A comprehensive study on growth and characterizations of diphenylcarbinol single crystal for electrical, mechanical, and non-linear optical applications.
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| Title: | A comprehensive study on growth and characterizations of diphenylcarbinol single crystal for electrical, mechanical, and non-linear optical applications. |
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| Authors: | Shukla, Mayank1 (AUTHOR), Kumar, Binay1 (AUTHOR) b3kumar69@yahoo.co.in |
| Source: | Journal of Materials Science: Materials in Electronics. Sep2025, Vol. 36 Issue 27, p1-15. 15p. |
| Subjects: | Single crystals, Crystal growth, Phenol, Lattice constants, Microhardness, Nonlinear optical techniques, Permittivity, Optical properties |
| Abstract: | Diphenylcarbinol single crystals were grown by cost-effective temperature-controlled solution growth technique of size 26 × 2 × 1 mm3. SCXRD and PXRD determined its orthorhombic crystal system and its structural parameters, which are a = 18.6499Å, b = 20.8936Å, c = 5.0359Å, and volume 1962.31 Å3. Molecular interactions and fingerprint plot of diphenylcarbinol (DPC) crystal were studied by Hirshfeld surface analysis and resulted that H–H intermolecular interaction dominates with 61.2% over other interactions. UV–Vis analysis revealed the linear optical response, direct allowed transition nature, and wide band gap 4.60 eV of the crystal. Thermal studies revealed high crystallinity, melting point 69 °C, and decomposition point 183 °C of the crystal. Diphenylcarbinol single crystal falls under the category of soft materials, which was revealed through microhardness study with work hardening coefficient 2.5. Voids cover 9.11% volume of the unit cell of DPC. High dielectric constant and low dielectric loss of organic DPC crystal are useful for good non-linear response. SHG study revealed the non-linear property of DPC, and its SHG efficiency is 30% of KDP. The promising results of diphenylcarbinol crystal under various characterizations suggest its potential to be used in electrical and non-linear applications. [ABSTRACT FROM AUTHOR] |
| Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) | |
| Database: | Engineering Source |
| FullText | Text: Availability: 0 |
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| Header | DbId: egs DbLabel: Engineering Source An: 188151363 AccessLevel: 6 PubType: Academic Journal PubTypeId: academicJournal PreciseRelevancyScore: 0 |
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| Items | – Name: Title Label: Title Group: Ti Data: A comprehensive study on growth and characterizations of diphenylcarbinol single crystal for electrical, mechanical, and non-linear optical applications. – Name: Author Label: Authors Group: Au Data: <searchLink fieldCode="AR" term="%22Shukla%2C+Mayank%22">Shukla, Mayank</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Kumar%2C+Binay%22">Kumar, Binay</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> b3kumar69@yahoo.co.in</i> – Name: TitleSource Label: Source Group: Src Data: <searchLink fieldCode="JN" term="%22Journal+of+Materials+Science%3A+Materials+in+Electronics%22">Journal of Materials Science: Materials in Electronics</searchLink>. Sep2025, Vol. 36 Issue 27, p1-15. 15p. – Name: Subject Label: Subjects Group: Su Data: <searchLink fieldCode="DE" term="%22Single+crystals%22">Single crystals</searchLink><br /><searchLink fieldCode="DE" term="%22Crystal+growth%22">Crystal growth</searchLink><br /><searchLink fieldCode="DE" term="%22Phenol%22">Phenol</searchLink><br /><searchLink fieldCode="DE" term="%22Lattice+constants%22">Lattice constants</searchLink><br /><searchLink fieldCode="DE" term="%22Microhardness%22">Microhardness</searchLink><br /><searchLink fieldCode="DE" term="%22Nonlinear+optical+techniques%22">Nonlinear optical techniques</searchLink><br /><searchLink fieldCode="DE" term="%22Permittivity%22">Permittivity</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+properties%22">Optical properties</searchLink> – Name: Abstract Label: Abstract Group: Ab Data: Diphenylcarbinol single crystals were grown by cost-effective temperature-controlled solution growth technique of size 26 × 2 × 1 mm3. SCXRD and PXRD determined its orthorhombic crystal system and its structural parameters, which are a = 18.6499Å, b = 20.8936Å, c = 5.0359Å, and volume 1962.31 Å3. Molecular interactions and fingerprint plot of diphenylcarbinol (DPC) crystal were studied by Hirshfeld surface analysis and resulted that H–H intermolecular interaction dominates with 61.2% over other interactions. UV–Vis analysis revealed the linear optical response, direct allowed transition nature, and wide band gap 4.60 eV of the crystal. Thermal studies revealed high crystallinity, melting point 69 °C, and decomposition point 183 °C of the crystal. Diphenylcarbinol single crystal falls under the category of soft materials, which was revealed through microhardness study with work hardening coefficient 2.5. Voids cover 9.11% volume of the unit cell of DPC. High dielectric constant and low dielectric loss of organic DPC crystal are useful for good non-linear response. SHG study revealed the non-linear property of DPC, and its SHG efficiency is 30% of KDP. The promising results of diphenylcarbinol crystal under various characterizations suggest its potential to be used in electrical and non-linear applications. [ABSTRACT FROM AUTHOR] – Name: AbstractSuppliedCopyright Label: Group: Ab Data: <i>Copyright of Journal of Materials Science: Materials in Electronics is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.) |
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| RecordInfo | BibRecord: BibEntity: Identifiers: – Type: doi Value: 10.1007/s10854-025-15796-7 Languages: – Code: eng Text: English PhysicalDescription: Pagination: PageCount: 15 StartPage: 1 Subjects: – SubjectFull: Single crystals Type: general – SubjectFull: Crystal growth Type: general – SubjectFull: Phenol Type: general – SubjectFull: Lattice constants Type: general – SubjectFull: Microhardness Type: general – SubjectFull: Nonlinear optical techniques Type: general – SubjectFull: Permittivity Type: general – SubjectFull: Optical properties Type: general Titles: – TitleFull: A comprehensive study on growth and characterizations of diphenylcarbinol single crystal for electrical, mechanical, and non-linear optical applications. Type: main BibRelationships: HasContributorRelationships: – PersonEntity: Name: NameFull: Shukla, Mayank – PersonEntity: Name: NameFull: Kumar, Binay IsPartOfRelationships: – BibEntity: Dates: – D: 21 M: 09 Text: Sep2025 Type: published Y: 2025 Identifiers: – Type: issn-print Value: 09574522 Numbering: – Type: volume Value: 36 – Type: issue Value: 27 Titles: – TitleFull: Journal of Materials Science: Materials in Electronics Type: main |
| ResultId | 1 |
