Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements.
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| Title: | Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements. |
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| Authors: | Kataria, Yash V.1 katariayash1603@gmail.com, Lavrenov, Sergey A.2, Yakovenko, Evgeniya Yu.1, Klushin, Victor A.1, Yakovenko, Roman E.1, Kashparova, Vera P.1, Zubkov, Ivan N.1 |
| Source: | Bulletin of Chemical Reaction Engineering & Catalysis. Oct2025, Vol. 20 Issue 3, p403-410. 8p. |
| Subjects: | Fischer-Tropsch process, Polyolefins, Catalysis, Bimetallic catalysts, Oxidative coupling, Metallic soaps, Alkenes, Lubrication & lubricants manufacturing |
| Abstract: | In the present work we further expanded the scope of the study of the oxidative oligomerization process of synthetic hydrocarbon fraction obtained by Fischer-Tropsch synthesis with a total olefin content (consisting predominantly internal/branched olefins) of 10 % with the aim of producing poly-a-olefin like lubricant material. The oxidative oligomerization was carried out using commercially available metal octoates based on Co, Mn, Zn, Ca, Ba, Li, Zr, Cu and Pb and their combinations as catalyst. It was established that the yield of the oligomerization reaction depending on the active metal component used decreased in the following order: Ba > Zr > Zn > Co > Mn > Ca > Li > Cu > Pb. While at the same time, the oxidative oligomerization reaction carried out using bimetallic catalytic systems did not led to any significant increase in the product yield. The oxidative oligomerization reaction using Ba octoate as catalyst gave a yield of 30.4 % and had a kinematic viscosity at 100 °C of 3.6 cSt, Viscosity Index value of 201 and pour point of minus 10. [ABSTRACT FROM AUTHOR] |
| Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
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| Header | DbId: egs DbLabel: Engineering Source An: 188037108 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Kataria%2C+Yash+V%2E%22">Kataria, Yash V.</searchLink><relatesTo>1</relatesTo><i> katariayash1603@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Lavrenov%2C+Sergey+A%2E%22">Lavrenov, Sergey A.</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Yakovenko%2C+Evgeniya+Yu%2E%22">Yakovenko, Evgeniya Yu.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Klushin%2C+Victor+A%2E%22">Klushin, Victor A.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Yakovenko%2C+Roman+E%2E%22">Yakovenko, Roman E.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Kashparova%2C+Vera+P%2E%22">Kashparova, Vera P.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Zubkov%2C+Ivan+N%2E%22">Zubkov, Ivan N.</searchLink><relatesTo>1</relatesTo> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Bulletin+of+Chemical+Reaction+Engineering+%26+Catalysis%22">Bulletin of Chemical Reaction Engineering & Catalysis</searchLink>. Oct2025, Vol. 20 Issue 3, p403-410. 8p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Fischer-Tropsch+process%22">Fischer-Tropsch process</searchLink><br /><searchLink fieldCode="DE" term="%22Polyolefins%22">Polyolefins</searchLink><br /><searchLink fieldCode="DE" term="%22Catalysis%22">Catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Bimetallic+catalysts%22">Bimetallic catalysts</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidative+coupling%22">Oxidative coupling</searchLink><br /><searchLink fieldCode="DE" term="%22Metallic+soaps%22">Metallic soaps</searchLink><br /><searchLink fieldCode="DE" term="%22Alkenes%22">Alkenes</searchLink><br /><searchLink fieldCode="DE" term="%22Lubrication+%26+lubricants+manufacturing%22">Lubrication & lubricants manufacturing</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: In the present work we further expanded the scope of the study of the oxidative oligomerization process of synthetic hydrocarbon fraction obtained by Fischer-Tropsch synthesis with a total olefin content (consisting predominantly internal/branched olefins) of 10 % with the aim of producing poly-a-olefin like lubricant material. The oxidative oligomerization was carried out using commercially available metal octoates based on Co, Mn, Zn, Ca, Ba, Li, Zr, Cu and Pb and their combinations as catalyst. It was established that the yield of the oligomerization reaction depending on the active metal component used decreased in the following order: Ba > Zr > Zn > Co > Mn > Ca > Li > Cu > Pb. While at the same time, the oxidative oligomerization reaction carried out using bimetallic catalytic systems did not led to any significant increase in the product yield. The oxidative oligomerization reaction using Ba octoate as catalyst gave a yield of 30.4 % and had a kinematic viscosity at 100 °C of 3.6 cSt, Viscosity Index value of 201 and pour point of minus 10. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Bulletin of Chemical Reaction Engineering & Catalysis is the property of Universitas Diponegoro and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.9767/bcrec.20363 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 8 StartPage: 403 Subjects: – SubjectFull: Fischer-Tropsch process Type: general – SubjectFull: Polyolefins Type: general – SubjectFull: Catalysis Type: general – SubjectFull: Bimetallic catalysts Type: general – SubjectFull: Oxidative coupling Type: general – SubjectFull: Metallic soaps Type: general – SubjectFull: Alkenes Type: general – SubjectFull: Lubrication & lubricants manufacturing Type: general Titles: – TitleFull: Oxidative Oligomerization of Fischer-Tropsch Internal Olefins Catalyzed by Metal Octoates of s, p and d Block Elements. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Kataria, Yash V. – PersonEntity: Name: NameFull: Lavrenov, Sergey A. – PersonEntity: Name: NameFull: Yakovenko, Evgeniya Yu. – PersonEntity: Name: NameFull: Klushin, Victor A. – PersonEntity: Name: NameFull: Yakovenko, Roman E. – PersonEntity: Name: NameFull: Kashparova, Vera P. – PersonEntity: Name: NameFull: Zubkov, Ivan N. IsPartOfRelationships: – BibEntity: Dates: – D: 01 M: 10 Text: Oct2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 19782993 Numbering: – Type: volume Value: 20 – Type: issue Value: 3 Titles: – TitleFull: Bulletin of Chemical Reaction Engineering & Catalysis Type: main |
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