View in EDS

Enzymatic synthesis of poly(erythritol sebacate).

Saved in:

Bibliographic Details
Title:	Enzymatic synthesis of poly(erythritol sebacate).
Authors:	Smarandache, Diana¹ (AUTHOR), Godinho, Bruno² (AUTHOR), Ionescu, Cătălina¹ (AUTHOR), Cioateră, Nicoleta¹ (AUTHOR), Ferreira, Artur³ (AUTHOR), Gama, Nuno² (AUTHOR) nuno.gama@ua.pt
Source:	Journal of Elastomers & Plastics. Oct2025, Vol. 57 Issue 6, p935-952. 18p.
Subjects:	Polyesters, Prepolymers, Condensation reactions, Lipolytic enzymes, Properties of matter, Biosynthesis, Degree of polymerization
Abstract:	This study details the synthesis of poly(erythritol sebacate) (PES), a polyester synthesized via thermal/enzymatic polycondensation of erythritol and sebacic acid in a three-step process. In the first step, a 1:1 molar ratio erythritol and sebacic acid was used, at various temperatures until achieving a theoretical 40% degree of esterification. The second prepolymerization step utilized Candida antarctica lipase B under different conditions. This was followed by a curing step at 150°C for 24 hours. The results indicated that a temperature of 150°C yielded a more homogeneous prepolymer richer in linear ester oligomers, making it the selected condition for the first prepolymerization step. Afterwards, the second prepolymerization yielded prepolymers with varying degrees of esterification and molecular mass distributions, confirming the high selectivity of lipase B for primary hydroxyl groups. These differences in prepolymers influenced the mechanical properties of the resulting polymers after the curing process. Notably, the enzymatic synthesis at 90°C for 48 hours resulted in a prepolymer with a higher degree of esterification (68%) and longer linear chains, producing the polymer with the best mechanical performance. These findings suggest that enzymatic polymerization, under optimal conditions, can yield PES with properties suitable for a wide range of applications. [ABSTRACT FROM AUTHOR]
	Copyright of Journal of Elastomers & Plastics is the property of Sage Publications Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database:	Engineering Source

FullText	Text: Availability: 0
Header	DbId: egs DbLabel: Engineering Source An: 187648903 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0
IllustrationInfo
Items	– Name: Title Label: Title Group: Ti Data: Enzymatic synthesis of poly(erythritol sebacate). – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Smarandache%2C+Diana%22">Smarandache, Diana</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Godinho%2C+Bruno%22">Godinho, Bruno</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ionescu%2C+Cătălina%22">Ionescu, Cătălina</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Cioateră%2C+Nicoleta%22">Cioateră, Nicoleta</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Ferreira%2C+Artur%22">Ferreira, Artur</searchLink><relatesTo>3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Gama%2C+Nuno%22">Gama, Nuno</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> nuno.gama@ua.pt</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Elastomers+%26+Plastics%22">Journal of Elastomers & Plastics</searchLink>. Oct2025, Vol. 57 Issue 6, p935-952. 18p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Polyesters%22">Polyesters</searchLink><br /><searchLink fieldCode="DE" term="%22Prepolymers%22">Prepolymers</searchLink><br /><searchLink fieldCode="DE" term="%22Condensation+reactions%22">Condensation reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Lipolytic+enzymes%22">Lipolytic enzymes</searchLink><br /><searchLink fieldCode="DE" term="%22Properties+of+matter%22">Properties of matter</searchLink><br /><searchLink fieldCode="DE" term="%22Biosynthesis%22">Biosynthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Degree+of+polymerization%22">Degree of polymerization</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: This study details the synthesis of poly(erythritol sebacate) (PES), a polyester synthesized via thermal/enzymatic polycondensation of erythritol and sebacic acid in a three-step process. In the first step, a 1:1 molar ratio erythritol and sebacic acid was used, at various temperatures until achieving a theoretical 40% degree of esterification. The second prepolymerization step utilized Candida antarctica lipase B under different conditions. This was followed by a curing step at 150°C for 24 hours. The results indicated that a temperature of 150°C yielded a more homogeneous prepolymer richer in linear ester oligomers, making it the selected condition for the first prepolymerization step. Afterwards, the second prepolymerization yielded prepolymers with varying degrees of esterification and molecular mass distributions, confirming the high selectivity of lipase B for primary hydroxyl groups. These differences in prepolymers influenced the mechanical properties of the resulting polymers after the curing process. Notably, the enzymatic synthesis at 90°C for 48 hours resulted in a prepolymer with a higher degree of esterification (68%) and longer linear chains, producing the polymer with the best mechanical performance. These findings suggest that enzymatic polymerization, under optimal conditions, can yield PES with properties suitable for a wide range of applications. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Elastomers & Plastics is the property of Sage Publications Inc. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink	https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=187648903
RecordInfo	BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1177/00952443251340823 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 18 StartPage: 935 Subjects: – SubjectFull: Polyesters Type: general – SubjectFull: Prepolymers Type: general – SubjectFull: Condensation reactions Type: general – SubjectFull: Lipolytic enzymes Type: general – SubjectFull: Properties of matter Type: general – SubjectFull: Biosynthesis Type: general – SubjectFull: Degree of polymerization Type: general Titles: – TitleFull: Enzymatic synthesis of poly(erythritol sebacate). Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Smarandache, Diana – PersonEntity: Name: NameFull: Godinho, Bruno – PersonEntity: Name: NameFull: Ionescu, Cătălina – PersonEntity: Name: NameFull: Cioateră, Nicoleta – PersonEntity: Name: NameFull: Ferreira, Artur – PersonEntity: Name: NameFull: Gama, Nuno IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 10 Text: Oct2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 00952443 Numbering: – Type: volume Value: 57 – Type: issue Value: 6 Titles: – TitleFull: Journal of Elastomers & Plastics Type: main
ResultId	1