Heterogeneous bimetallic Ni-Mo oxide and C3N4 conjugation for boosted photocatalytic degradation of rhodamine B dye.

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Title: Heterogeneous bimetallic Ni-Mo oxide and C3N4 conjugation for boosted photocatalytic degradation of rhodamine B dye.
Authors: Jery, Atef El1 (AUTHOR), Aldrdery, Moutaz1 (AUTHOR), Hossain, Mohammad Ashraf2 (AUTHOR), Hossain, Ismail3 (AUTHOR), Murrari, Raj Moohan4 (AUTHOR), Kumar, Ome Parkash5 (AUTHOR) okumar112@gmail.com, Jamshaid, Muhammad5 (AUTHOR) jimmichemist@gmail.com
Source: Journal of Materials Science: Materials in Electronics. Jul2025, Vol. 36 Issue 21, p1-16. 16p.
Abstract: Currently, there has been considerable interest in developing heterojunction materials for the removal of dyes. However, there is a bottleneck in creating an impressive photocatalyst that can degrade organic pollutants propelled by visible light. The integration of graphitic nitride (C3N4) with NiO-MoO3 is edified using a combination of polymerization and hydrothermal processes. The structural features of fabricated materials were then examined using various analytical techniques. The optimized C3N4/NiO-MoO3 bestowed with Z-scheme achieved 94.8% degradation efficiency of RhB in the presence of visible light within 100 min at a kinetic rate of 0.025 min−1, which is four times higher than neat NiO-MoO3. The heterojunction C3N4/NiO-MoO3 has enhanced striking photodegradation efficiency, limited charge recombination, and extended visible light radiation absorbance. The trapping experiment for radicals has revealed hydroxyl (⋅OH) and superoxide (⋅O2−) radicals as key players in the photodegradation of RhB. Furthermore, C3N4/NiO-MoO3 exhibited an 82% photodegradation efficiency even after four iterative cycles in the reusability test, demonstrating its potential for prolonged usage. The stability test indicated that the optimal material might retain sufficient crystallinity after use. This study demonstrated that C3N4/NiO-MoO3 could effectively optimize the elimination of other pollutants, such as the RhB dye, from wastewater. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Heterogeneous bimetallic Ni-Mo oxide and C<subscript>3</subscript>N<subscript>4</subscript> conjugation for boosted photocatalytic degradation of rhodamine B dye.
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%3A+Materials+in+Electronics%22">Journal of Materials Science: Materials in Electronics</searchLink>. Jul2025, Vol. 36 Issue 21, p1-16. 16p.
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Currently, there has been considerable interest in developing heterojunction materials for the removal of dyes. However, there is a bottleneck in creating an impressive photocatalyst that can degrade organic pollutants propelled by visible light. The integration of graphitic nitride (C3N4) with NiO-MoO3 is edified using a combination of polymerization and hydrothermal processes. The structural features of fabricated materials were then examined using various analytical techniques. The optimized C3N4/NiO-MoO3 bestowed with Z-scheme achieved 94.8% degradation efficiency of RhB in the presence of visible light within 100 min at a kinetic rate of 0.025 min−1, which is four times higher than neat NiO-MoO3. The heterojunction C3N4/NiO-MoO3 has enhanced striking photodegradation efficiency, limited charge recombination, and extended visible light radiation absorbance. The trapping experiment for radicals has revealed hydroxyl (⋅OH) and superoxide (⋅O2−) radicals as key players in the photodegradation of RhB. Furthermore, C3N4/NiO-MoO3 exhibited an 82% photodegradation efficiency even after four iterative cycles in the reusability test, demonstrating its potential for prolonged usage. The stability test indicated that the optimal material might retain sufficient crystallinity after use. This study demonstrated that C3N4/NiO-MoO3 could effectively optimize the elimination of other pollutants, such as the RhB dye, from wastewater. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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              M: 07
              Text: Jul2025
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