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Preparation of peroxide initiator monomer containing degradable disulphide bond.

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Title: Preparation of peroxide initiator monomer containing degradable disulphide bond.
Authors: Jiang, Fang1 (AUTHOR), Huang, Feiyao2 (AUTHOR), Yang, Hongjun1 (AUTHOR), Jiang, Li1 (AUTHOR), Jiang, Qimin1 (AUTHOR), Huang, Wenyan1 (AUTHOR) ellahwy@cczu.edu.cn, Xue, Xiaoqiang1 (AUTHOR), Jiang, Bibiao1 (AUTHOR)
Source: Materials Research Innovations. Sep2025, Vol. 29 Issue 6, p396-400. 5p.
Subjects: Lipoic acid, Vinyl polymers, Chemical synthesis, Hydrogen peroxide, High performance liquid chromatography, Chemical bonds, Biodegradable materials, Nuclear magnetic resonance
Abstract: A functional initiator monomer containing lipoic acid ester both with degradable disulphide bond and peroxide bond was designed and synthesised. Here, the precursors are lipoic acid and tert-butyl (isopropylbenzene) hydroperoxide, while dichloromethane (tetrahydrofuran) was used as a solvent and 4-dimethylaminopyridine (DMAP) and N, N'-dicyclohexylcarbodiimide (DCC) were used as condensation agents. The structure and purity of lipoic acid ester functional initiator monomer were characterised by proton nuclear magnetic resonance (1H-NMR) and high-performance liquid chromatography (HPLC). The purity of lipoic acid ester functional initiator monomer prepared is as high as over 90%. The precursor material is low-cost and widely available, and does not require special methods to purify the product, which means it can be directly used in the synthesis of degradable vinyl polymers. Therefore, it provides great application prospects for green and environmentally friendly materials. [ABSTRACT FROM AUTHOR]
Copyright of Materials Research Innovations is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Preparation of peroxide initiator monomer containing degradable disulphide bond.
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  Data: <searchLink fieldCode="AR" term="%22Jiang%2C+Fang%22">Jiang, Fang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Huang%2C+Feiyao%22">Huang, Feiyao</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Hongjun%22">Yang, Hongjun</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Li%22">Jiang, Li</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Qimin%22">Jiang, Qimin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Huang%2C+Wenyan%22">Huang, Wenyan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ellahwy@cczu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Xue%2C+Xiaoqiang%22">Xue, Xiaoqiang</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jiang%2C+Bibiao%22">Jiang, Bibiao</searchLink><relatesTo>1</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Materials+Research+Innovations%22">Materials Research Innovations</searchLink>. Sep2025, Vol. 29 Issue 6, p396-400. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Lipoic+acid%22">Lipoic acid</searchLink><br /><searchLink fieldCode="DE" term="%22Vinyl+polymers%22">Vinyl polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+synthesis%22">Chemical synthesis</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrogen+peroxide%22">Hydrogen peroxide</searchLink><br /><searchLink fieldCode="DE" term="%22High+performance+liquid+chromatography%22">High performance liquid chromatography</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+bonds%22">Chemical bonds</searchLink><br /><searchLink fieldCode="DE" term="%22Biodegradable+materials%22">Biodegradable materials</searchLink><br /><searchLink fieldCode="DE" term="%22Nuclear+magnetic+resonance%22">Nuclear magnetic resonance</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: A functional initiator monomer containing lipoic acid ester both with degradable disulphide bond and peroxide bond was designed and synthesised. Here, the precursors are lipoic acid and tert-butyl (isopropylbenzene) hydroperoxide, while dichloromethane (tetrahydrofuran) was used as a solvent and 4-dimethylaminopyridine (DMAP) and N, N'-dicyclohexylcarbodiimide (DCC) were used as condensation agents. The structure and purity of lipoic acid ester functional initiator monomer were characterised by proton nuclear magnetic resonance (1H-NMR) and high-performance liquid chromatography (HPLC). The purity of lipoic acid ester functional initiator monomer prepared is as high as over 90%. The precursor material is low-cost and widely available, and does not require special methods to purify the product, which means it can be directly used in the synthesis of degradable vinyl polymers. Therefore, it provides great application prospects for green and environmentally friendly materials. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Materials Research Innovations is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1080/14328917.2025.2470732
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      – Code: eng
        Text: English
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        PageCount: 5
        StartPage: 396
    Subjects:
      – SubjectFull: Lipoic acid
        Type: general
      – SubjectFull: Vinyl polymers
        Type: general
      – SubjectFull: Chemical synthesis
        Type: general
      – SubjectFull: Hydrogen peroxide
        Type: general
      – SubjectFull: High performance liquid chromatography
        Type: general
      – SubjectFull: Chemical bonds
        Type: general
      – SubjectFull: Biodegradable materials
        Type: general
      – SubjectFull: Nuclear magnetic resonance
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      – TitleFull: Preparation of peroxide initiator monomer containing degradable disulphide bond.
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            NameFull: Jiang, Fang
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            NameFull: Huang, Feiyao
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            NameFull: Yang, Hongjun
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            NameFull: Jiang, Li
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            – D: 01
              M: 09
              Text: Sep2025
              Type: published
              Y: 2025
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              Value: 29
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