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胜利油田氮气泡沫稠油乳状液 稳定性影响因素研究.

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Title: 胜利油田氮气泡沫稠油乳状液 稳定性影响因素研究.
Alternate Title: Study on the factors affecting the stability of N2 foam heavy oil emulsion in Shengli Oilfield.
Authors: 孙玉海1 sunyuhai.slyt@sinopec.com, 张阳1, 刘树德2, 张云芝1, 贾云飞2, 刘文胜2, 王倩1, 武宏伟2, 李如雪1
Source: Chemical Engineering of Oil & Gas / Shi You Yu Tian Ran Qi Hua Gong. Oct2025, Vol. 54 Issue 5, p98-105. 8p.
Subjects: Enhanced oil recovery, Demulsification, Coalescence (Chemistry), Oil fields, Surface stability, Shengli Oil Field (China), Emulsions, Foam
Abstract (English): Objective The produced fluid from the CNL joint station in Shengli Oilfield is predominantly composed of high-viscosity heavy oil. After chemical enhanced oil recovery (EOR) treatment, the liquid phase remains production enhancing treatment agents such as residual heavy oil viscosity reducers, organic retarding acid, reservoir cleaning agents. Under the production mode of gas flooding and foam flooding, highly dispersed microbubble groups are formed in the heavy oil emulsion, which makes defoaming and demulsification difficult. In view of the above technical bottlenecks, the multi-scale stability mechanism of foam heavy oil emulsion is systematically analyzed, which is a key guiding significance for the development of targeted demulsification technology. Method Based on the mechanism of multiphase interface interaction, the characteristic components of crude oil, the interfacial activity of foaming agents and the adsorption characteristics of production enhancing treatment agents were systematically explored, and the main controlling factors affecting the stability of foam heavy oil emulsion were revealed at the molecular level. Based on interfacial dilational rheology, Zeta potential spectra and dynamic light scattering experiments, the synergistic mechanism of interfacial film strength, electrostatic repulsion effect and steric hindrance effect in emulsion stability was explained in multiple dimensions. Result When the mass ratio of colloid to asphaltene in crude oil was 1.45∶1.00, the colloid and asphaltene were adsorbed to the oil-water interfacial film, and the stability of the interfacial film was enhanced by the steric hindrance effect. QP2 (foaming agent type Ⅱ) and CL3 (water-soluble viscosity reducer) had the strongest influence on the stability of foam heavy oil emulsion. When the two agents were compounded, the interfacial dilational viscoelastic modulus increased to 83.9 mN/m, the absolute value of Zeta potential reached 32.6 mV, and the stability parameter TSI value decreased to 23.6, which was 14.2% lower than that of the single system. Conclusion This study first elucidates the multi-scale synergistic stabilization mechanism of chemical agent-microbubble-interface film under the combined exploitation mode of gas flooding and chemical flooding, which can guide the joint station to study the targeted demulsification system based on the reaction principle, improve the work efficiency of the joint station and reduce the production cost. [ABSTRACT FROM AUTHOR]
Abstract (Chinese): 目的 胜利油田 CNL 联合站采出液以高黏度稠油为主, 经化学强化采油工艺处理后, 液相中残留稠油降黏剂、有 机缓速酸、油层清洗剂等增产处理剂; 在气驱、泡沫驱开采模式下, 稠油乳状液内形成高分散性微气泡群, 导致体系消泡破 乳困难。针对上述技术瓶颈, 系统解析泡沫稠油乳状液多尺度稳定机制, 对开发靶向破乳技术具有关键指导意义。方法 基 于多相界面作用机制, 系统探究原油特征组分、起泡剂界面活性以及增产处理剂吸附特性, 从分子水平揭示影响泡沫稠油 乳状液稳定性的主控因素; 基于界面扩张流变学、Zeta 电位谱图以及动态光散射实验, 多维度阐释界面膜强度、静电排斥 效应及空间位阻效应在乳状液稳定性中的协同作用机制。结果 原油中胶质和沥青质的质量比为 1.45∶1.00, 胶质协同沥 青质吸附到油水界面膜, 通过空间位阻效应强化界面膜稳定性; 起泡剂Ⅱ型 (QP2) 、水溶性降黏剂 (CL3) 对泡沫稠油乳状 液稳定性影响因素最为显著; 二者复配时, 界面扩张黏弹模量提升至 83.9 mN/ m, Zeta 电位绝对值达到 32.6 mV, 且稳定性指 数 TSI 值降至 23.6, 较单一体系下降 14.2%。结论 在气驱/化学驱复合开采模式下, 化学剂−微气泡−界面膜多尺度协同稳定 机制, 可指导联合站基于反作用原理研究靶向破乳体系, 提高联合站工作效率, 降低生产成本。 [ABSTRACT FROM AUTHOR]
Copyright of Chemical Engineering of Oil & Gas / Shi You Yu Tian Ran Qi Hua Gong is the property of PetroChina Southwest Oil & Gas Field Company and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Label: Title
  Group: Ti
  Data: 胜利油田氮气泡沫稠油乳状液 稳定性影响因素研究.
– Name: TitleAlt
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  Data: Study on the factors affecting the stability of N2 foam heavy oil emulsion in Shengli Oilfield.
