Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals.
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| Title: | Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals. |
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| Authors: | Tolstikov, S. E.1 (AUTHOR) tse@tomo.nsc.ru, Romanenko, G. V.1 (AUTHOR), Tretyakov, E. V.2 (AUTHOR), Bogomyakov, A. S.1 (AUTHOR) |
| Source: | Journal of Structural Chemistry. Aug2025, Vol. 66 Issue 8, p1708-1714. 7p. |
| Subjects: | Pyrazoles, Nitroxides, Biradicals, Magnetic ions, Molecular structure, Chemical synthesis, Scholarly method, X-ray crystallography |
| Abstract: | The reaction of bisnitronylnitroxide with a diacetylene bridging group and diazomethane leads to the modification of the initial substrate while preserving its paramagnetic centers. As a result, new nitronylnitroxide biradicals containing a bispyrazolyl fragment were prepared. Molecular and crystal structures of the biradicals are determined by single crystal XRD. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Structural Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 187672462 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Tolstikov%2C+S%2E+E%2E%22">Tolstikov, S. E.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> tse@tomo.nsc.ru</i><br /><searchLink fieldCode="AR" term="%22Romanenko%2C+G%2E+V%2E%22">Romanenko, G. V.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Tretyakov%2C+E%2E+V%2E%22">Tretyakov, E. V.</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Bogomyakov%2C+A%2E+S%2E%22">Bogomyakov, A. S.</searchLink><relatesTo>1</relatesTo> (AUTHOR) – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Structural+Chemistry%22">Journal of Structural Chemistry</searchLink>. Aug2025, Vol. 66 Issue 8, p1708-1714. 7p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Pyrazoles%22">Pyrazoles</searchLink><br /><searchLink fieldCode="DE" term="%22Nitroxides%22">Nitroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Biradicals%22">Biradicals</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetic+ions%22">Magnetic ions</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+structure%22">Molecular structure</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Scholarly+method%22">Scholarly method</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: The reaction of bisnitronylnitroxide with a diacetylene bridging group and diazomethane leads to the modification of the initial substrate while preserving its paramagnetic centers. As a result, new nitronylnitroxide biradicals containing a bispyrazolyl fragment were prepared. Molecular and crystal structures of the biradicals are determined by single crystal XRD. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Structural Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1134/S0022476625080165 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 7 StartPage: 1708 Subjects: – SubjectFull: Pyrazoles Type: general – SubjectFull: Nitroxides Type: general – SubjectFull: Biradicals Type: general – SubjectFull: Magnetic ions Type: general – SubjectFull: Molecular structure Type: general – SubjectFull: Chemical synthesis Type: general – SubjectFull: Scholarly method Type: general – SubjectFull: X-ray crystallography Type: general Titles: – TitleFull: Synthesis and Structure of Bispyrazolyl Nitronylnitroxide Biradicals. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Tolstikov, S. E. – PersonEntity: Name: NameFull: Romanenko, G. V. – PersonEntity: Name: NameFull: Tretyakov, E. V. – PersonEntity: Name: NameFull: Bogomyakov, A. S. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 08 Text: Aug2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 00224766 Numbering: – Type: volume Value: 66 – Type: issue Value: 8 Titles: – TitleFull: Journal of Structural Chemistry Type: main |
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