Microbial-induced structural changes in non-stoichiometric magnetite via radioanalytical methods.

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Title: Microbial-induced structural changes in non-stoichiometric magnetite via radioanalytical methods.
Authors: Vyhnáleková, Silvia1 (AUTHOR) vyhnalekova2@uniba.sk, Miglierini, Marcel B.2,3 (AUTHOR), Cesnek, Martin3 (AUTHOR), Štefánik, Milan3,4 (AUTHOR), Matúš, Peter1 (AUTHOR)
Source: Journal of Radioanalytical & Nuclear Chemistry. Jun2025, Vol. 334 Issue 6, p4179-4188. 10p.
Subjects: Nuclear activation analysis, Aspergillus niger, Maghemite, Magnetite, Magnetic properties
Abstract: Structural alterations in non-stoichiometric magnetite induced by microorganisms are studied by nuclear methods. Magnetite samples were exposed to fungal strain known for its immobilization capabilities. Neutron activation analysis identified iron as the dominant element. The presence of maghemite in non-stoichiometric magnetite complicates the determination of iron sites by Mössbauer spectrometry. Mössbauer spectra recorded at 4.2 K display overlapping lines corresponding to tetrahedral and octahedral iron sites. Application of external magnetic field of 6 T improved the spectral resolution and revealed a presence of distinct sextets. Interaction with Aspergillus niger did not notably affect magnetite´s magnetic properties, indicating its stability. [ABSTRACT FROM AUTHOR]
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Abstract:Structural alterations in non-stoichiometric magnetite induced by microorganisms are studied by nuclear methods. Magnetite samples were exposed to fungal strain known for its immobilization capabilities. Neutron activation analysis identified iron as the dominant element. The presence of maghemite in non-stoichiometric magnetite complicates the determination of iron sites by Mössbauer spectrometry. Mössbauer spectra recorded at 4.2 K display overlapping lines corresponding to tetrahedral and octahedral iron sites. Application of external magnetic field of 6 T improved the spectral resolution and revealed a presence of distinct sextets. Interaction with Aspergillus niger did not notably affect magnetite´s magnetic properties, indicating its stability. [ABSTRACT FROM AUTHOR]
ISSN:02365731
DOI:10.1007/s10967-024-09863-2