The Engineered Synthesis and Enhancement of Nitrogen and Chlorine Co-Doped Fluorescent Carbon Dots for the Sensitive Detection of Quercetin.

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Title: The Engineered Synthesis and Enhancement of Nitrogen and Chlorine Co-Doped Fluorescent Carbon Dots for the Sensitive Detection of Quercetin.
Authors: Jiao, Yuan1,2,3 (AUTHOR), Miao, Xuewen2,3 (AUTHOR), Wang, Lizhang1,3 (AUTHOR) 16696243382@139.com, Hong, Shasha4 (AUTHOR), Gao, Yifang1 (AUTHOR) gaoyifang@tyut.edu.cn, Wang, Xin2 (AUTHOR)
Source: Materials (1996-1944). Jun2025, Vol. 18 Issue 11, p2669. 11p.
Subjects: Complex compounds, Complex matrices, Environmental security, Fluorescence quenching, Charge exchange
Abstract: Flavonoid alcohols, particularly quercetin, as emerging antioxidants, demand advanced detection methodologies to comprehensively explore and evaluate their potential environmental and health risks. In this study, nitrogen–chlorine co-doped carbon dots (N, Cl-CDs), featuring an extended wavelength emission at 625 nm, were synthesized via the reaction of 4-chloro-1,2-phenylenediamine with polyethyleneimine. The engineered N, Cl-CDs exhibit superior photostability, exceptional aqueous dispersibility, and anti-interference capability in complex matrices. Leveraging static electron transfer mechanisms, the N, Cl-CDs demonstrate selective fluorescence quenching toward quercetin with an ultralow detection limit of 60.42 nM. Validation through rigorous spiked recovery assays in apple peel and red wine has been proficiently performed with satisfactory accuracy, highlighting the significant prospect of the constructed N, Cl-CDs for quercetin identification in real samples. This study provides valuable insights into the analytical determination of flavonoid compounds in complex environmental matrices, highlighting the potential of N, Cl-CDs for environmental and food safety monitoring. [ABSTRACT FROM AUTHOR]
Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 185869831
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  Label: Title
  Group: Ti
  Data: The Engineered Synthesis and Enhancement of Nitrogen and Chlorine Co-Doped Fluorescent Carbon Dots for the Sensitive Detection of Quercetin.
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  Data: <searchLink fieldCode="AR" term="%22Jiao%2C+Yuan%22">Jiao, Yuan</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Miao%2C+Xuewen%22">Miao, Xuewen</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Wang%2C+Lizhang%22">Wang, Lizhang</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<i> 16696243382@139.com</i><br /><searchLink fieldCode="AR" term="%22Hong%2C+Shasha%22">Hong, Shasha</searchLink><relatesTo>4</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gao%2C+Yifang%22">Gao, Yifang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> gaoyifang@tyut.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Xin%22">Wang, Xin</searchLink><relatesTo>2</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+%281996-1944%29%22">Materials (1996-1944)</searchLink>. Jun2025, Vol. 18 Issue 11, p2669. 11p.
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  Data: <searchLink fieldCode="DE" term="%22Complex+compounds%22">Complex compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Complex+matrices%22">Complex matrices</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+security%22">Environmental security</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescence+quenching%22">Fluorescence quenching</searchLink><br /><searchLink fieldCode="DE" term="%22Charge+exchange%22">Charge exchange</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Flavonoid alcohols, particularly quercetin, as emerging antioxidants, demand advanced detection methodologies to comprehensively explore and evaluate their potential environmental and health risks. In this study, nitrogen–chlorine co-doped carbon dots (N, Cl-CDs), featuring an extended wavelength emission at 625 nm, were synthesized via the reaction of 4-chloro-1,2-phenylenediamine with polyethyleneimine. The engineered N, Cl-CDs exhibit superior photostability, exceptional aqueous dispersibility, and anti-interference capability in complex matrices. Leveraging static electron transfer mechanisms, the N, Cl-CDs demonstrate selective fluorescence quenching toward quercetin with an ultralow detection limit of 60.42 nM. Validation through rigorous spiked recovery assays in apple peel and red wine has been proficiently performed with satisfactory accuracy, highlighting the significant prospect of the constructed N, Cl-CDs for quercetin identification in real samples. This study provides valuable insights into the analytical determination of flavonoid compounds in complex environmental matrices, highlighting the potential of N, Cl-CDs for environmental and food safety monitoring. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.3390/ma18112669
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      – Code: eng
        Text: English
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        PageCount: 11
        StartPage: 2669
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      – SubjectFull: Complex compounds
        Type: general
      – SubjectFull: Complex matrices
        Type: general
      – SubjectFull: Environmental security
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      – SubjectFull: Fluorescence quenching
        Type: general
      – SubjectFull: Charge exchange
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      – TitleFull: The Engineered Synthesis and Enhancement of Nitrogen and Chlorine Co-Doped Fluorescent Carbon Dots for the Sensitive Detection of Quercetin.
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            NameFull: Jiao, Yuan
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            NameFull: Miao, Xuewen
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            NameFull: Wang, Lizhang
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            NameFull: Hong, Shasha
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            NameFull: Gao, Yifang
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            NameFull: Wang, Xin
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            – D: 01
              M: 06
              Text: Jun2025
              Type: published
              Y: 2025
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