Research on the Effect of Oxygen Ions on the Coordination Structure and Electrochemical Behavior of Titanium Ions in NaCl-KCl Melt.
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| Title: | Research on the Effect of Oxygen Ions on the Coordination Structure and Electrochemical Behavior of Titanium Ions in NaCl-KCl Melt. |
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| Authors: | Li, Shaolong1,2 (AUTHOR) 13237641651@163.com, Mao, Peizhu2 (AUTHOR), Mu, Tianzhu1,3 (AUTHOR), Zhu, Fuxing1 (AUTHOR), Li, Shengwei2,3 (AUTHOR) |
| Source: | Materials (1996-1944). Jul2025, Vol. 18 Issue 13, p3161. 11p. |
| Subjects: | Titanium compounds, Electrochemical analysis, Chemical structure, Titanium chlorides, Anions, Spectrometry, Fused salts, Cyclic voltammetry |
| Abstract: | Presently, extensive research has been conducted on the electrochemical behavior of titanium ions in molten salt, especially in relation to titanium fluoride coordination. However, there is limited research on the coordination between titanium and oxygen. Consequently, this research delved into the influence of oxygen ions on the electrochemical behavior and coordination properties of titanium ions through the utilization of both electrochemical and spectroscopy techniques. The study involved the use of cyclic voltammetry (CV), square wave voltammetry (SWV), and the open-circuit potential (OCP) method to explore the electrochemical properties of titanium ions at different titanium-oxygen ratios. Furthermore, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were applied to assess the presence of titanium ions in molten salt and the coordination structure of titanium ions and anions in molten salts, respectively. The results demonstrate that with an increase in oxygen ion content, chloride ions are gradually replaced by oxygen ions, forming TiOxClym− complexes. [ABSTRACT FROM AUTHOR] |
| Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 186596924 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Research on the Effect of Oxygen Ions on the Coordination Structure and Electrochemical Behavior of Titanium Ions in NaCl-KCl Melt. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Li%2C+Shaolong%22">Li, Shaolong</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> 13237641651@163.com</i><br /><searchLink fieldCode="AR" term="%22Mao%2C+Peizhu%22">Mao, Peizhu</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Mu%2C+Tianzhu%22">Mu, Tianzhu</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhu%2C+Fuxing%22">Zhu, Fuxing</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Shengwei%22">Li, Shengwei</searchLink><relatesTo>2,3</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Materials+%281996-1944%29%22">Materials (1996-1944)</searchLink>. Jul2025, Vol. 18 Issue 13, p3161. 11p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Titanium+compounds%22">Titanium compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+analysis%22">Electrochemical analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+structure%22">Chemical structure</searchLink><br /><searchLink fieldCode="DE" term="%22Titanium+chlorides%22">Titanium chlorides</searchLink><br /><searchLink fieldCode="DE" term="%22Anions%22">Anions</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrometry%22">Spectrometry</searchLink><br /><searchLink fieldCode="DE" term="%22Fused+salts%22">Fused salts</searchLink><br /><searchLink fieldCode="DE" term="%22Cyclic+voltammetry%22">Cyclic voltammetry</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Presently, extensive research has been conducted on the electrochemical behavior of titanium ions in molten salt, especially in relation to titanium fluoride coordination. However, there is limited research on the coordination between titanium and oxygen. Consequently, this research delved into the influence of oxygen ions on the electrochemical behavior and coordination properties of titanium ions through the utilization of both electrochemical and spectroscopy techniques. The study involved the use of cyclic voltammetry (CV), square wave voltammetry (SWV), and the open-circuit potential (OCP) method to explore the electrochemical properties of titanium ions at different titanium-oxygen ratios. Furthermore, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy were applied to assess the presence of titanium ions in molten salt and the coordination structure of titanium ions and anions in molten salts, respectively. The results demonstrate that with an increase in oxygen ion content, chloride ions are gradually replaced by oxygen ions, forming TiOxClym− complexes. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Materials (1996-1944) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.3390/ma18133161 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 11 StartPage: 3161 Subjects: – SubjectFull: Titanium compounds Type: general – SubjectFull: Electrochemical analysis Type: general – SubjectFull: Chemical structure Type: general – SubjectFull: Titanium chlorides Type: general – SubjectFull: Anions Type: general – SubjectFull: Spectrometry Type: general – SubjectFull: Fused salts Type: general – SubjectFull: Cyclic voltammetry Type: general Titles: – TitleFull: Research on the Effect of Oxygen Ions on the Coordination Structure and Electrochemical Behavior of Titanium Ions in NaCl-KCl Melt. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Li, Shaolong – PersonEntity: Name: NameFull: Mao, Peizhu – PersonEntity: Name: NameFull: Mu, Tianzhu – PersonEntity: Name: NameFull: Zhu, Fuxing – PersonEntity: Name: NameFull: Li, Shengwei IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: Jul2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 19961944 Numbering: – Type: volume Value: 18 – Type: issue Value: 13 Titles: – TitleFull: Materials (1996-1944) Type: main |
| ResultId | 1 |
