High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles.
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| Title: | High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles. |
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| Authors: | Bao, Jingjing1 (AUTHOR) baojj@dgpt.edu.cn, Ji, Yang1 (AUTHOR), Hong, Xiaoting1 (AUTHOR), Lu, Ye1 (AUTHOR) |
| Source: | Journal of Dispersion Science & Technology. 2025, Vol. 46 Issue 9, p1389-1395. 7p. |
| Subjects: | Electrochemiluminescence, Delayed fluorescence, Nanoparticles, Organic solvents |
| Abstract: | In this paper, the synthesis of thermally activated delayed fluorescence nanoparticles (TADF NPs) is reported using a micelle-confined soft template self-assembly. With vaporing organic solvent in this system, TADF NPs with a diameter of about 500 nm were obtained. The main advantage is to nanoencapsulate these TADF molecules with an amphiphilic polymer. As demonstrated, air-stable nanoparticles with efficient TADF properties are realized in water. The application of these as-prepared TADF NPs as a kind of alternative electrochemiluminescent (ECL) material has also been investigated. The triplet-harvesting ability combined with excellent redox properties endows as-prepared TADF NPs with a high ECL efficiency of 10.82%, which is a marked enhancement over previous results. Therefore, ECL materials with similar behavior to reported TADF materials in this article are desirable in applications such as ECL sensing, imaging, and light-emitting devices. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | In this paper, the synthesis of thermally activated delayed fluorescence nanoparticles (TADF NPs) is reported using a micelle-confined soft template self-assembly. With vaporing organic solvent in this system, TADF NPs with a diameter of about 500 nm were obtained. The main advantage is to nanoencapsulate these TADF molecules with an amphiphilic polymer. As demonstrated, air-stable nanoparticles with efficient TADF properties are realized in water. The application of these as-prepared TADF NPs as a kind of alternative electrochemiluminescent (ECL) material has also been investigated. The triplet-harvesting ability combined with excellent redox properties endows as-prepared TADF NPs with a high ECL efficiency of 10.82%, which is a marked enhancement over previous results. Therefore, ECL materials with similar behavior to reported TADF materials in this article are desirable in applications such as ECL sensing, imaging, and light-emitting devices. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 01932691 |
| DOI: | 10.1080/01932691.2024.2327425 |