Fabrication, characterization and corrosion inhibition performance of sustainable metal-organic framework nanocomposite.

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Title: Fabrication, characterization and corrosion inhibition performance of sustainable metal-organic framework nanocomposite.
Authors: Aslam, Ruby1,2 (AUTHOR), Wang, Qihui1,3 (AUTHOR), Sun, Yi1 (AUTHOR), Yan, Zhitao1,4 (AUTHOR) yanzhitao@cqu.edu.cn
Source: Colloids & Surfaces A: Physicochemical & Engineering Aspects. Sep2025, Vol. 720, pN.PAG-N.PAG. 1p.
Subjects: Pipeline corrosion, Corrosion potential, Metal-organic frameworks, Functional groups, Nanocomposite materials, Corrosion inhibitors
Abstract: The objective of this study is to develop novel and sustainable corrosion inhibitors, which is an important and challenging task in corrosion management. This study reports the fabrication of a novel nanocomposite (NC) through the functionalization of an iron metal-organic framework (MOF) using cumin-derived carbon dots (CD). The MOF@CD NC was tested as a novel corrosion inhibitor for Q235B steel in 1.0 M HCl solution. The corrosion inhibition potential was significantly improved through the functionalization process and gravimetric tests showed an inhibition efficiency of about 98 % after 72 h immersion at 25 °C with an inhibitor concentration of 100 mg/L. FT-IR and XPS analysis indicated that binding and adsorption were achieved through functional groups of MOF@CD NC. SEM and AFM studies showed significant surface damage reduction and supported the formation of a powerful protective layer in the presence of inhibitor. This research represents a significant step forward in corrosion protection technology by introducing a new class of materials with excellent performance at low concentrations, offering a promising solution for industrial applications. [Display omitted] • The corrosion inhibition behavior of carbon dot modified Fe-MOF was tested. • MOF@CD reduced the dissolution of Q235B steel in acidic media. • Metal/inhibitor interaction was explored through FT-IR/XPS studies. • Protective film formation was explored through AFM/SEM studies. [ABSTRACT FROM AUTHOR]
Copyright of Colloids & Surfaces A: Physicochemical & Engineering Aspects is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 185599406
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Label: Title
  Group: Ti
  Data: Fabrication, characterization and corrosion inhibition performance of sustainable metal-organic framework nanocomposite.
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  Data: <searchLink fieldCode="AR" term="%22Aslam%2C+Ruby%22">Aslam, Ruby</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Qihui%22">Wang, Qihui</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sun%2C+Yi%22">Sun, Yi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yan%2C+Zhitao%22">Yan, Zhitao</searchLink><relatesTo>1,4</relatesTo> (AUTHOR)<i> yanzhitao@cqu.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Colloids+%26+Surfaces+A%3A+Physicochemical+%26+Engineering+Aspects%22">Colloids & Surfaces A: Physicochemical & Engineering Aspects</searchLink>. Sep2025, Vol. 720, pN.PAG-N.PAG. 1p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Pipeline+corrosion%22">Pipeline corrosion</searchLink><br /><searchLink fieldCode="DE" term="%22Corrosion+potential%22">Corrosion potential</searchLink><br /><searchLink fieldCode="DE" term="%22Metal-organic+frameworks%22">Metal-organic frameworks</searchLink><br /><searchLink fieldCode="DE" term="%22Functional+groups%22">Functional groups</searchLink><br /><searchLink fieldCode="DE" term="%22Nanocomposite+materials%22">Nanocomposite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Corrosion+inhibitors%22">Corrosion inhibitors</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The objective of this study is to develop novel and sustainable corrosion inhibitors, which is an important and challenging task in corrosion management. This study reports the fabrication of a novel nanocomposite (NC) through the functionalization of an iron metal-organic framework (MOF) using cumin-derived carbon dots (CD). The MOF@CD NC was tested as a novel corrosion inhibitor for Q235B steel in 1.0 M HCl solution. The corrosion inhibition potential was significantly improved through the functionalization process and gravimetric tests showed an inhibition efficiency of about 98 % after 72 h immersion at 25 °C with an inhibitor concentration of 100 mg/L. FT-IR and XPS analysis indicated that binding and adsorption were achieved through functional groups of MOF@CD NC. SEM and AFM studies showed significant surface damage reduction and supported the formation of a powerful protective layer in the presence of inhibitor. This research represents a significant step forward in corrosion protection technology by introducing a new class of materials with excellent performance at low concentrations, offering a promising solution for industrial applications. [Display omitted] • The corrosion inhibition behavior of carbon dot modified Fe-MOF was tested. • MOF@CD reduced the dissolution of Q235B steel in acidic media. • Metal/inhibitor interaction was explored through FT-IR/XPS studies. • Protective film formation was explored through AFM/SEM studies. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Colloids & Surfaces A: Physicochemical & Engineering Aspects is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.colsurfa.2025.137095
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      – Code: eng
        Text: English
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        PageCount: 1
        StartPage: N.PAG
    Subjects:
      – SubjectFull: Pipeline corrosion
        Type: general
      – SubjectFull: Corrosion potential
        Type: general
      – SubjectFull: Metal-organic frameworks
        Type: general
      – SubjectFull: Functional groups
        Type: general
      – SubjectFull: Nanocomposite materials
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      – SubjectFull: Corrosion inhibitors
        Type: general
    Titles:
      – TitleFull: Fabrication, characterization and corrosion inhibition performance of sustainable metal-organic framework nanocomposite.
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            NameFull: Aslam, Ruby
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            NameFull: Wang, Qihui
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            NameFull: Sun, Yi
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            NameFull: Yan, Zhitao
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            – D: 05
              M: 09
              Text: Sep2025
              Type: published
              Y: 2025
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              Value: 720
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            – TitleFull: Colloids & Surfaces A: Physicochemical & Engineering Aspects
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