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Developments in the Catalytic Cationic Polymerization of Olefins.

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Title: Developments in the Catalytic Cationic Polymerization of Olefins.
Authors: Lewis, Stewart P.1 (AUTHOR) slewis@innovscience.com
Source: Topics in Catalysis. Jun2025, Vol. 68 Issue 11, p1192-1215. 24p.
Subjects: Catalytic polymerization, Addition polymerization, Small molecules, Alkylation, Polymerization
Abstract: This article describes research where the main goal is the development of cationic polymerization systems for olefins that operate in a catalytic manner. Moreover, these chemistries are fine-tuned so that they operate in a green manner but are still conducive for commercialization. Although a portion of this article constitutes a brief review of previously published work further details on those investigations are provided here for the first time in the peer-reviewed literature in addition to new unpublished studies. The reader not specializing in polymers should keep in mind that much of the chemistry described in this document overlaps with small molecule electrophilic transformations (e.g., cracking, alkylation) and thus can be applied to endeavors other than polymerization. [ABSTRACT FROM AUTHOR]
Copyright of Topics in Catalysis is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Developments in the Catalytic Cationic Polymerization of Olefins.
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  Data: This article describes research where the main goal is the development of cationic polymerization systems for olefins that operate in a catalytic manner. Moreover, these chemistries are fine-tuned so that they operate in a green manner but are still conducive for commercialization. Although a portion of this article constitutes a brief review of previously published work further details on those investigations are provided here for the first time in the peer-reviewed literature in addition to new unpublished studies. The reader not specializing in polymers should keep in mind that much of the chemistry described in this document overlaps with small molecule electrophilic transformations (e.g., cracking, alkylation) and thus can be applied to endeavors other than polymerization. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Topics in Catalysis is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1007/s11244-024-02039-y
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        Text: English
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      – SubjectFull: Catalytic polymerization
        Type: general
      – SubjectFull: Addition polymerization
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      – SubjectFull: Small molecules
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      – SubjectFull: Alkylation
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      – SubjectFull: Polymerization
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      – TitleFull: Developments in the Catalytic Cationic Polymerization of Olefins.
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              Text: Jun2025
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