View in EDS

Kinetic study of dihydroxy-1,3-indanedione and aspartic acid in gemini (14-s-14) surfactants: a multi-technique approach.

Saved in:
Bibliographic Details
Title: Kinetic study of dihydroxy-1,3-indanedione and aspartic acid in gemini (14-s-14) surfactants: a multi-technique approach.
Authors: Kumar, Dileep1,2 (AUTHOR) kumar.dileep@vlu.edu.vn, Rub, Malik Abdul3 (AUTHOR) malikrub@gmail.com, Srivastava, Abhishek4 (AUTHOR) aabhichem@gla.ac.in, Sultana, Nazima5 (AUTHOR) sultana.nazima47@gmail.com, Posa, Mihalj6 (AUTHOR) mihaljp@uns.ac.rs, Sharma, Poonam7 (AUTHOR) drpoonamsharma@rediffmail.com, Saha, Bidyut8 (AUTHOR) b_saha31@rediffmail.com, Alzahrani, Khalid A.3,9 (AUTHOR) kaalzahrani1@kau.edu.sa, Bhattarai, Ajaya10 (AUTHOR) ajaya.bhattarai@mmamc.tu.edu.np
Source: Research on Chemical Intermediates. Dec2025, Vol. 51 Issue 12, p6819-6837. 19p.
Subjects: Aspartic acid, Micellar catalysis, Chemical kinetics, Surface active agents, Critical micelle concentration, Thermodynamic state variables, Organic compounds, Spectrophotometry
Abstract: The present work deals with kinetic study of dihydroxy-1,3-indanedione (Nin) and aspartic acid (AA) in gemini (14-s-14) surfactants at 343 K applying the UV spectrophotometric approach. The values of the rate constant (kψ) were determined in geminis by varying different experimental reaction ingredients, i.e., [Nin], [AA], pH and temperatures. The study follows a fractional- and first-order kinetics of paths in [Nin] and [AA], respectively. The effect of several concentrations of gemini surfactants ranging from 1 to 3000 × 10–5 mol dm−3 was carried out and kψ achieved at varied concentrations, thus, were recorded. Quantitative analyses of results calculated at [surfactants] are shown as kψ vs. [14-s-14] plot and are treated using a kinetic model called pseudo-phase model of micellar catalysis. To evaluate the critical micellar concentration (cmc) of pure gemini and gemini + reactants, a conductometric approach was applied under the current kinetic reaction conditions. Binding parameters (KX for AA and KY for Nin), micellar-rate constant (km) and thermodynamic parameters (ΔH#, ΔS# and Ea) are also determined and discussed, appropriately. [ABSTRACT FROM AUTHOR]
Copyright of Research on Chemical Intermediates is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 189360688
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Kinetic study of dihydroxy-1,3-indanedione and aspartic acid in gemini (14-s-14) surfactants: a multi-technique approach.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Kumar%2C+Dileep%22">Kumar, Dileep</searchLink><relatesTo>1,2</relatesTo> (AUTHOR)<i> kumar.dileep@vlu.edu.vn</i><br /><searchLink fieldCode="AR" term="%22Rub%2C+Malik+Abdul%22">Rub, Malik Abdul</searchLink><relatesTo>3</relatesTo> (AUTHOR)<i> malikrub@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Srivastava%2C+Abhishek%22">Srivastava, Abhishek</searchLink><relatesTo>4</relatesTo> (AUTHOR)<i> aabhichem@gla.ac.in</i><br /><searchLink fieldCode="AR" term="%22Sultana%2C+Nazima%22">Sultana, Nazima</searchLink><relatesTo>5</relatesTo> (AUTHOR)<i> sultana.nazima47@gmail.com</i><br /><searchLink fieldCode="AR" term="%22Posa%2C+Mihalj%22">Posa, Mihalj</searchLink><relatesTo>6</relatesTo> (AUTHOR)<i> mihaljp@uns.ac.rs</i><br /><searchLink fieldCode="AR" term="%22Sharma%2C+Poonam%22">Sharma, Poonam</searchLink><relatesTo>7</relatesTo> (AUTHOR)<i> drpoonamsharma@rediffmail.com</i><br /><searchLink fieldCode="AR" term="%22Saha%2C+Bidyut%22">Saha, Bidyut</searchLink><relatesTo>8</relatesTo> (AUTHOR)<i> b_saha31@rediffmail.com</i><br /><searchLink fieldCode="AR" term="%22Alzahrani%2C+Khalid+A%2E%22">Alzahrani, Khalid A.</searchLink><relatesTo>3,9</relatesTo> (AUTHOR)<i> kaalzahrani1@kau.edu.sa</i><br /><searchLink fieldCode="AR" term="%22Bhattarai%2C+Ajaya%22">Bhattarai, Ajaya</searchLink><relatesTo>10</relatesTo> (AUTHOR)<i> ajaya.bhattarai@mmamc.tu.edu.np</i>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Research+on+Chemical+Intermediates%22">Research on Chemical Intermediates</searchLink>. Dec2025, Vol. 51 Issue 12, p6819-6837. 