Multifunctional superhydrophobic coating with enhanced mechanical durability, corrosion protection, and buoyancy via tripolyphosphate modified layered double hydroxides.

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Title: Multifunctional superhydrophobic coating with enhanced mechanical durability, corrosion protection, and buoyancy via tripolyphosphate modified layered double hydroxides.
Authors: Wang, Haojie1 (AUTHOR) wanghaojiekyfs329@163.com, Luo, Da1 (AUTHOR) luoda222@stu.ahjzu.edu.cn, Xu, Dong1 (AUTHOR) xudong@stu.ahjzu.edu.cn, Lu, Xiangyou1 (AUTHOR) gaoyunwansu@ahjzu.edu.cn, Wang, Jinjin1 (AUTHOR) wangjinjin2024@163.com, Hu, Chao1 (AUTHOR) chaohu@mail.ustc.edu.cn, Liang, Jie1 (AUTHOR) 2584837161@qq.com, Wei, Honghong1 (AUTHOR) 2449429109@qq.com, Xie, Yuanlai2 (AUTHOR) 872719866@qq.com
Source: Journal of Materials Science. Sep2025, Vol. 60 Issue 35, p15813-15832. 20p.
Subjects: Corrosion prevention, Sodium tripolyphosphate, Hydrophobic interactions, Buoyancy, Layered double hydroxides, Epoxy resins, Surface cleaning, Durability
Abstract: In this study, a multifunctional superhydrophobic coating with mechanical stability, temperature resistance, buoyancy enhancement, and corrosion resistance was developed to expand its application in real life. Through the co-precipitation and hydrothermal method, tripolyphosphate was introduced into the structure of layered double hydroxides. Based on this structure, it was composited with an epoxy resin matrix after surface loading and hydrophobic modification, and then, a new superhydrophobic coating was constructed through the spraying process. The contact angle of the coating is 155°, and the rolling angle is 4.5°. After a 400 cm friction resistance test and 90 tape peeling tests, the contact angle remains higher than 150°, indicating excellent mechanical stability. The top and bottom coatings withstood 6.594 g and 5.181 g loads, respectively, in the buoyancy test. Electrochemical tests show that the coating resistance is as high as 3.89 × 107 Ω cm2, the charge transfer resistance is as high as 8.135 × 108 Ω cm2, the corrosion potential is positively shifted by 0.966 V, and the corrosion current density is reduced to 9.506 × 10–12 A/cm2. The corrosion inhibition efficiency was increased by 8.16% compared to EP coating. The superhydrophobic coating developed in this study exhibits excellent comprehensive performance and significant protective advantages in complex environments, providing a new strategy for the practical application of superhydrophobic materials and offering high popularization value and research reference significance. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: Multifunctional superhydrophobic coating with enhanced mechanical durability, corrosion protection, and buoyancy via tripolyphosphate modified layered double hydroxides.
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  Label: Authors
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  Data: <searchLink fieldCode="AR" term="%22Wang%2C+Haojie%22">Wang, Haojie</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wanghaojiekyfs329@163.com</i><br /><searchLink fieldCode="AR" term="%22Luo%2C+Da%22">Luo, Da</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> luoda222@stu.ahjzu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Xu%2C+Dong%22">Xu, Dong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xudong@stu.ahjzu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Lu%2C+Xiangyou%22">Lu, Xiangyou</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> gaoyunwansu@ahjzu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Wang%2C+Jinjin%22">Wang, Jinjin</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> wangjinjin2024@163.com</i><br /><searchLink fieldCode="AR" term="%22Hu%2C+Chao%22">Hu, Chao</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> chaohu@mail.ustc.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Liang%2C+Jie%22">Liang, Jie</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> 2584837161@qq.com</i><br /><searchLink fieldCode="AR" term="%22Wei%2C+Honghong%22">Wei, Honghong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> 2449429109@qq.com</i><br /><searchLink fieldCode="AR" term="%22Xie%2C+Yuanlai%22">Xie, Yuanlai</searchLink><relatesTo>2</relatesTo> (AUTHOR)<i> 872719866@qq.com</i>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%22">Journal of Materials Science</searchLink>. Sep2025, Vol. 60 Issue 35, p15813-15832. 20p.
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  Data: <searchLink fieldCode="DE" term="%22Corrosion+prevention%22">Corrosion prevention</searchLink><br /><searchLink fieldCode="DE" term="%22Sodium+tripolyphosphate%22">Sodium tripolyphosphate</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrophobic+interactions%22">Hydrophobic interactions</searchLink><br /><searchLink fieldCode="DE" term="%22Buoyancy%22">Buoyancy</searchLink><br /><searchLink fieldCode="DE" term="%22Layered+double+hydroxides%22">Layered double hydroxides</searchLink><br /><searchLink fieldCode="DE" term="%22Epoxy+resins%22">Epoxy resins</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+cleaning%22">Surface cleaning</searchLink><br /><searchLink fieldCode="DE" term="%22Durability%22">Durability</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: In this study, a multifunctional superhydrophobic coating with mechanical stability, temperature resistance, buoyancy enhancement, and corrosion resistance was developed to expand its application in real life. Through the co-precipitation and hydrothermal method, tripolyphosphate was introduced into the structure of layered double hydroxides. Based on this structure, it was composited with an epoxy resin matrix after surface loading and hydrophobic modification, and then, a new superhydrophobic coating was constructed through the spraying process. The contact angle of the coating is 155°, and the rolling angle is 4.5°. After a 400 cm friction resistance test and 90 tape peeling tests, the contact angle remains higher than 150°, indicating excellent mechanical stability. The top and bottom coatings withstood 6.594 g and 5.181 g loads, respectively, in the buoyancy test. Electrochemical tests show that the coating resistance is as high as 3.89 × 107 Ω cm2, the charge transfer resistance is as high as 8.135 × 108 Ω cm2, the corrosion potential is positively shifted by 0.966 V, and the corrosion current density is reduced to 9.506 × 10–12 A/cm2. The corrosion inhibition efficiency was increased by 8.16% compared to EP coating. The superhydrophobic coating developed in this study exhibits excellent comprehensive performance and significant protective advantages in complex environments, providing a new strategy for the practical application of superhydrophobic materials and offering high popularization value and research reference significance. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Journal of Materials Science is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1007/s10853-025-11365-9
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 20
        StartPage: 15813
    Subjects:
      – SubjectFull: Corrosion prevention
        Type: general
      – SubjectFull: Sodium tripolyphosphate
        Type: general
      – SubjectFull: Hydrophobic interactions
        Type: general
      – SubjectFull: Buoyancy
        Type: general
      – SubjectFull: Layered double hydroxides
        Type: general
      – SubjectFull: Epoxy resins
        Type: general
      – SubjectFull: Surface cleaning
        Type: general
      – SubjectFull: Durability
        Type: general
    Titles:
      – TitleFull: Multifunctional superhydrophobic coating with enhanced mechanical durability, corrosion protection, and buoyancy via tripolyphosphate modified layered double hydroxides.
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            NameFull: Wang, Haojie
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            NameFull: Luo, Da
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            NameFull: Xu, Dong
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            NameFull: Lu, Xiangyou
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            NameFull: Wang, Jinjin
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            NameFull: Wei, Honghong
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            – D: 15
              M: 09
              Text: Sep2025
              Type: published
              Y: 2025
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