View in EDS PDF Full Text

Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements.

Saved in:
Bibliographic Details
Title: Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements.
Authors: Kataria, Yash V.1 katariayash1603@gmail.com, Lavrenov, Sergey A.2, Yakovenko, Evgeniya Yu.1, Klushin, Victor A.1, Yakovenko, Roman E.1, Kashparova, Vera P.1, Zubkov, Ivan N.1
Source: Bulletin of Chemical Reaction Engineering & Catalysis. Oct2025, Vol. 20 Issue 3, p403-410. 8p.
Subjects: Fischer-Tropsch process, Polyolefins, Catalysis, Bimetallic catalysts, Oxidative coupling, Metallic soaps, Alkenes, Lubrication & lubricants manufacturing
Abstract: In the present work we further expanded the scope of the study of the oxidative oligomerization process of synthetic hydrocarbon fraction obtained by Fischer-Tropsch synthesis with a total olefin content (consisting predominantly internal/branched olefins) of 10 % with the aim of producing poly-a-olefin like lubricant material. The oxidative oligomerization was carried out using commercially available metal octoates based on Co, Mn, Zn, Ca, Ba, Li, Zr, Cu and Pb and their combinations as catalyst. It was established that the yield of the oligomerization reaction depending on the active metal component used decreased in the following order: Ba > Zr > Zn > Co > Mn > Ca > Li > Cu > Pb. While at the same time, the oxidative oligomerization reaction carried out using bimetallic catalytic systems did not led to any significant increase in the product yield. The oxidative oligomerization reaction using Ba octoate as catalyst gave a yield of 30.4 % and had a kinematic viscosity at 100 °C of 3.6 cSt, Viscosity Index value of 201 and pour point of minus 10. [ABSTRACT FROM AUTHOR]
Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Description
Abstract:In the present work we further expanded the scope of the study of the oxidative oligomerization process of synthetic hydrocarbon fraction obtained by Fischer-Tropsch synthesis with a total olefin content (consisting predominantly internal/branched olefins) of 10 % with the aim of producing poly-a-olefin like lubricant material. The oxidative oligomerization was carried out using commercially available metal octoates based on Co, Mn, Zn, Ca, Ba, Li, Zr, Cu and Pb and their combinations as catalyst. It was established that the yield of the oligomerization reaction depending on the active metal component used decreased in the following order: Ba > Zr > Zn > Co > Mn > Ca > Li > Cu > Pb. While at the same time, the oxidative oligomerization reaction carried out using bimetallic catalytic systems did not led to any significant increase in the product yield. The oxidative oligomerization reaction using Ba octoate as catalyst gave a yield of 30.4 % and had a kinematic viscosity at 100 °C of 3.6 cSt, Viscosity Index value of 201 and pour point of minus 10. [ABSTRACT FROM AUTHOR]
ISSN:19782993
DOI:10.9767/bcrec.20363