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Synergy of Pseudocapacitive Properties of Ferromagnetic La1 − xSrxMnO3 and Polypyrrole in high Active Mass Composite Electrodes for Supercapacitors.

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Title: Synergy of Pseudocapacitive Properties of Ferromagnetic La1 − xSrxMnO3 and Polypyrrole in high Active Mass Composite Electrodes for Supercapacitors.
Authors: Tang, D.1 (AUTHOR), Zhitomirsky, I.1 (AUTHOR) zhitom@mcmaster.ca
Source: Journal of Inorganic & Organometallic Polymers & Materials. Jul2025, Vol. 35 Issue 7, p5596-5610. 15p.
Subjects: Polypyrrole, Supercapacitors, Ferromagnetism, Perovskite, Electric capacity, Polymer electrodes, Electrochemical experiments
Abstract: This investigation is inspired by interest in magnetically ordered pseudocapacitive materials. Pseudocapacitive composites of La0.8Sr0.2MnO3 (LSM), polypyrrole (PPy) and carbon nanotubes are prepared. The electrochemical testing conditions for the composite electrodes are optimized for an active mass (AM) of 0.04 g cm− 2. Testing is performed in a sodium sulfate electrolyte in a potential range of– 0.5 to 0.4 V vs. SCE. The benefits of such composites are threefold. Firstly, the investigation of electrodes with different LSM and PPy contents reveals the synergistic contributions of LSM and PPy to the capacitance. Testing results show that significant capacitance enhancement can be achieved in the high AM composites. The best capacitance of 6.03 F cm− 2 (150.69 F g− 1) is obtained for composites containing 20% LSM. The composites show ideal pseudocapacitive behavior. Secondly, the composites show significant capacitance enhancement at fast charging conditions, which opens a door for improved devices. Thirdly, the synergy of LSM and PPy is manifested by significant reduction of electrode resistance and charge transfer resistance. Pseudocapacitive and magnetic characteristics of the electrodes can be varied. The mechanisms of synergetic effect of LSM and PPy on the electrode capacitance and enhanced LSM/PPy interface charge transfer are suggested. The approach proposed in this study offers a platform for manufacturing advanced magnetic pseudocapacitors with enhanced capacitive properties. The composite electrodes are utilized for the design of asymmetric devices, which show capacitances of 2.58 and 2.64 F cm− 2 from cyclic voltammetry and chronopotentiomentry testing results, respectively. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Inorganic & Organometallic Polymers & Materials is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Synergy of Pseudocapacitive Properties of Ferromagnetic La<subscript>1 − x</subscript>Sr<subscript>x</subscript>MnO<subscript>3</subscript> and Polypyrrole in high Active Mass Composite Electrodes for Supercapacitors.
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  Data: <searchLink fieldCode="AR" term="%22Tang%2C+D%2E%22">Tang, D.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhitomirsky%2C+I%2E%22">Zhitomirsky, I.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> zhitom@mcmaster.ca</i>
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  Data: <searchLink fieldCode="DE" term="%22Polypyrrole%22">Polypyrrole</searchLink><br /><searchLink fieldCode="DE" term="%22Supercapacitors%22">Supercapacitors</searchLink><br /><searchLink fieldCode="DE" term="%22Ferromagnetism%22">Ferromagnetism</searchLink><br /><searchLink fieldCode="DE" term="%22Perovskite%22">Perovskite</searchLink><br /><searchLink fieldCode="DE" term="%22Electric+capacity%22">Electric capacity</searchLink><br /><searchLink fieldCode="DE" term="%22Polymer+electrodes%22">Polymer electrodes</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+experiments%22">Electrochemical experiments</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: This investigation is inspired by interest in magnetically ordered pseudocapacitive materials. Pseudocapacitive composites of La0.8Sr0.2MnO3 (LSM), polypyrrole (PPy) and carbon nanotubes are prepared. The electrochemical testing conditions for the composite electrodes are optimized for an active mass (AM) of 0.04 g cm− 2. Testing is performed in a sodium sulfate electrolyte in a potential range of– 0.5 to 0.4 V vs. SCE. The benefits of such composites are threefold. Firstly, the investigation of electrodes with different LSM and PPy contents reveals the synergistic contributions of LSM and PPy to the capacitance. Testing results show that significant capacitance enhancement can be achieved in the high AM composites. The best capacitance of 6.03 F cm− 2 (150.69 F g− 1) is obtained for composites containing 20% LSM. The composites show ideal pseudocapacitive behavior. Secondly, the composites show significant capacitance enhancement at fast charging conditions, which opens a door for improved devices. Thirdly, the synergy of LSM and PPy is manifested by significant reduction of electrode resistance and charge transfer resistance. Pseudocapacitive and magnetic characteristics of the electrodes can be varied. The mechanisms of synergetic effect of LSM and PPy on the electrode capacitance and enhanced LSM/PPy interface charge transfer are suggested. The approach proposed in this study offers a platform for manufacturing advanced magnetic pseudocapacitors with enhanced capacitive properties. The composite electrodes are utilized for the design of asymmetric devices, which show capacitances of 2.58 and 2.64 F cm− 2 from cyclic voltammetry and chronopotentiomentry testing results, respectively. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Inorganic & Organometallic Polymers & Materials is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s10904-025-03610-0
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      – Code: eng
        Text: English
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      Pagination:
        PageCount: 15
        StartPage: 5596
    Subjects:
      – SubjectFull: Polypyrrole
        Type: general
      – SubjectFull: Supercapacitors
        Type: general
      – SubjectFull: Ferromagnetism
        Type: general
      – SubjectFull: Perovskite
        Type: general
      – SubjectFull: Electric capacity
        Type: general
      – SubjectFull: Polymer electrodes
        Type: general
      – SubjectFull: Electrochemical experiments
        Type: general
    Titles:
      – TitleFull: Synergy of Pseudocapacitive Properties of Ferromagnetic La1 − xSrxMnO3 and Polypyrrole in high Active Mass Composite Electrodes for Supercapacitors.
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            NameFull: Tang, D.
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            NameFull: Zhitomirsky, I.
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          Dates:
            – D: 01
              M: 07
              Text: Jul2025
              Type: published
              Y: 2025
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            – TitleFull: Journal of Inorganic & Organometallic Polymers & Materials
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