural clay minerals and soil NPs, which are crucial for soil quality and play a vital role in determining the fate of nutrients and contaminants in the environment. Soil is a naturally occurring complex system composed of multiple components. Existing research on soil particle aggregation has predominantly focused on homo‐aggregation. However, the addition of biochar to soil inevitably induces hetero‐aggregation with soil components. In this study, the effects of biochar NPs on the aggregation of representative clay minerals (hematite and illite) and natural soil NPs from Luvisol, Phaeozem and Ferralsol under various solution chemistry were studied. The mechanisms were further elucidated by adopting the Derjaguin‐Landau‐Verwey‐Overbeek (DLVO) theory. The results indicated that the addition of negatively charged biochar NPs significantly altered the aggregation behaviours of positively charged hematite NPs through charge neutralisation. The aggregation of negatively charged illite particles was inhibited by the generating H‐bonding and steric repulsion. Biochar NPs significantly increased the colloidal stability of Luvisol (from 343.82 to 382.96 mM) and Ferralsol NPs (from 28.39 to 215.35 mM) by increasing the net DLVO repulsive forces. Nevertheless, the stability of Phaeozem NPs, containing higher organic matter, decreased with increasing biochar NP concentrations due to electrostatic shielding. In conclusion, for complicated natural soil systems with significant differences between organic and inorganic components, the application of biochar NPs has a profound impact on colloidal particle interactions, particularly affecting positively‐charged mineral colloids and soils with low soil organic matter content. [ABSTRACT FROM AUTHOR] |
| Copyright of European Journal of Soil Science is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 184712991 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Biochar Addition Changes the Aggregation of Clay Mineral and Natural Soil Nanoparticles via Different Mechanisms. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Li%2C+Qi‐rui%22">Li, Qi‐rui</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Chen‐yang%22">Xu, Chen‐yang</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<i> xuchenyang.ms@163.com</i><br /><searchLink fieldCode="AR" term="%22Geng%2C+Zeng‐chao%22">Geng, Zeng‐chao</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hu%2C+Fei‐nan%22">Hu, Fei‐nan</searchLink><relatesTo>4,5</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Chun‐li%22">Wang, Chun‐li</searchLink><relatesTo>1,2</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22European+Journal+of+Soil+Science%22">European Journal of Soil Science</searchLink>. Mar/Apr2025, Vol. 76 Issue 2, p1-12. 12p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Organic+compound+content+of+soils%22">Organic compound content of soils</searchLink><br /><searchLink fieldCode="DE" term="%22Clay%22">Clay</searchLink><br /><searchLink fieldCode="DE" term="%22Soil+mineralogy%22">Soil mineralogy</searchLink><br /><searchLink fieldCode="DE" term="%22DLVO+theory%22">DLVO theory</searchLink><br /><searchLink fieldCode="DE" term="%22Clay+minerals%22">Clay minerals</searchLink><br /><searchLink fieldCode="DE" term="%22Hematite%22">Hematite</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Wide application of biochar and subsequent release of biochar nanoparticles (NPs) significantly impact the stability of natural clay minerals and soil NPs, which are crucial for soil quality and play a vital role in determining the fate of nutrients and contaminants in the environment. Soil is a naturally occurring complex system composed of multiple components. Existing research on soil particle aggregation has predominantly focused on homo‐aggregation. However, the addition of biochar to soil inevitably induces hetero‐aggregation with soil components. In this study, the effects of biochar NPs on the aggregation of representative clay minerals (hematite and illite) and natural soil NPs from Luvisol, Phaeozem and Ferralsol under various solution chemistry were studied. The mechanisms were further elucidated by adopting the Derjaguin‐Landau‐Verwey‐Overbeek (DLVO) theory. The results indicated that the addition of negatively charged biochar NPs significantly altered the aggregation behaviours of positively charged hematite NPs through charge neutralisation. The aggregation of negatively charged illite particles was inhibited by the generating H‐bonding and steric repulsion. Biochar NPs significantly increased the colloidal stability of Luvisol (from 343.82 to 382.96 mM) and Ferralsol NPs (from 28.39 to 215.35 mM) by increasing the net DLVO repulsive forces. Nevertheless, the stability of Phaeozem NPs, containing higher organic matter, decreased with increasing biochar NP concentrations due to electrostatic shielding. In conclusion, for complicated natural soil systems with significant differences between organic and inorganic components, the application of biochar NPs has a profound impact on colloidal particle interactions, particularly affecting positively‐charged mineral colloids and soils with low soil organic matter content. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of European Journal of Soil Science is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1111/ejss.70056 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 12 StartPage: 1 Subjects: – SubjectFull: Organic compound content of soils Type: general – SubjectFull: Clay Type: general – SubjectFull: Soil mineralogy Type: general – SubjectFull: DLVO theory Type: general – SubjectFull: Clay minerals Type: general – SubjectFull: Hematite Type: general Titles: – TitleFull: Biochar Addition Changes the Aggregation of Clay Mineral and Natural Soil Nanoparticles via Different Mechanisms. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Li, Qi‐rui – PersonEntity: Name: NameFull: Xu, Chen‐yang – PersonEntity: Name: NameFull: Geng, Zeng‐chao – PersonEntity: Name: NameFull: Hu, Fei‐nan – PersonEntity: Name: NameFull: Wang, Chun‐li IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 03 Text: Mar/Apr2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 13510754 Numbering: – Type: volume Value: 76 – Type: issue Value: 2 Titles: – TitleFull: European Journal of Soil Science Type: main |
| ResultId | 1 |