In situ growth of Cu(OH)2@FeNi-LDH nanoarrays and their OER properties.

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Title: In situ growth of Cu(OH)2@FeNi-LDH nanoarrays and their OER properties.
Authors: Wang, Tianshuo1 (AUTHOR), Xiao, Jiajia1 (AUTHOR), Chen, Feng1 (AUTHOR), Zhao, ZiKang1 (AUTHOR), Yuan, Yubin1 (AUTHOR), Xie, Tianxiao1 (AUTHOR), Luo, Yide1 (AUTHOR), Zhou, Zongtai1 (AUTHOR), Zhou, Junshuang1 (AUTHOR) jszhou@ysu.edu.cn, Gao, Faming1,2 (AUTHOR) fmgao@ysu.edu.cn
Source: Journal of Materials Science. Sep2025, Vol. 60 Issue 33, p14473-14484. 12p.
Subjects: Oxygen evolution reactions, Hydrogen production, Metal catalysts, Nanocomposite materials, Layered double hydroxides, Cuprous oxide, Electrocatalysts
Abstract: Hydrogen has great potential. Electrolysis of water is an efficient method for hydrogen production, but highly efficient catalysts (such as platinum, iridium/ruthenium oxides) are limited due to cost and resource issues. Therefore, in the past decade, research focus has shifted to developing low-cost non-precious metal catalysts. In this study, a novel bimetallic nanomaterial based on metal foam was synthesized in situ by designing the structure and composition of transition metal catalysts. Specifically, Cu(OH)2 nanowire arrays with a core-shell structure of NiFe-LDH were fabricated via in-situ etching of Cu(OH)2 nanowire arrays on the surface of copper foam (CF) using a simple room-temperature corrosion oxidation process, followed by immersion in a mixture of FeCl2 and NiCl2 solutions. The resulting NiFe-LDH nanowires, grown directly on the array, exhibit a large surface area that exposes more active sites, significantly enhancing electrocatalytic activity and enabling the electrode to demonstrate excellent OER performance. It exhibits excellent oxygen evolution performance in alkaline electrolytes (1 M KOH and 6 M KOH). At an overpotential of 350 mV, the current densities are 371.6 mA cm-2 and 637 mA cm-2 respectively, and it also has excellent long-term stability (≥ 30 hours).This work provides innovative insights into the design of highly stable and active electrodes. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: In situ growth of Cu(OH)<subscript>2</subscript>@FeNi-LDH nanoarrays and their OER properties.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Wang%2C+Tianshuo%22">Wang, Tianshuo</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xiao%2C+Jiajia%22">Xiao, Jiajia</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Chen%2C+Feng%22">Chen, Feng</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhao%2C+ZiKang%22">Zhao, ZiKang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yuan%2C+Yubin%22">Yuan, Yubin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Xie%2C+Tianxiao%22">Xie, Tianxiao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Luo%2C+Yide%22">Luo, Yide</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhou%2C+Zongtai%22">Zhou, Zongtai</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zhou%2C+Junshuang%22">Zhou, Junshuang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> jszhou@ysu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Gao%2C+Faming%22">Gao, Faming</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> fmgao@ysu.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%22">Journal of Materials Science</searchLink>. Sep2025, Vol. 60 Issue 33, p14473-14484. 12p.
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  Data: <searchLink fieldCode="DE" term="%22Oxygen+evolution+reactions%22">Oxygen evolution reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+production%22">Hydrogen production</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+catalysts%22">Metal catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Nanocomposite+materials%22">Nanocomposite materials</searchLink><br /><searchLink fieldCode="DE" term="%22Layered+double+hydroxides%22">Layered double hydroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Cuprous+oxide%22">Cuprous oxide</searchLink><br /><searchLink fieldCode="DE" term="%22Electrocatalysts%22">Electrocatalysts</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Hydrogen has great potential. Electrolysis of water is an efficient method for hydrogen production, but highly efficient catalysts (such as platinum, iridium/ruthenium oxides) are limited due to cost and resource issues. Therefore, in the past decade, research focus has shifted to developing low-cost non-precious metal catalysts. In this study, a novel bimetallic nanomaterial based on metal foam was synthesized in situ by designing the structure and composition of transition metal catalysts. Specifically, Cu(OH)2 nanowire arrays with a core-shell structure of NiFe-LDH were fabricated via in-situ etching of Cu(OH)2 nanowire arrays on the surface of copper foam (CF) using a simple room-temperature corrosion oxidation process, followed by immersion in a mixture of FeCl2 and NiCl2 solutions. The resulting NiFe-LDH nanowires, grown directly on the array, exhibit a large surface area that exposes more active sites, significantly enhancing electrocatalytic activity and enabling the electrode to demonstrate excellent OER performance. It exhibits excellent oxygen evolution performance in alkaline electrolytes (1 M KOH and 6 M KOH). At an overpotential of 350 mV, the current densities are 371.6 mA cm-2 and 637 mA cm-2 respectively, and it also has excellent long-term stability (≥ 30 hours).This work provides innovative insights into the design of highly stable and active electrodes. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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      – Type: doi
        Value: 10.1007/s10853-025-11327-1
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 12
        StartPage: 14473
    Subjects:
      – SubjectFull: Oxygen evolution reactions
        Type: general
      – SubjectFull: Hydrogen production
        Type: general
      – SubjectFull: Metal catalysts
        Type: general
      – SubjectFull: Nanocomposite materials
        Type: general
      – SubjectFull: Layered double hydroxides
        Type: general
      – SubjectFull: Cuprous oxide
        Type: general
      – SubjectFull: Electrocatalysts
        Type: general
    Titles:
      – TitleFull: In situ growth of Cu(OH)2@FeNi-LDH nanoarrays and their OER properties.
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            NameFull: Wang, Tianshuo
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            NameFull: Xiao, Jiajia
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            NameFull: Chen, Feng
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            NameFull: Zhao, ZiKang
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            NameFull: Yuan, Yubin
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            NameFull: Zhou, Zongtai
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            – D: 01
              M: 09
              Text: Sep2025
              Type: published
              Y: 2025
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