Reducing the Heterogeneity in Tensile Strength in the Coir (Cocos nucifera)-Epoxy Composite Through Enhancing Surface Quality and Maintaining Longitudinal Integrity.

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Title: Reducing the Heterogeneity in Tensile Strength in the Coir (Cocos nucifera)-Epoxy Composite Through Enhancing Surface Quality and Maintaining Longitudinal Integrity.
Authors: Mishra, Shashank1 (AUTHOR) Sha07mis@gmail.com, Parashar, Vishal1 (AUTHOR) vishpara79@gmail.com
Source: Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. ). Jun2025, Vol. 50 Issue 12, p8975-8993. 19p.
Subjects: Coconut palm, Optical microscopes, Coir, Synthetic fibers, Scanning electron microscopes, Hydrophilic interactions, Lignins
Abstract: Coir fibers (Cocos nucifera) are strong and sustainable alternative to hazardous synthetic fiber; however, there are certain challenges that has to be dealt with, in order to fully exploit the strength of these fiber. These challenges include hydrophilic and hygroscopic behavior of coir fiber, poor fiber–matrix interface, and the twirling of fibers. In this work, these challenges are resolved in different stages through various surface modification techniques, like alkali treatment for reduced hydrophilicity, silane coating for enhanced interface, and straightening to reduce fiber twirling. FTIR spectroscopy reveals the removal of hemicellulose, lignin, wax, etc. post-alkali treatment, and the following silane treatment show development of new Si–O–Si bonds. Their influence on tensile strength of composite is monitored after every step. Hand-layup methodology is employed for composite fabrication of 25% (w/w) fibers with matrix epoxy LY556/HY951. Developed composite includes untreated coir epoxy (UCE), alkali-treated coir epoxy, alkali-silane coir epoxy, and alkali-silane-straightened coir epoxy (ASSCE). Tensile behavior and thermogravimetric analysis (TGA) were examined. The results show 41% rise in the tensile strength from 29 MPa for UCE specimens to 41 MPa for ASSCE. In addition, there was 70% reduction in the standard deviation for ASSCE specimens. Analysis of variance shows that these modifications produce significant results. TGA test reveals that coir epoxy composites degrade on and above 250 ℃, the untreated coir epoxy shows slightly more thermal stability than alkali-silane composite, followed by alkali treated. The morphology of failed specimens examined under an optical microscope and scanning electron microscope reveals details like fiber cross section, microfibrils, and fiber rupture. [ABSTRACT FROM AUTHOR]
Copyright of Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. ) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Reducing the Heterogeneity in Tensile Strength in the Coir (Cocos nucifera)-Epoxy Composite Through Enhancing Surface Quality and Maintaining Longitudinal Integrity.
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  Data: <searchLink fieldCode="DE" term="%22Coconut+palm%22">Coconut palm</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+microscopes%22">Optical microscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Coir%22">Coir</searchLink><br /><searchLink fieldCode="DE" term="%22Synthetic+fibers%22">Synthetic fibers</searchLink><br /><searchLink fieldCode="DE" term="%22Scanning+electron+microscopes%22">Scanning electron microscopes</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrophilic+interactions%22">Hydrophilic interactions</searchLink><br /><searchLink fieldCode="DE" term="%22Lignins%22">Lignins</searchLink>
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  Data: Coir fibers (Cocos nucifera) are strong and sustainable alternative to hazardous synthetic fiber; however, there are certain challenges that has to be dealt with, in order to fully exploit the strength of these fiber. These challenges include hydrophilic and hygroscopic behavior of coir fiber, poor fiber–matrix interface, and the twirling of fibers. In this work, these challenges are resolved in different stages through various surface modification techniques, like alkali treatment for reduced hydrophilicity, silane coating for enhanced interface, and straightening to reduce fiber twirling. FTIR spectroscopy reveals the removal of hemicellulose, lignin, wax, etc. post-alkali treatment, and the following silane treatment show development of new Si–O–Si bonds. Their influence on tensile strength of composite is monitored after every step. Hand-layup methodology is employed for composite fabrication of 25% (w/w) fibers with matrix epoxy LY556/HY951. Developed composite includes untreated coir epoxy (UCE), alkali-treated coir epoxy, alkali-silane coir epoxy, and alkali-silane-straightened coir epoxy (ASSCE). Tensile behavior and thermogravimetric analysis (TGA) were examined. The results show 41% rise in the tensile strength from 29 MPa for UCE specimens to 41 MPa for ASSCE. In addition, there was 70% reduction in the standard deviation for ASSCE specimens. Analysis of variance shows that these modifications produce significant results. TGA test reveals that coir epoxy composites degrade on and above 250 ℃, the untreated coir epoxy shows slightly more thermal stability than alkali-silane composite, followed by alkali treated. The morphology of failed specimens examined under an optical microscope and scanning electron microscope reveals details like fiber cross section, microfibrils, and fiber rupture. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Arabian Journal for Science & Engineering (Springer Science & Business Media B.V. ) is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s13369-024-09331-9
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        Text: English
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        PageCount: 19
        StartPage: 8975
    Subjects:
      – SubjectFull: Coconut palm
        Type: general
      – SubjectFull: Optical microscopes
        Type: general
      – SubjectFull: Coir
        Type: general
      – SubjectFull: Synthetic fibers
        Type: general
      – SubjectFull: Scanning electron microscopes
        Type: general
      – SubjectFull: Hydrophilic interactions
        Type: general
      – SubjectFull: Lignins
        Type: general
    Titles:
      – TitleFull: Reducing the Heterogeneity in Tensile Strength in the Coir (Cocos nucifera)-Epoxy Composite Through Enhancing Surface Quality and Maintaining Longitudinal Integrity.
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              M: 06
              Text: Jun2025
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              Y: 2025
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