Oxidative N‐Formylation of Amines to Formamides.

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Title: Oxidative N‐Formylation of Amines to Formamides.
Authors: Dai, Xingchao1 (AUTHOR) daixingchao@licp.cas.cn, Rabeah, Jabor1,2 (AUTHOR) Jabor.Rabeah@licp.cas.cn
Source: ChemCatChem. 7/22/2025, Vol. 17 Issue 14, p1-10. 10p.
Subjects: Formamide, Amines, Chemical synthesis, Amine oxidase, Methanol, Oxidizing agents, Chemical products manufacturing
Abstract: Formamides are an important class of amine chemicals with a wide range of applications in industry, synthetic chemistry, and materials, and their synthesis has gained increasing attention. Among the various methods developed, oxidative N‐formylation of amines with methanol, formaldehyde, and non‐C1 feedstocks constitutes an attractive one, especially using green oxidants, such as air, O2, and H2O2, due to satisfied production efficiency, mild reaction conditions, and effective cost. Although great progress has been made in this direction, a review focusing on this aspect remains scarce. This review summarizes the recent development on the oxidative N‐formylation of amines to formamides according to the kinds of formyl sources and oxidants. [ABSTRACT FROM AUTHOR]
Copyright of ChemCatChem is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Oxidative N‐Formylation of Amines to Formamides.
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  Data: <searchLink fieldCode="AR" term="%22Dai%2C+Xingchao%22">Dai, Xingchao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> daixingchao@licp.cas.cn</i><br /><searchLink fieldCode="AR" term="%22Rabeah%2C+Jabor%22">Rabeah, Jabor</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> Jabor.Rabeah@licp.cas.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22ChemCatChem%22">ChemCatChem</searchLink>. 7/22/2025, Vol. 17 Issue 14, p1-10. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Formamide%22">Formamide</searchLink><br /><searchLink fieldCode="DE" term="%22Amines%22">Amines</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Amine+oxidase%22">Amine oxidase</searchLink><br /><searchLink fieldCode="DE" term="%22Methanol%22">Methanol</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidizing+agents%22">Oxidizing agents</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+products+manufacturing%22">Chemical products manufacturing</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Formamides are an important class of amine chemicals with a wide range of applications in industry, synthetic chemistry, and materials, and their synthesis has gained increasing attention. Among the various methods developed, oxidative N‐formylation of amines with methanol, formaldehyde, and non‐C1 feedstocks constitutes an attractive one, especially using green oxidants, such as air, O2, and H2O2, due to satisfied production efficiency, mild reaction conditions, and effective cost. Although great progress has been made in this direction, a review focusing on this aspect remains scarce. This review summarizes the recent development on the oxidative N‐formylation of amines to formamides according to the kinds of formyl sources and oxidants. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Group: Ab
  Data: <i>Copyright of ChemCatChem is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1002/cctc.202500359
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      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 10
        StartPage: 1
    Subjects:
      – SubjectFull: Formamide
        Type: general
      – SubjectFull: Amines
        Type: general
      – SubjectFull: Chemical synthesis
        Type: general
      – SubjectFull: Amine oxidase
        Type: general
      – SubjectFull: Methanol
        Type: general
      – SubjectFull: Oxidizing agents
        Type: general
      – SubjectFull: Chemical products manufacturing
        Type: general
    Titles:
      – TitleFull: Oxidative N‐Formylation of Amines to Formamides.
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            NameFull: Dai, Xingchao
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            NameFull: Rabeah, Jabor
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            – D: 22
              M: 07
              Text: 7/22/2025
              Type: published
              Y: 2025
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