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  Data: <searchLink fieldCode="AR" term="%22孙玉海%22">孙玉海</searchLink><relatesTo>1</relatesTo><i> sunyuhai.slyt@sinopec.com</i><br /><searchLink fieldCode="AR" term="%22张阳%22">张阳</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22刘树德%22">刘树德</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22张云芝%22">张云芝</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22贾云飞%22">贾云飞</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22刘文胜%22">刘文胜</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22王倩%22">王倩</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22武宏伟%22">武宏伟</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22李如雪%22">李如雪</searchLink><relatesTo>1</relatesTo>
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– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Enhanced+oil+recovery%22">Enhanced oil recovery</searchLink><br /><searchLink fieldCode="DE" term="%22Demulsification%22">Demulsification</searchLink><br /><searchLink fieldCode="DE" term="%22Coalescence+%28Chemistry%29%22">Coalescence (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Oil+fields%22">Oil fields</searchLink><br /><searchLink fieldCode="DE" term="%22Surface+stability%22">Surface stability</searchLink><br /><searchLink fieldCode="DE" term="%22Shengli+Oil+Field+%28China%29%22">Shengli Oil Field (China)</searchLink><br /><searchLink fieldCode="DE" term="%22Emulsions%22">Emulsions</searchLink><br /><searchLink fieldCode="DE" term="%22Foam%22">Foam</searchLink>
– Name: Abstract
  Label: Abstract (English)
  Group: Ab
  Data: Objective The produced fluid from the CNL joint station in Shengli Oilfield is predominantly composed of high-viscosity heavy oil. After chemical enhanced oil recovery (EOR) treatment, the liquid phase remains production enhancing treatment agents such as residual heavy oil viscosity reducers, organic retarding acid, reservoir cleaning agents. Under the production mode of gas flooding and foam flooding, highly dispersed microbubble groups are formed in the heavy oil emulsion, which makes defoaming and demulsification difficult. In view of the above technical bottlenecks, the multi-scale stability mechanism of foam heavy oil emulsion is systematically analyzed, which is a key guiding significance for the development of targeted demulsification technology. Method Based on the mechanism of multiphase interface interaction, the characteristic components of crude oil, the interfacial activity of foaming agents and the adsorption characteristics of production enhancing treatment agents were systematically explored, and the main controlling factors affecting the stability of foam heavy oil emulsion were revealed at the molecular level. Based on interfacial dilational rheology, Zeta potential spectra and dynamic light scattering experiments, the synergistic mechanism of interfacial film strength, electrostatic repulsion effect and steric hindrance effect in emulsion stability was explained in multiple dimensions. Result When the mass ratio of colloid to asphaltene in crude oil was 1.45∶1.00, the colloid and asphaltene were adsorbed to the oil-water interfacial film, and the stability of the interfacial film was enhanced by the steric hindrance effect. QP2 (foaming agent type Ⅱ) and CL3 (water-soluble viscosity reducer) had the strongest influence on the stability of foam heavy oil emulsion. When the two agents were compounded, the interfacial dilational viscoelastic modulus increased to 83.9 mN/m, the absolute value of Zeta potential reached 32.6 mV, and the stability parameter TSI value decreased to 23.6, which was 14.2% lower than that of the single system. Conclusion This study first elucidates the multi-scale synergistic stabilization mechanism of chemical agent-microbubble-interface film under the combined exploitation mode of gas flooding and chemical flooding, which can guide the joint station to study the targeted demulsification system based on the reaction principle, improve the work efficiency of the joint station and reduce the production cost. [ABSTRACT FROM AUTHOR]
– Name: Abstract
  Label: Abstract (Chinese)
  Group: Ab
  Data: 目的 胜利油田 CNL 联合站采出液以高黏度稠油为主, 经化学强化采油工艺处理后, 液相中残留稠油降黏剂、有 机缓速酸、油层清洗剂等增产处理剂; 在气驱、泡沫驱开采模式下, 稠油乳状液内形成高分散性微气泡群, 导致体系消泡破 乳困难。针对上述技术瓶颈, 系统解析泡沫稠油乳状液多尺度稳定机制, 对开发靶向破乳技术具有关键指导意义。方法 基 于多相界面作用机制, 系统探究原油特征组分、起泡剂界面活性以及增产处理剂吸附特性, 从分子水平揭示影响泡沫稠油 乳状液稳定性的主控因素; 基于界面扩张流变学、Zeta 电位谱图以及动态光散射实验, 多维度阐释界面膜强度、静电排斥 效应及空间位阻效应在乳状液稳定性中的协同作用机制。结果 原油中胶质和沥青质的质量比为 1.45∶1.00, 胶质协同沥 青质吸附到油水界面膜, 通过空间位阻效应强化界面膜稳定性; 起泡剂Ⅱ型 (QP2) 、水溶性降黏剂 (CL3) 对泡沫稠油乳状 液稳定性影响因素最为显著; 二者复配时, 界面扩张黏弹模量提升至 83.9 mN/ m, Zeta 电位绝对值达到 32.6 mV, 且稳定性指 数 TSI 值降至 23.6, 较单一体系下降 14.2%。结论 在气驱/化学驱复合开采模式下, 化学剂−微气泡−界面膜多尺度协同稳定 机制, 可指导联合站基于反作用原理研究靶向破乳体系, 提高联合站工作效率, 降低生产成本。 [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Chemical Engineering of Oil & Gas / Shi You Yu Tian Ran Qi Hua Gong is the property of PetroChina Southwest Oil & Gas Field Company and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.3969/j.issn.1007-3426.2025.05.012
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      – Code: chi
        Text: Chinese
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        PageCount: 8
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      – SubjectFull: Enhanced oil recovery
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      – SubjectFull: Demulsification
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      – SubjectFull: Coalescence (Chemistry)
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      – SubjectFull: Oil fields
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      – SubjectFull: Surface stability
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      – SubjectFull: Emulsions
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      – SubjectFull: Foam
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      – TitleFull: 胜利油田氮气泡沫稠油乳状液 稳定性影响因素研究.
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              Text: Oct2025
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