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High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles.

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Title: High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles.
Authors: Bao, Jingjing1 (AUTHOR) baojj@dgpt.edu.cn, Ji, Yang1 (AUTHOR), Hong, Xiaoting1 (AUTHOR), Lu, Ye1 (AUTHOR)
Source: Journal of Dispersion Science & Technology. 2025, Vol. 46 Issue 9, p1389-1395. 7p.
Subjects: Electrochemiluminescence, Delayed fluorescence, Nanoparticles, Organic solvents
Abstract: In this paper, the synthesis of thermally activated delayed fluorescence nanoparticles (TADF NPs) is reported using a micelle-confined soft template self-assembly. With vaporing organic solvent in this system, TADF NPs with a diameter of about 500 nm were obtained. The main advantage is to nanoencapsulate these TADF molecules with an amphiphilic polymer. As demonstrated, air-stable nanoparticles with efficient TADF properties are realized in water. The application of these as-prepared TADF NPs as a kind of alternative electrochemiluminescent (ECL) material has also been investigated. The triplet-harvesting ability combined with excellent redox properties endows as-prepared TADF NPs with a high ECL efficiency of 10.82%, which is a marked enhancement over previous results. Therefore, ECL materials with similar behavior to reported TADF materials in this article are desirable in applications such as ECL sensing, imaging, and light-emitting devices. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Dispersion Science & Technology is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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DbLabel: Engineering Source
An: 186345415
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PubTypeId: academicJournal
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  Label: Title
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  Data: High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles.
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  Data: <searchLink fieldCode="AR" term="%22Bao%2C+Jingjing%22">Bao, Jingjing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> baojj@dgpt.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Ji%2C+Yang%22">Ji, Yang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hong%2C+Xiaoting%22">Hong, Xiaoting</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lu%2C+Ye%22">Lu, Ye</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Dispersion+Science+%26+Technology%22">Journal of Dispersion Science & Technology</searchLink>. 2025, Vol. 46 Issue 9, p1389-1395. 7p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Electrochemiluminescence%22">Electrochemiluminescence</searchLink><br /><searchLink fieldCode="DE" term="%22Delayed+fluorescence%22">Delayed fluorescence</searchLink><br /><searchLink fieldCode="DE" term="%22Nanoparticles%22">Nanoparticles</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+solvents%22">Organic solvents</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this paper, the synthesis of thermally activated delayed fluorescence nanoparticles (TADF NPs) is reported using a micelle-confined soft template self-assembly. With vaporing organic solvent in this system, TADF NPs with a diameter of about 500 nm were obtained. The main advantage is to nanoencapsulate these TADF molecules with an amphiphilic polymer. As demonstrated, air-stable nanoparticles with efficient TADF properties are realized in water. The application of these as-prepared TADF NPs as a kind of alternative electrochemiluminescent (ECL) material has also been investigated. The triplet-harvesting ability combined with excellent redox properties endows as-prepared TADF NPs with a high ECL efficiency of 10.82%, which is a marked enhancement over previous results. Therefore, ECL materials with similar behavior to reported TADF materials in this article are desirable in applications such as ECL sensing, imaging, and light-emitting devices. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Dispersion Science & Technology is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1080/01932691.2024.2327425
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 7
        StartPage: 1389
    Subjects:
      – SubjectFull: Electrochemiluminescence
        Type: general
      – SubjectFull: Delayed fluorescence
        Type: general
      – SubjectFull: Nanoparticles
        Type: general
      – SubjectFull: Organic solvents
        Type: general
    Titles:
      – TitleFull: High-performance electrochemiluminescence of self-assembled multi-resonance thermally activated delayed fluorescence nanoparticles.
        Type: main
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            NameFull: Bao, Jingjing
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            NameFull: Ji, Yang
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            NameFull: Hong, Xiaoting
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            NameFull: Lu, Ye
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          Dates:
            – D: 01
              M: 08
              Text: 2025
              Type: published
              Y: 2025
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              Value: 46
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              Value: 9
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            – TitleFull: Journal of Dispersion Science & Technology
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