19p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Aspartic+acid%22">Aspartic acid</searchLink><br /><searchLink fieldCode="DE" term="%22Micellar+catalysis%22">Micellar catalysis</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+kinetics%22">Chemical kinetics</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+active+agents%22">Surface active agents</searchLink><br /><searchLink fieldCode="DE" term="%22Critical+micelle+concentration%22">Critical micelle concentration</searchLink><br /><searchLink fieldCode="DE" term="%22Thermodynamic+state+variables%22">Thermodynamic state variables</searchLink><br /><searchLink fieldCode="DE" term="%22Organic+compounds%22">Organic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Spectrophotometry%22">Spectrophotometry</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The present work deals with kinetic study of dihydroxy-1,3-indanedione (Nin) and aspartic acid (AA) in gemini (14-s-14) surfactants at 343 K applying the UV spectrophotometric approach. The values of the rate constant (kψ) were determined in geminis by varying different experimental reaction ingredients, i.e., [Nin], [AA], pH and temperatures. The study follows a fractional- and first-order kinetics of paths in [Nin] and [AA], respectively. The effect of several concentrations of gemini surfactants ranging from 1 to 3000 × 10–5 mol dm−3 was carried out and kψ achieved at varied concentrations, thus, were recorded. Quantitative analyses of results calculated at [surfactants] are shown as kψ vs. [14-s-14] plot and are treated using a kinetic model called pseudo-phase model of micellar catalysis. To evaluate the critical micellar concentration (cmc) of pure gemini and gemini + reactants, a conductometric approach was applied under the current kinetic reaction conditions. Binding parameters (KX for AA and KY for Nin), micellar-rate constant (km) and thermodynamic parameters (ΔH#, ΔS# and Ea) are also determined and discussed, appropriately. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Research on Chemical Intermediates is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=189360688
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1007/s11164-025-05756-5
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 19
        StartPage: 6819
    Subjects:
      – SubjectFull: Aspartic acid
        Type: general
      – SubjectFull: Micellar catalysis
        Type: general
      – SubjectFull: Chemical kinetics
        Type: general
      – SubjectFull: Surface active agents
        Type: general
      – SubjectFull: Critical micelle concentration
        Type: general
      – SubjectFull: Thermodynamic state variables
        Type: general
      – SubjectFull: Organic compounds
        Type: general
      – SubjectFull: Spectrophotometry
        Type: general
    Titles:
      – TitleFull: Kinetic study of dihydroxy-1,3-indanedione and aspartic acid in gemini (14-s-14) surfactants: a multi-technique approach.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Kumar, Dileep
      – PersonEntity:
          Name:
            NameFull: Rub, Malik Abdul
      – PersonEntity:
          Name:
            NameFull: Srivastava, Abhishek
      – PersonEntity:
          Name:
            NameFull: Sultana, Nazima
      – PersonEntity:
          Name:
            NameFull: Posa, Mihalj
      – PersonEntity:
          Name:
            NameFull: Sharma, Poonam
      – PersonEntity:
          Name:
            NameFull: Saha, Bidyut
      – PersonEntity:
          Name:
            NameFull: Alzahrani, Khalid A.
      – PersonEntity:
          Name:
            NameFull: Bhattarai, Ajaya
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 12
              Text: Dec2025
              Type: published
              Y: 2025
          Identifiers:
            – Type: issn-print
              Value: 09226168
          Numbering:
            – Type: volume
              Value: 51
            – Type: issue
              Value: 12
          Titles:
            – TitleFull: Research on Chemical Intermediates
              Type: main
ResultId 1