Luminescent coordination polymers with d10 metal centres for cation sensing: A review.

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Title: Luminescent coordination polymers with d10 metal centres for cation sensing: A review.
Authors: Zhao, Zi-Hao1 (AUTHOR), Yang, Qian-Yu1 (AUTHOR), Xu, Xin-Rui1 (AUTHOR), Tong, Zhao-Yang1 (AUTHOR) billzytong@126.com
Source: Microchemical Journal. Aug2025, Vol. 215, pN.PAG-N.PAG. 1p.
Subjects: Coordination polymers, Optical materials, Quantum efficiency, Bodies of water, Industrial ecology, Fluorescence
Abstract: [Display omitted] • This article reviews the research progress of d¹⁰ metal-centered CPs in cation detection. • CPs used for fluorescence sensing are categorized into three types. • LODs , working LOD range, Ksv and the experimental mechanisms were compiled in a table and compared. With the development of industrial activities, agricultural labor, and other human activities, some metal cations enter water bodies through surface runoff or infiltration, posing threats not only to ecosystems and normal industrial production but also causing irreversible impacts on human health. Coordination polymers (CPs) formed by the coordination of metal ions with organic ligands, as fluorescent materials, can adapt to different detection needs and possess the ability to modulate fluorescence properties by changing the types of metal ions or ligands, thereby achieving highly selective recognition and low-concentration detection of specific cations. d10 metal centres have stable coordination environment, enabling them to maintain structural integrity under wide range of conditions. Additionally, d1⁰ metal-centered CPs typically exhibit high fluorescence quantum efficiency and longer fluorescence lifetimes. These excellent properties make them highly promising for applications in optical materials and fluorescence sensors. Therefore, this article reviews the research progress of d1⁰ metal-centered CPs in cation detection, including the types of fluorescence detection, detection mechanisms, and other related advancements. [ABSTRACT FROM AUTHOR]
Copyright of Microchemical Journal is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Luminescent coordination polymers with d10 metal centres for cation sensing: A review.
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  Data: <searchLink fieldCode="AR" term="%22Zhao%2C+Zi-Hao%22">Zhao, Zi-Hao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Qian-Yu%22">Yang, Qian-Yu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xu%2C+Xin-Rui%22">Xu, Xin-Rui</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tong%2C+Zhao-Yang%22">Tong, Zhao-Yang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> billzytong@126.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Microchemical+Journal%22">Microchemical Journal</searchLink>. Aug2025, Vol. 215, pN.PAG-N.PAG. 1p.
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  Data: <searchLink fieldCode="DE" term="%22Coordination+polymers%22">Coordination polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+materials%22">Optical materials</searchLink><br /><searchLink fieldCode="DE" term="%22Quantum+efficiency%22">Quantum efficiency</searchLink><br /><searchLink fieldCode="DE" term="%22Bodies+of+water%22">Bodies of water</searchLink><br /><searchLink fieldCode="DE" term="%22Industrial+ecology%22">Industrial ecology</searchLink><br /><searchLink fieldCode="DE" term="%22Fluorescence%22">Fluorescence</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: [Display omitted] • This article reviews the research progress of d¹⁰ metal-centered CPs in cation detection. • CPs used for fluorescence sensing are categorized into three types. • LODs , working LOD range, Ksv and the experimental mechanisms were compiled in a table and compared. With the development of industrial activities, agricultural labor, and other human activities, some metal cations enter water bodies through surface runoff or infiltration, posing threats not only to ecosystems and normal industrial production but also causing irreversible impacts on human health. Coordination polymers (CPs) formed by the coordination of metal ions with organic ligands, as fluorescent materials, can adapt to different detection needs and possess the ability to modulate fluorescence properties by changing the types of metal ions or ligands, thereby achieving highly selective recognition and low-concentration detection of specific cations. d10 metal centres have stable coordination environment, enabling them to maintain structural integrity under wide range of conditions. Additionally, d1⁰ metal-centered CPs typically exhibit high fluorescence quantum efficiency and longer fluorescence lifetimes. These excellent properties make them highly promising for applications in optical materials and fluorescence sensors. Therefore, this article reviews the research progress of d1⁰ metal-centered CPs in cation detection, including the types of fluorescence detection, detection mechanisms, and other related advancements. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Microchemical Journal is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1016/j.microc.2025.114096
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      – Code: eng
        Text: English
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        PageCount: 1
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    Subjects:
      – SubjectFull: Coordination polymers
        Type: general
      – SubjectFull: Optical materials
        Type: general
      – SubjectFull: Quantum efficiency
        Type: general
      – SubjectFull: Bodies of water
        Type: general
      – SubjectFull: Industrial ecology
        Type: general
      – SubjectFull: Fluorescence
        Type: general
    Titles:
      – TitleFull: Luminescent coordination polymers with d10 metal centres for cation sensing: A review.
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            NameFull: Zhao, Zi-Hao
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            NameFull: Yang, Qian-Yu
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            NameFull: Xu, Xin-Rui
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            NameFull: Tong, Zhao-Yang
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            – D: 01
              M: 08
              Text: Aug2025
              Type: published
              Y: 2025
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              Value: 215
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