Effect of Alloy Elements Segregation on Bi Heterogeneous Nucleation and Local Corrosion Activity in 1215MS Steel with Added Bi.

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Title: Effect of Alloy Elements Segregation on Bi Heterogeneous Nucleation and Local Corrosion Activity in 1215MS Steel with Added Bi.
Authors: Hou, Yanhui1,2,3 (AUTHOR) houyanhui@wust.edu.cn, Ni, Zhi1,2,3 (AUTHOR), Li, Guangqiang1,2,3 (AUTHOR)
Source: Steel Research International. Nov2025, Vol. 96 Issue 11, p524-533. 10p.
Subjects: Heterogenous nucleation, Interface stability, Ab-initio calculations, Alloys, Steel corrosion, Manganous sulfide, Separation (Technology), High strength steel
Abstract: This study detected and analyzed the composite inclusion MnSBi in 1215MS steel with added Bi. The heterogeneous nucleation interface between MnS and Bi was comprehensively studied using first‐principles calculations, and the segregation tendency of alloy elements at the interface and the effect of element segregation on nucleation and local corrosion activity are analyzed in depth. The calculation results indicate that Cr, Mo, and V can segregate at the MnS (001)/Bi (100) interface, while Co, Cu, and Ni do not segregate at this interface. As the atomic radius increases, the segregation tendency of these elements at this interface gradually shifts from being less prone to segregation to being more prone to segregation. The segregation of Cr, Mo, and V at the interface enhances the stability of the interface and facilitates the heterogeneous nucleation of Bi on MnS. The segregation of Cr and Mo at the interface has a certain inhibitory effect on the adsorption of chloride ions at the interface, while the segregation of V at the interface promotes the adsorption of chloride ions at the interface. [ABSTRACT FROM AUTHOR]
Copyright of Steel Research International is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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Items – Name: Title
  Label: Title
  Group: Ti
  Data: Effect of Alloy Elements Segregation on Bi Heterogeneous Nucleation and Local Corrosion Activity in 1215MS Steel with Added Bi.
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  Data: <searchLink fieldCode="AR" term="%22Hou%2C+Yanhui%22">Hou, Yanhui</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<i> houyanhui@wust.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Ni%2C+Zhi%22">Ni, Zhi</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Li%2C+Guangqiang%22">Li, Guangqiang</searchLink><relatesTo>1,2,3</relatesTo> (AUTHOR)
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  Data: <searchLink fieldCode="JN" term="%22Steel+Research+International%22">Steel Research International</searchLink>. Nov2025, Vol. 96 Issue 11, p524-533. 10p.
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  Data: <searchLink fieldCode="DE" term="%22Heterogenous+nucleation%22">Heterogenous nucleation</searchLink><br /><searchLink fieldCode="DE" term="%22Interface+stability%22">Interface stability</searchLink><br /><searchLink fieldCode="DE" term="%22Ab-initio+calculations%22">Ab-initio calculations</searchLink><br /><searchLink fieldCode="DE" term="%22Alloys%22">Alloys</searchLink><br /><searchLink fieldCode="DE" term="%22Steel+corrosion%22">Steel corrosion</searchLink><br /><searchLink fieldCode="DE" term="%22Manganous+sulfide%22">Manganous sulfide</searchLink><br /><searchLink fieldCode="DE" term="%22Separation+%28Technology%29%22">Separation (Technology)</searchLink><br /><searchLink fieldCode="DE" term="%22High+strength+steel%22">High strength steel</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: This study detected and analyzed the composite inclusion MnSBi in 1215MS steel with added Bi. The heterogeneous nucleation interface between MnS and Bi was comprehensively studied using first‐principles calculations, and the segregation tendency of alloy elements at the interface and the effect of element segregation on nucleation and local corrosion activity are analyzed in depth. The calculation results indicate that Cr, Mo, and V can segregate at the MnS (001)/Bi (100) interface, while Co, Cu, and Ni do not segregate at this interface. As the atomic radius increases, the segregation tendency of these elements at this interface gradually shifts from being less prone to segregation to being more prone to segregation. The segregation of Cr, Mo, and V at the interface enhances the stability of the interface and facilitates the heterogeneous nucleation of Bi on MnS. The segregation of Cr and Mo at the interface has a certain inhibitory effect on the adsorption of chloride ions at the interface, while the segregation of V at the interface promotes the adsorption of chloride ions at the interface. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Steel Research International is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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    Identifiers:
      – Type: doi
        Value: 10.1002/srin.202500236
    Languages:
      – Code: eng
        Text: English
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      Pagination:
        PageCount: 10
        StartPage: 524
    Subjects:
      – SubjectFull: Heterogenous nucleation
        Type: general
      – SubjectFull: Interface stability
        Type: general
      – SubjectFull: Ab-initio calculations
        Type: general
      – SubjectFull: Alloys
        Type: general
      – SubjectFull: Steel corrosion
        Type: general
      – SubjectFull: Manganous sulfide
        Type: general
      – SubjectFull: Separation (Technology)
        Type: general
      – SubjectFull: High strength steel
        Type: general
    Titles:
      – TitleFull: Effect of Alloy Elements Segregation on Bi Heterogeneous Nucleation and Local Corrosion Activity in 1215MS Steel with Added Bi.
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            NameFull: Hou, Yanhui
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            NameFull: Ni, Zhi
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            NameFull: Li, Guangqiang
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            – D: 01
              M: 11
              Text: Nov2025
              Type: published
              Y: 2025
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