Synthesis and characterization of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer via free-radical polymerization and 'click' chemistry.
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| Title: | Synthesis and characterization of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer via free-radical polymerization and 'click' chemistry. |
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| Authors: | Savaş, Bedrettin1 (AUTHOR), Öztürk, Temel2 (AUTHOR) temelozturk@msn.com, Günaydin, Elif2 (AUTHOR), Akman, Murat Emre1 (AUTHOR) |
| Source: | Journal of Chemical Sciences. Jun2025, Vol. 137 Issue 2, p1-9. 9p. |
| Subjects: | Methoxyethanol, Addition polymerization, Physical & theoretical chemistry, Methyl ether, Polyethylene glycol, Graft copolymers |
| Abstract: | Poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) (poly(VB-g-mPEG)) amphiphilic graft copolymer was obtained using 'click' chemistry of polyethylene glycol methyl ether propargyl (mPEG-propargyl) and terminal azido poly(4-vinylbenzyl chloride) (PVB-N3). Using 2,2′-azobis(2-methylpropionitrile) and 4-vinylbenzyl chloride, poly(4-vinylbenzyl chloride) (PVBC) was created by free-radical polymerization (FRP). PVB-N3 was obtained using PVBC and sodium azide. Propargyl chloride and polyethylene glycol methyl ether were reacted to form mPEG-propargyl. The 'click' chemical method created poly(VB-g-mPEG) amphiphilic graft copolymer by reacting PVB-N3 with mPEG-propargyl. 1H-NMR, DSC, FTIR and GPC characterized the products. The spectroscopic and thermal studies monitored that poly(VB-g-mPEG) was built via combining FRP and 'click' chemistry. The synthesis of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer was demonstrated in this study by using "click" chemistry and free radical polymerization. The synthesized products were characterized by using 1H-NMR, DSC, FT-IR, and GPC instruments. Here, we aimed to report on synthesizing the amphiphilic graft copolymer using "click" chemistry and free radical polymerization methods. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Chemical Sciences is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 184825645 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Synthesis and characterization of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer via free-radical polymerization and 'click' chemistry. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Savaş%2C+Bedrettin%22">Savaş, Bedrettin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Öztürk%2C+Temel%22">Öztürk, Temel</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> temelozturk@msn.com</i><br /><searchLink fieldCode="AR" term="%22Günaydin%2C+Elif%22">Günaydin, Elif</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Akman%2C+Murat+Emre%22">Akman, Murat Emre</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Chemical+Sciences%22">Journal of Chemical Sciences</searchLink>. Jun2025, Vol. 137 Issue 2, p1-9. 9p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Methoxyethanol%22">Methoxyethanol</searchLink><br /><searchLink fieldCode="DE" term="%22Addition+polymerization%22">Addition polymerization</searchLink><br /><searchLink fieldCode="DE" term="%22Physical+%26+theoretical+chemistry%22">Physical & theoretical chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Methyl+ether%22">Methyl ether</searchLink><br /><searchLink fieldCode="DE" term="%22Polyethylene+glycol%22">Polyethylene glycol</searchLink><br /><searchLink fieldCode="DE" term="%22Graft+copolymers%22">Graft copolymers</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) (poly(VB-g-mPEG)) amphiphilic graft copolymer was obtained using 'click' chemistry of polyethylene glycol methyl ether propargyl (mPEG-propargyl) and terminal azido poly(4-vinylbenzyl chloride) (PVB-N3). Using 2,2′-azobis(2-methylpropionitrile) and 4-vinylbenzyl chloride, poly(4-vinylbenzyl chloride) (PVBC) was created by free-radical polymerization (FRP). PVB-N3 was obtained using PVBC and sodium azide. Propargyl chloride and polyethylene glycol methyl ether were reacted to form mPEG-propargyl. The 'click' chemical method created poly(VB-g-mPEG) amphiphilic graft copolymer by reacting PVB-N3 with mPEG-propargyl. 1H-NMR, DSC, FTIR and GPC characterized the products. The spectroscopic and thermal studies monitored that poly(VB-g-mPEG) was built via combining FRP and 'click' chemistry. The synthesis of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer was demonstrated in this study by using "click" chemistry and free radical polymerization. The synthesized products were characterized by using 1H-NMR, DSC, FT-IR, and GPC instruments. Here, we aimed to report on synthesizing the amphiphilic graft copolymer using "click" chemistry and free radical polymerization methods. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Chemical Sciences is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s12039-025-02368-9 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 9 StartPage: 1 Subjects: – SubjectFull: Methoxyethanol Type: general – SubjectFull: Addition polymerization Type: general – SubjectFull: Physical & theoretical chemistry Type: general – SubjectFull: Methyl ether Type: general – SubjectFull: Polyethylene glycol Type: general – SubjectFull: Graft copolymers Type: general Titles: – TitleFull: Synthesis and characterization of poly(4-vinylbenzyl-graft-ethylene glycol methyl ether) amphiphilic graft copolymer via free-radical polymerization and 'click' chemistry. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Savaş, Bedrettin – PersonEntity: Name: NameFull: Öztürk, Temel – PersonEntity: Name: NameFull: Günaydin, Elif – PersonEntity: Name: NameFull: Akman, Murat Emre IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 06 Text: Jun2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 09743626 Numbering: – Type: volume Value: 137 – Type: issue Value: 2 Titles: – TitleFull: Journal of Chemical Sciences Type: main |
| ResultId | 1 |
