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Structural and electronic tuning of hybrid metal thiocyanate N-oxides.

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Title: Structural and electronic tuning of hybrid metal thiocyanate N-oxides.
Authors: Robertson, Grace M.1 (AUTHOR), Jaffe, Adam1 (AUTHOR) ajaffe@nd.edu
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 10/21/2025, Vol. 54 Issue 39, p14648-14653. 6p.
Subjects: Pyridine derivatives, Manganese, Thiocyanates, Electron configuration, Nickel, Cobalt
Abstract: Hybrid metal thiocyanates are highly tailorable materials isolable under mild synthetic conditions. By varying pyridine-N-oxide derivatives within manganese, cobalt, and nickel congeners, we show fine-tuning of structural and electronic features depending on molecular substituent and metal selection, providing a roadmap for application-specific customization and potential property-tuning. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 188472606
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Data: Structural and electronic tuning of hybrid metal thiocyanate N-oxides.
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  Data: <searchLink fieldCode="AR" term="%22Robertson%2C+Grace+M%2E%22">Robertson, Grace M.</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Jaffe%2C+Adam%22">Jaffe, Adam</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> ajaffe@nd.edu</i>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 10/21/2025, Vol. 54 Issue 39, p14648-14653. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Pyridine+derivatives%22">Pyridine derivatives</searchLink><br /><searchLink fieldCode="DE" term="%22Manganese%22">Manganese</searchLink><br /><searchLink fieldCode="DE" term="%22Thiocyanates%22">Thiocyanates</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+configuration%22">Electron configuration</searchLink><br /><searchLink fieldCode="DE" term="%22Nickel%22">Nickel</searchLink><br /><searchLink fieldCode="DE" term="%22Cobalt%22">Cobalt</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Hybrid metal thiocyanates are highly tailorable materials isolable under mild synthetic conditions. By varying pyridine-N-oxide derivatives within manganese, cobalt, and nickel congeners, we show fine-tuning of structural and electronic features depending on molecular substituent and metal selection, providing a roadmap for application-specific customization and potential property-tuning. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.1039/d5dt02188j
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      – Code: eng
        Text: English
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        PageCount: 6
        StartPage: 14648
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      – SubjectFull: Pyridine derivatives
        Type: general
      – SubjectFull: Manganese
        Type: general
      – SubjectFull: Thiocyanates
        Type: general
      – SubjectFull: Electron configuration
        Type: general
      – SubjectFull: Nickel
        Type: general
      – SubjectFull: Cobalt
        Type: general
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      – TitleFull: Structural and electronic tuning of hybrid metal thiocyanate N-oxides.
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            NameFull: Robertson, Grace M.
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            NameFull: Jaffe, Adam
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            – D: 21
              M: 10
              Text: 10/21/2025
              Type: published
              Y: 2025
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              Value: 54
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              Value: 39
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            – TitleFull: Dalton Transactions: An International Journal of Inorganic Chemistry
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