CU ELECTRODEPOSITION ON POLYPYRROLE PRECOAT FOR THE METALLIZATION OF PRINTED CIRCUIT BOARDS.

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Title: CU ELECTRODEPOSITION ON POLYPYRROLE PRECOAT FOR THE METALLIZATION OF PRINTED CIRCUIT BOARDS.
Authors: JUNHUI, HU1, HUI, Y.1, XIAOGE, CH.1, CHUANYUN, W.1 cywan@sit.edu.cn
Source: Archives of Metallurgy & Materials. 2025, Vol. 70 Issue 4, p1905-1912. 8p.
Subjects: Copper plating, Polypyrrole, Metalation, Circuit board manufacturing, Electroplating, Electrochemical experiments, Green technology, Printed circuits industry
Abstract: To explore an alternative green metallization strategy for nonconductive plastics, a conductive polypyrrole (PPy) precoat was prepared by in-situ interfacial polymerization of pyrrole on printed circuit boards (PCBs) and the electrodeposition of Cu on PPy precoat was investigated using both voltage-controlled method and current-controlled method. A uniform PPy film was successfully obtained on the PCB surface through modifying the PCB wettability and optimizing the pyrrole solution. Electrochemical measurements showed that sufficient polarization was necessary for the electroreduction and growth of Cu crystals on the PPy precoat due to its high electrical resistance. The presence of through-holes adjacent to copper in PCB boards demonstrates that constant-current electroplating enables effective deposition of uniform, adherent copper layers on polypyrrole (PPy) - pretreated substrates, establishing a viable alternative to conventional electroless copper plating for through-hole metallization in PCB manufacturing. [ABSTRACT FROM AUTHOR]
Copyright of Archives of Metallurgy & Materials is the property of Polish Academy of Sciences and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
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  Data: CU ELECTRODEPOSITION ON POLYPYRROLE PRECOAT FOR THE METALLIZATION OF PRINTED CIRCUIT BOARDS.
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  Data: <searchLink fieldCode="AR" term="%22JUNHUI%2C+HU%22">JUNHUI, HU</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22HUI%2C+Y%2E%22">HUI, Y.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22XIAOGE%2C+CH%2E%22">XIAOGE, CH.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22CHUANYUN%2C+W%2E%22">CHUANYUN, W.</searchLink><relatesTo>1</relatesTo><i> cywan@sit.edu.cn</i>
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  Data: <searchLink fieldCode="JN" term="%22Archives+of+Metallurgy+%26+Materials%22">Archives of Metallurgy & Materials</searchLink>. 2025, Vol. 70 Issue 4, p1905-1912. 8p.
– Name: Subject
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  Data: <searchLink fieldCode="DE" term="%22Copper+plating%22">Copper plating</searchLink><br /><searchLink fieldCode="DE" term="%22Polypyrrole%22">Polypyrrole</searchLink><br /><searchLink fieldCode="DE" term="%22Metalation%22">Metalation</searchLink><br /><searchLink fieldCode="DE" term="%22Circuit+board+manufacturing%22">Circuit board manufacturing</searchLink><br /><searchLink fieldCode="DE" term="%22Electroplating%22">Electroplating</searchLink><br /><searchLink fieldCode="DE" term="%22Electrochemical+experiments%22">Electrochemical experiments</searchLink><br /><searchLink fieldCode="DE" term="%22Green+technology%22">Green technology</searchLink><br /><searchLink fieldCode="DE" term="%22Printed+circuits+industry%22">Printed circuits industry</searchLink>
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  Label: Abstract
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  Data: To explore an alternative green metallization strategy for nonconductive plastics, a conductive polypyrrole (PPy) precoat was prepared by in-situ interfacial polymerization of pyrrole on printed circuit boards (PCBs) and the electrodeposition of Cu on PPy precoat was investigated using both voltage-controlled method and current-controlled method. A uniform PPy film was successfully obtained on the PCB surface through modifying the PCB wettability and optimizing the pyrrole solution. Electrochemical measurements showed that sufficient polarization was necessary for the electroreduction and growth of Cu crystals on the PPy precoat due to its high electrical resistance. The presence of through-holes adjacent to copper in PCB boards demonstrates that constant-current electroplating enables effective deposition of uniform, adherent copper layers on polypyrrole (PPy) - pretreated substrates, establishing a viable alternative to conventional electroless copper plating for through-hole metallization in PCB manufacturing. [ABSTRACT FROM AUTHOR]
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  Label:
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  Data: <i>Copyright of Archives of Metallurgy & Materials is the property of Polish Academy of Sciences and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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RecordInfo BibRecord:
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    Identifiers:
      – Type: doi
        Value: 10.24425/amm.2025.156277
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 8
        StartPage: 1905
    Subjects:
      – SubjectFull: Copper plating
        Type: general
      – SubjectFull: Polypyrrole
        Type: general
      – SubjectFull: Metalation
        Type: general
      – SubjectFull: Circuit board manufacturing
        Type: general
      – SubjectFull: Electroplating
        Type: general
      – SubjectFull: Electrochemical experiments
        Type: general
      – SubjectFull: Green technology
        Type: general
      – SubjectFull: Printed circuits industry
        Type: general
    Titles:
      – TitleFull: CU ELECTRODEPOSITION ON POLYPYRROLE PRECOAT FOR THE METALLIZATION OF PRINTED CIRCUIT BOARDS.
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            NameFull: JUNHUI, HU
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            NameFull: HUI, Y.
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            NameFull: XIAOGE, CH.
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            NameFull: CHUANYUN, W.
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            – D: 01
              M: 10
              Text: 2025
              Type: published
              Y: 2025
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