Optimizing the Tribological Performance of Graphite–Resin Composites: The Role of High Crystallinity, Nano Morphology, and Hydrophobic Surface Modification.

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Title: Optimizing the Tribological Performance of Graphite–Resin Composites: The Role of High Crystallinity, Nano Morphology, and Hydrophobic Surface Modification.
Authors: Baek, So-jung1 (AUTHOR), Tak, Yeo-jin1,2 (AUTHOR), Yu, Da-hyun1 (AUTHOR), Park, Seong-yeon1,2 (AUTHOR), Um, Do-hyun2 (AUTHOR), Cho, Kwang-youn1 (AUTHOR) kycho@kicet.re.kr
Source: Nanomaterials (2079-4991). Nov2025, Vol. 15 Issue 21, p1655. 19p.
Subjects: Graphite composites, Crystallinity, Friction velocity, Wear resistance, Nanostructures, Hydrophobic surfaces, Mechanical behavior of materials
Abstract: Graphite, with its layered structure and weak van der Waals bonding between graphene nano layers, exhibits excellent self-lubricating properties. Natural graphite, characterized by high crystallinity, and artificial graphite, with relatively low crystallinity, exhibit distinct friction behaviors and structural differences, which significantly influence the performance of graphite–resin composites as solid lubricants. This study investigates the effects of natural/artificial graphite ratios and hydrophobic silane coupling treatment on the oil impregnation behavior, friction coefficient, wear stability, and microstructural changes in graphite–resin composites. Under a vertical load of 88,260 N and surface pressure of 50 MPa, the impregnated graphite–resin composites demonstrated low friction coefficients and stable wear behavior. SEM analysis revealed well-preserved microstructures, and Raman spectroscopy confirmed the formation of stable lubrication films through the ID/IG ratio, indicating graphene exfoliation. The results indicate that natural graphite provides dense structures and stable friction, while artificial graphite enhances oil impregnation but leads to unstable friction behavior. [ABSTRACT FROM AUTHOR]
Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Optimizing the Tribological Performance of Graphite–Resin Composites: The Role of High Crystallinity, Nano Morphology, and Hydrophobic Surface Modification.
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  Data: <searchLink fieldCode="JN" term="%22Nanomaterials+%282079-4991%29%22">Nanomaterials (2079-4991)</searchLink>. Nov2025, Vol. 15 Issue 21, p1655. 19p.
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  Data: <searchLink fieldCode="DE" term="%22Graphite+composites%22">Graphite composites</searchLink><br /><searchLink fieldCode="DE" term="%22Crystallinity%22">Crystallinity</searchLink><br /><searchLink fieldCode="DE" term="%22Friction+velocity%22">Friction velocity</searchLink><br /><searchLink fieldCode="DE" term="%22Wear+resistance%22">Wear resistance</searchLink><br /><searchLink fieldCode="DE" term="%22Nanostructures%22">Nanostructures</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrophobic+surfaces%22">Hydrophobic surfaces</searchLink><br /><searchLink fieldCode="DE" term="%22Mechanical+behavior+of+materials%22">Mechanical behavior of materials</searchLink>
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  Data: Graphite, with its layered structure and weak van der Waals bonding between graphene nano layers, exhibits excellent self-lubricating properties. Natural graphite, characterized by high crystallinity, and artificial graphite, with relatively low crystallinity, exhibit distinct friction behaviors and structural differences, which significantly influence the performance of graphite–resin composites as solid lubricants. This study investigates the effects of natural/artificial graphite ratios and hydrophobic silane coupling treatment on the oil impregnation behavior, friction coefficient, wear stability, and microstructural changes in graphite–resin composites. Under a vertical load of 88,260 N and surface pressure of 50 MPa, the impregnated graphite–resin composites demonstrated low friction coefficients and stable wear behavior. SEM analysis revealed well-preserved microstructures, and Raman spectroscopy confirmed the formation of stable lubrication films through the ID/IG ratio, indicating graphene exfoliation. The results indicate that natural graphite provides dense structures and stable friction, while artificial graphite enhances oil impregnation but leads to unstable friction behavior. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Nanomaterials (2079-4991) is the property of MDPI and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3390/nano15211655
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      – Code: eng
        Text: English
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        PageCount: 19
        StartPage: 1655
    Subjects:
      – SubjectFull: Graphite composites
        Type: general
      – SubjectFull: Crystallinity
        Type: general
      – SubjectFull: Friction velocity
        Type: general
      – SubjectFull: Wear resistance
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      – SubjectFull: Nanostructures
        Type: general
      – SubjectFull: Hydrophobic surfaces
        Type: general
      – SubjectFull: Mechanical behavior of materials
        Type: general
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      – TitleFull: Optimizing the Tribological Performance of Graphite–Resin Composites: The Role of High Crystallinity, Nano Morphology, and Hydrophobic Surface Modification.
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            NameFull: Baek, So-jung
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            NameFull: Um, Do-hyun
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              M: 11
              Text: Nov2025
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              Y: 2025
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