Effect of Lignin@N‐Cyclohexyl‐2‐Benzothiazole Sulfonamide on the Vulcanization Properties of Natural Rubber/Emulsion Styrene Butadiene Rubber Composites.
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| Title: | Effect of Lignin@N‐Cyclohexyl‐2‐Benzothiazole Sulfonamide on the Vulcanization Properties of Natural Rubber/Emulsion Styrene Butadiene Rubber Composites. |
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| Authors: | Peng, Keyu1 (AUTHOR), Duan, Hao1 (AUTHOR), Zhang, Su1 (AUTHOR) zhangsu0318@163.com, Zhang, Lin1 (AUTHOR), Zhao, Zaiqiang1 (AUTHOR), Jing, Yuan2,3 (AUTHOR), Geng, Chuanbao1 (AUTHOR), Lin, Guangyi1 (AUTHOR) gylin666@163.com |
| Source: | Polymers for Advanced Technologies. Jul2025, Vol. 36 Issue 7, p1-13. 13p. |
| Subjects: | Lignins, Vulcanization, Environmental risk, Composite materials, Mechanical behavior of materials, Rubber, Styrene-butadiene rubber, Energy consumption |
| Abstract: | Lignin, a by‐product of the paper‐making industry, is often associated with significant environmental concerns, commonly called "black water pollution," due to its brutal degradation. Utilizing lignin in rubber not only addresses this pollution issue but also has the potential to enhance the performance of rubber composites, achieving a dual optimization of resources and functionality. This study introduces an innovative method to enhance lignin dispersion and strengthen its interface with rubber. Lignin is modified using a promoter, N‐cyclohexyl‐2‐benzothiazole sulfonamide, and silane coupling agent KH560. The N‐cyclohexyl‐2‐benzothiazole sulfonamide‐modified lignin hybrid materials (LC) are produced by introducing epoxy groups onto the lignin surface via a ring‐opening reaction. The impact of these modified lignin hybrid materials on the properties of natural rubber/emulsion styrene butadiene rubber (NR/ESBR) composites has been thoroughly examined. The results indicate a marked improvement in the dispersion of the modified lignin filler and enhanced interfacial compatibility between the filler and rubber. Additionally, the vulcanization performance of the rubber composites is notably improved; the vulcanization time is reduced by 33.2%, while the vulcanization rate is increased by 43.9%. Notably, when utilizing a filling amount of 20 parts per hundred (20 phr) rubbers for lignin, the mechanical property retention of the NR/ESBR composites aged at 100°C for 48 h is measured at 86.47%, alongside an 18.6% reduction in rolling resistance. This work presents a unique approach to reducing energy consumption in tire production. [ABSTRACT FROM AUTHOR] |
| Copyright of Polymers for Advanced Technologies is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
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| Header | DbId: egs DbLabel: Engineering Source An: 186996897 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Effect of Lignin@N‐Cyclohexyl‐2‐Benzothiazole Sulfonamide on the Vulcanization Properties of Natural Rubber/Emulsion Styrene Butadiene Rubber Composites. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Peng%2C+Keyu%22">Peng, Keyu</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Duan%2C+Hao%22">Duan, Hao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhang%2C+Su%22">Zhang, Su</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhangsu0318@163.com</i><br /><searchLink fieldCode="AR" term="%22Zhang%2C+Lin%22">Zhang, Lin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhao%2C+Zaiqiang%22">Zhao, Zaiqiang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jing%2C+Yuan%22">Jing, Yuan</searchLink><relatesTo>2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Geng%2C+Chuanbao%22">Geng, Chuanbao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Lin%2C+Guangyi%22">Lin, Guangyi</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> gylin666@163.com</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Polymers+for+Advanced+Technologies%22">Polymers for Advanced Technologies</searchLink>. Jul2025, Vol. 36 Issue 7, p1-13. 13p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Lignins%22">Lignins</searchLink><br /><searchLink fieldCode="DE" term="%22Vulcanization%22">Vulcanization</searchLink><br /><searchLink fieldCode="DE" term="%22Environmental+risk%22">Environmental risk</searchLink><br /><searchLink fieldCode="DE" term="%22Composite+materials%22">Composite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink><br /><searchLink fieldCode="DE" term="%22Rubber%22">Rubber</searchLink><br /><searchLink fieldCode="DE" term="%22Styrene-butadiene+rubber%22">Styrene-butadiene rubber</searchLink><br /><searchLink fieldCode="DE" term="%22Energy+consumption%22">Energy consumption</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Lignin, a by‐product of the paper‐making industry, is often associated with significant environmental concerns, commonly called "black water pollution," due to its brutal degradation. Utilizing lignin in rubber not only addresses this pollution issue but also has the potential to enhance the performance of rubber composites, achieving a dual optimization of resources and functionality. This study introduces an innovative method to enhance lignin dispersion and strengthen its interface with rubber. Lignin is modified using a promoter, N‐cyclohexyl‐2‐benzothiazole sulfonamide, and silane coupling agent KH560. The N‐cyclohexyl‐2‐benzothiazole sulfonamide‐modified lignin hybrid materials (LC) are produced by introducing epoxy groups onto the lignin surface via a ring‐opening reaction. The impact of these modified lignin hybrid materials on the properties of natural rubber/emulsion styrene butadiene rubber (NR/ESBR) composites has been thoroughly examined. The results indicate a marked improvement in the dispersion of the modified lignin filler and enhanced interfacial compatibility between the filler and rubber. Additionally, the vulcanization performance of the rubber composites is notably improved; the vulcanization time is reduced by 33.2%, while the vulcanization rate is increased by 43.9%. Notably, when utilizing a filling amount of 20 parts per hundred (20 phr) rubbers for lignin, the mechanical property retention of the NR/ESBR composites aged at 100°C for 48 h is measured at 86.47%, alongside an 18.6% reduction in rolling resistance. This work presents a unique approach to reducing energy consumption in tire production. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Polymers for Advanced Technologies is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1002/pat.70236 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 13 StartPage: 1 Subjects: – SubjectFull: Lignins Type: general – SubjectFull: Vulcanization Type: general – SubjectFull: Environmental risk Type: general – SubjectFull: Composite materials Type: general – SubjectFull: Mechanical behavior of materials Type: general – SubjectFull: Rubber Type: general – SubjectFull: Styrene-butadiene rubber Type: general – SubjectFull: Energy consumption Type: general Titles: – TitleFull: Effect of Lignin@N‐Cyclohexyl‐2‐Benzothiazole Sulfonamide on the Vulcanization Properties of Natural Rubber/Emulsion Styrene Butadiene Rubber Composites. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Peng, Keyu – PersonEntity: Name: NameFull: Duan, Hao – PersonEntity: Name: NameFull: Zhang, Su – PersonEntity: Name: NameFull: Zhang, Lin – PersonEntity: Name: NameFull: Zhao, Zaiqiang – PersonEntity: Name: NameFull: Jing, Yuan – PersonEntity: Name: NameFull: Geng, Chuanbao – PersonEntity: Name: NameFull: Lin, Guangyi IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 07 Text: Jul2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 10427147 Numbering: – Type: volume Value: 36 – Type: issue Value: 7 Titles: – TitleFull: Polymers for Advanced Technologies Type: main |
| ResultId | 1 |
