Graphene Oxide-Doped CNT Membrane for Dye Adsorption.

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Title: Graphene Oxide-Doped CNT Membrane for Dye Adsorption.
Authors: Baratta, Mariafrancesca1 (AUTHOR) fiore.nicoletta@unical.it, Nicoletta, Fiore Pasquale2 (AUTHOR), De Filpo, Giovanni1 (AUTHOR)
Source: Nanomaterials (2079-4991). Jun2025, Vol. 15 Issue 11, p782. 18p.
Subjects: Malachite green, Basic dyes, Water pollution, Rhodamine B, Graphene oxide, Gentian violet
Abstract: Recently, graphene oxide (GO) has been largely investigated as a potential adsorbent towards dyes. However, the major obstacle to its full employment is linked to its natural powder consistence, which greatly complexifies the operations of recovery and reuse. With the aim to overcome this issue, the present work reports on the design of GO-modified carbon nanotubes buckypapers (BPs), in which the main component, GO, is entirely entrapped in the BP grid generated by CNTs for the double purpose of (a) increasing adsorption performance of GO-BPs and (b) ensure a fast process of regeneration and reuse. Adsorption experiments were performed towards several dyes: Acid Blue 29 (AB29), Crystal Violet (CV), Eosyn Y (EY), Malachite Green (MG), and Rhodamine B (RB) (Ci = 50 ppm, pH = 6). Results demonstrated that adsorption is strictly dependent on the charge occurring both on GO-BP and dye surfaces, observing great adsorption capacities towards MG (493.44 mg g−1), RB (467.35 mg g−1), and CV (374.53 mg g−1), due to the best coupling of dye cationic form with negative GO-BP surface. Adsorption isotherms revealed that dyes capture onto GO-BPs is thermodynamically favored (ΔG < 0), becoming more negative at 313 K. Kinetic studies evidenced that the process can be described through a pseudo-first-order model, with MG, RB, and CV exhibiting the highest values of k1. In view of these results, the following trend in GO-BP adsorption performance has been derived: MG ≈ RB > CV > AB29 > EY. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Graphene Oxide-Doped CNT Membrane for Dye Adsorption.
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  Label: Authors
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  Data: &lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Baratta%2C+Mariafrancesca%22&quot;&gt;Baratta, Mariafrancesca&lt;/searchLink&gt;&lt;relatesTo&gt;1&lt;/relatesTo&gt; (AUTHOR)&lt;i&gt; fiore.nicoletta@unical.it&lt;/i&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22Nicoletta%2C+Fiore+Pasquale%22&quot;&gt;Nicoletta, Fiore Pasquale&lt;/searchLink&gt;&lt;relatesTo&gt;2&lt;/relatesTo&gt; (AUTHOR)&lt;br /&gt;&lt;searchLink fieldCode=&quot;AR&quot; term=&quot;%22De+Filpo%2C+Giovanni%22&quot;&gt;De Filpo, Giovanni&lt;/searchLink&gt;&lt;relatesTo&gt;1&lt;/relatesTo&gt; (AUTHOR)
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  Data: &lt;searchLink fieldCode=&quot;JN&quot; term=&quot;%22Nanomaterials+%282079-4991%29%22&quot;&gt;Nanomaterials (2079-4991)&lt;/searchLink&gt;. Jun2025, Vol. 15 Issue 11, p782. 18p.
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  Data: &lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Malachite+green%22&quot;&gt;Malachite green&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Basic+dyes%22&quot;&gt;Basic dyes&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Water+pollution%22&quot;&gt;Water pollution&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Rhodamine+B%22&quot;&gt;Rhodamine B&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Graphene+oxide%22&quot;&gt;Graphene oxide&lt;/searchLink&gt;&lt;br /&gt;&lt;searchLink fieldCode=&quot;DE&quot; term=&quot;%22Gentian+violet%22&quot;&gt;Gentian violet&lt;/searchLink&gt;
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Recently, graphene oxide (GO) has been largely investigated as a potential adsorbent towards dyes. However, the major obstacle to its full employment is linked to its natural powder consistence, which greatly complexifies the operations of recovery and reuse. With the aim to overcome this issue, the present work reports on the design of GO-modified carbon nanotubes buckypapers (BPs), in which the main component, GO, is entirely entrapped in the BP grid generated by CNTs for the double purpose of (a) increasing adsorption performance of GO-BPs and (b) ensure a fast process of regeneration and reuse. Adsorption experiments were performed towards several dyes: Acid Blue 29 (AB29), Crystal Violet (CV), Eosyn Y (EY), Malachite Green (MG), and Rhodamine B (RB) (Ci = 50 ppm, pH = 6). Results demonstrated that adsorption is strictly dependent on the charge occurring both on GO-BP and dye surfaces, observing great adsorption capacities towards MG (493.44 mg g−1), RB (467.35 mg g−1), and CV (374.53 mg g−1), due to the best coupling of dye cationic form with negative GO-BP surface. Adsorption isotherms revealed that dyes capture onto GO-BPs is thermodynamically favored (ΔG &lt; 0), becoming more negative at 313 K. Kinetic studies evidenced that the process can be described through a pseudo-first-order model, with MG, RB, and CV exhibiting the highest values of k1. In view of these results, the following trend in GO-BP adsorption performance has been derived: MG ≈ RB &gt; CV &gt; AB29 &gt; EY. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: &lt;i&gt;Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder&#39;s express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.&lt;/i&gt; (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.3390/nano15110782
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 18
        StartPage: 782
    Subjects:
      – SubjectFull: Malachite green
        Type: general
      – SubjectFull: Basic dyes
        Type: general
      – SubjectFull: Water pollution
        Type: general
      – SubjectFull: Rhodamine B
        Type: general
      – SubjectFull: Graphene oxide
        Type: general
      – SubjectFull: Gentian violet
        Type: general
    Titles:
      – TitleFull: Graphene Oxide-Doped CNT Membrane for Dye Adsorption.
        Type: main
  BibRelationships:
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      – PersonEntity:
          Name:
            NameFull: Baratta, Mariafrancesca
      – PersonEntity:
          Name:
            NameFull: Nicoletta, Fiore Pasquale
      – PersonEntity:
          Name:
            NameFull: De Filpo, Giovanni
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          Dates:
            – D: 01
              M: 06
              Text: Jun2025
              Type: published
              Y: 2025
          Identifiers:
            – Type: issn-print
              Value: 20794991
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              Value: 15
            – Type: issue
              Value: 11
          Titles:
            – TitleFull: Nanomaterials (2079-4991)
              Type: main
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